Tridentate Metal Coordination Complexes As Active Species for Non-Aqueous Redox Flow Batteries

ChemSusChem ◽  
2016 ◽  
Vol 9 (23) ◽  
pp. 3317-3323 ◽  
Author(s):  
Anjula M. Kosswattaarachchi ◽  
Alan E. Friedman ◽  
Timothy R. Cook

2017 ◽  
Vol 46 (47) ◽  
pp. 16439-16445 ◽  
Author(s):  
Gabriel M. Duarte ◽  
Jason D. Braun ◽  
Patrick K. Giesbrecht ◽  
David E. Herbert

Reduce, reuse, recycle: Coordination complexes of ‘non-innocent’ diimine-pyridine ligands (DIP) are shown to be stable, multi-electron anolytes for redox-flow batteries.


2018 ◽  
Vol 6 (27) ◽  
pp. 13286-13293 ◽  
Author(s):  
Gongwei Wang ◽  
Bing Huang ◽  
Dan Liu ◽  
Dong Zheng ◽  
Joshua Harris ◽  
...  

A series of polycyclic aromatic hydrocarbons were systematically investigated as the anode redox-active species for nonaqueous flow batteries.


Author(s):  
Ruijie Ye ◽  
Dirk Henkensmeier ◽  
Sang Jun Yoon ◽  
Zhifeng Huang ◽  
Dong Kyu Kim ◽  
...  

The utilization of intermittent renewable energy sources needs low-cost, reliable energy storage systems in the future. Among various electrochemical energy storage systems, redox flow batteries (RFBs) are promising with merits of independent energy storage and power generation capability, localization flexibility, high efficiency, low scaling-up cost, and excellent long charge/discharge cycle life. RFBs typically use metal ions as reacting species. The most exploited types are all-vanadium RFBs (VRFBs). Here, we discuss the core components for the VRFBs, including the development and application of different types of membranes, electrode materials, and stack system. In addition, we introduce the recent progress in the discovery of novel electrolytes, such as redox-active organic compounds, polymers, and organic/inorganic suspensions. Versatile structures, tunable properties, and abundant resources of organic-based electrolytes make them suitable for cost-effective stationary applications. With the active species in solid form, suspension electrolytes are expected to provide enhanced volumetric energy densities.


2021 ◽  
Author(s):  
Claudina X. Cammack ◽  
Harry D. Pratt ◽  
Leo J. Small ◽  
Travis M. Anderson

A new family of tunable iron bipyridine coordination complexes has been synthesized and tested in a non-aqueous flow battery.


2016 ◽  
Vol 9 (11) ◽  
pp. 3531-3543 ◽  
Author(s):  
Jarrod D. Milshtein ◽  
Aman Preet Kaur ◽  
Matthew D. Casselman ◽  
Jeffrey A. Kowalski ◽  
Subrahmanyam Modekrutti ◽  
...  

Symmetric flow cell cycling of a soluble phenothiazine.


2021 ◽  
Author(s):  
N. Harsha Attanayake ◽  
Zhiming Liang ◽  
Yilin Wang ◽  
Aman Preet Kaur ◽  
Sean R. Parkin ◽  
...  

Nonaqueous electrolytes require the inclusion of supporting salts to achieve sufficient conductivity for battery applications. In redox flow batteries (RFBs) wherein solutions contain active species at molar values, the presence...


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