Halomethyl Derivatives of Silicon, Germanium, and Tin by the Diazomethane Method

2007 ◽  
pp. 37-42 ◽  
Author(s):  
Dietmar Seyferth ◽  
Eugene G. Rochow ◽  
Julian B. Honeycutt ◽  
Robert C. Bryan
1975 ◽  
Vol 53 (7) ◽  
pp. 975-978 ◽  
Author(s):  
E. E. Isaacs ◽  
W. A. G. Graham

Convenient procedures are reported for the synthesis of the compounds (η-C7H7)Mo(CO)2MR3 (M = Si, R = Cl; M = Ge, R = Cl, F, Ph; M = Sn, R = Cl, Ph ). The triphenyl derivatives were accessible through the anion [(η-C7H7)Mo(CO)2]−, while the MCl3 derivatives were prepared from (η-C7H7)Mo(CO)2Cl. Infrared, n.m.r., and mass spectrometric properties are reported.


Author(s):  
Noboru Yamazaki ◽  
Seiichi Nakahama ◽  
Akira Hirao ◽  
Yoshinobu Shiraishi ◽  
Hoang Minh Phung

1971 ◽  
Vol 49 (4) ◽  
pp. 644-648 ◽  
Author(s):  
M. E. Peach ◽  
H. G. Spinney

Various non-metallic derivatives of pentafluorothiophenol, containing sulfur bonded to boron, carbon, silicon, germanium, phosphorus, arsenic, antimony, sulfur, and chlorine, have been prepared, mainly from the reaction of Pb(SC6F5)2 with a non-metallic halide, and characterized. The 19F n.m.r. spectra have been examined. The coordinating power of sulfur attached to a C6F5 group is minimal.


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