Insertions of Sulfur Dioxide into Metal-Carbon Bonds

2007 ◽  
pp. 394-397
Author(s):  
Fausto Calderazzo
Keyword(s):  
Sulfur Dioxide ◽  
Carbon Bonds

Zinc-Mediated Intermolecular Reductive Radical Fluoroalkylsulfination of Unsaturated Carbon-Carbon Bonds with Fluoroalkyl Bromides and Sulfur Dioxide

2019 ◽  
Vol 25 (7) ◽  
pp. 1824-1828 ◽  
Author(s):  
Yongan Liu ◽  
Qiongzhen Lin ◽  
Zhiwei Xiao ◽  
Changge Zheng ◽  
Yong Guo ◽  
...  
Keyword(s):  
Sulfur Dioxide ◽  
Carbon Carbon Bonds ◽  
Carbon Bonds

Insertion of sulfur dioxide into metalcarbon bonds of chloro(methyl)palladium complexes

Polyhedron ◽  
2003 ◽  
Vol 22 (6) ◽  
pp. 805-810 ◽  
Author(s):  
Kelin Li ◽  
Ilia A Guzei ◽  
James Darkwa
Keyword(s):  
Sulfur Dioxide ◽  
Palladium Complexes ◽  
Carbon Bonds

Bestimmung des nucleophilen Charakters der Zinn-Kohlenstoff-Bindung, II / Determination of the Nucleophilicity of Tin-Carbon Bond, II

1975 ◽  
Vol 30 (1-2) ◽  
pp. 91-95 ◽  
Author(s):  
Udo Kunze ◽  
Johnson D. Koola
Keyword(s):  
Sulfur Dioxide ◽  
Organic Residue ◽  
Carbon Bond ◽  
Carbon Bonds ◽  
Good Agreement

The SO2-insertion into tin-carbon bonds of mixed tetraorganostannanes, R3SnR′ (R=C6H5, CH3; R'=CH3, C6H5, CH2=CH), is determined by the nucleophilicity of the organic residue attached to metal and shows a decreasing rate in the order aryl > alkenyl > alkyl. A correlation to Taft’s constant is given. The behaviour of triphenylvinyltin toward sulfur dioxide is in good agreement with this rule, as the insertion of one or two moles of SO2 takes place only into Sn—C6H5 bond.

The Determination of Sulfur Dioxide-Correction

1917 ◽  
Vol 9 (12) ◽  
pp. 1148-1148
Author(s):  
James Withrow
Keyword(s):  
Sulfur Dioxide
Sign in / Sign up

Export Citation Format

Share Document