scholarly journals Electrochemical Fluorination of Vinyl Boronates through Donor‐Stabilized Vinyl Carbocation Intermediates

2022 ◽  
Author(s):  
Hosea M. Nelson ◽  
Benjamin Wigman ◽  
Woojin Lee ◽  
Wenjing Wei ◽  
K. N. Houk
Keyword(s):  
Electrochemical Fluorination ◽  
Vinyl Boronates

scholarly journals Electrochemical Fluorination of Vinyl Boronates Through Donor-Stabilized Vinyl Carbocation Intermediates

2021 ◽  
Author(s):  
Benjamin Wigman ◽  
Woojin Lee ◽  
Wenjing Wei ◽  
Ken Houk ◽  
Hosea Nelson
Keyword(s):  
Electrochemical Fluorination ◽  
Vinyl Boronates

scholarly journals Flow Electrochemistry: A Safe Tool for Fluorine Chemistry

2021 ◽  
Author(s):  
Bethan Winterson ◽  
Tim Rennigholtz ◽  
Thomas Wirth
Keyword(s):  
Fluorine Chemistry ◽  
Electrochemical Fluorination

The heightened activity of compounds containing fluorine, especially in the field of pharmaceuticals, provides major impetus for the development of new fluorination procedures. A scalable, versatile, and safe electrochemical fluorination...

The electrochemical fluorination of propene

1976 ◽  
Vol 6 (1) ◽  
pp. 23-32 ◽  
Author(s):  
F. G. Drakesmith ◽  
D. A. Hughes
Keyword(s):  
Electrochemical Fluorination

scholarly journals Highly selective electrochemical fluorination of dithioacetal derivatives bearing electron-withdrawing substituents at the position α to the sulfur atom using poly(HF) salts

2015 ◽  
Vol 11 ◽  
pp. 85-91 ◽  
Author(s):  
Bin Yin ◽  
Shinsuke Inagi ◽  
Toshio Fuchigami
Keyword(s):  
Sulfur Atom ◽  
Nitrile Group ◽  
Amide Group ◽  
Sharp Contrast ◽  
Product Selectivity ◽  
Electrochemical Fluorination ◽  
Weak Electron ◽  
Electron Withdrawing Substituents

Anodic fluorination of dithioacetals bearing electron-withdrawing ester, acetyl, amide, and nitrile groups at their α-positions was comparatively studied using various supporting poly(HF) salts like Et3N·nHF (n = 3–5) and Et4NF·nHF (n = 3–5). In the former two cases, the corresponding α-fluorination products or fluorodesulfurization products were obtained selectively depending on supporting poly(HF) salts used. In sharp contrast, in the latter two cases, fluorination product selectivity was strongly affected by the electron-withdrawing ability of α-substituents: A dithioacetal bearing a relatively weak electron-withdrawing amide group provided a fluorodesulfurization product selectively while a dithioacetal having a strongly electron-withdrawing nitrile group gave the α-fluorination product predominantly regardless of the poly(HF) salts used.

Electrochemical fluorination of sulfones

1969 ◽  
Vol 18 (4) ◽  
pp. 862-863
Author(s):  
I. N. Rozhkov ◽  
A. V. Bukhtiarov ◽  
I. L. Knunyants
Keyword(s):  
Electrochemical Fluorination

Development of a Split Bipolar Electrode System for Electrochemical Fluorination of Triphenylmethane

2018 ◽  
Vol 6 (1) ◽  
pp. 97-100 ◽  
Author(s):  
Kazuhiro Miyamoto ◽  
Hiroki Nishiyama ◽  
Ikuyoshi Tomita ◽  
Shinsuke Inagi
Keyword(s):  
Electrode System ◽  
Bipolar Electrode ◽  
Electrochemical Fluorination
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