ChemInform Abstract: VIBRATIONAL SPECTRA OF SOME GROUP VB HALIDES PART 3, A FAR INFRARED AND RAMAN SPECTRAL STUDY OF SOME HEXAHALOGENO-, PENTAHALOGENO-, AND TETRAHALOGENO-BISMUTHATE(III) AND -ANTIMONATE(III) SALTS

1973 ◽  
Vol 4 (38) ◽  
pp. no-no
Author(s):  
M. A. HOOPER ◽  
D. W. JAMES
1973 ◽  
Vol 26 (7) ◽  
pp. 1401 ◽  
Author(s):  
MA Hooper ◽  
DW James

Vibrational spectra of a series of halogeno-complex ions of antimony(III) and bismuth(III) are reported. Results of crystal spectra are discussed in terms of the structural environment and a comparative study of Raman solution and solid state spectra is given. Some force constants for hexahalogeno species on a modified Urey-Bradley force field have been calculated and their significance is discussed.


2002 ◽  
Author(s):  
Cibelle Lopes ◽  
Sokki Sathaiah ◽  
Antonio L. B. Pinheiro ◽  
Janaina Duarte ◽  
Airton A. Martin ◽  
...  

1984 ◽  
Vol 39 (4) ◽  
pp. 357-361 ◽  
Author(s):  
Robert Becker ◽  
Wolfgang Brockner ◽  
Herbert Schäfer

Pb2P2Se6 crystallizes in the monoclinic system, space group Pn (No. 13) with the lattice constantsa = 974.2 (4) pm. b = 766.2 (3) pm. c = 689.8 (3) pm, β=91.44(5)°.The title compound is isotypic to the homologous Pb2P2S6. In the structure there are discrete P2Se4-6 anions.Far infrared, infrared and Raman spectra of this compound have been recorded. The observed frequencies are assigned on the basis of P2Se4-6 units with C2h symmetry in the crystal. DTA-data have been determined and interpreted.


1994 ◽  
Vol 228 (4-5) ◽  
pp. 410-416 ◽  
Author(s):  
Benoît Tremblay ◽  
Laurent Manceron ◽  
Pascale Roy ◽  
Anne-Marie LeQuéré ◽  
Denis Roy

2022 ◽  
Vol 5 (1) ◽  
pp. 1-7
Author(s):  
Asmaa J.i AL-Lame ◽  
Wafaa F. Rodhan ◽  
Nafeesa J. Kadhim ◽  
Shahed K. Taher

The standard heat of formation (ΔHof) and binding energy (ΔEb) for the free compound and their derivatives are calculated by using the PM3 method at 273K of Hyperchem.-8.07 program. The compound is more stable than their derivatives. furthermore to investigate the reactive site of the molecules the electrostatic potential of free derivatives is measured and pm3 is used to evaluate the vibrational spectra of the free derivatives, the frequencies are obtained approximately agreed with those values experimentally found; in addition, the calculation helps to assign clearly the most diagnostic bands .


1998 ◽  
Vol 78 (2) ◽  
pp. 111-116 ◽  
Author(s):  
T Wadayama ◽  
T Arigane ◽  
K Fujine ◽  
A Hatta

1983 ◽  
Vol 38 (5) ◽  
pp. 555-558 ◽  
Author(s):  
Robert Becker ◽  
Wolfgang Brockner ◽  
Claus Wibbelmann

Far infrared, infrared and Raman spectra of tin hexathiohypodiphosphate Sn2P2S6 (mono­clinic modification II) have been recorded. The observed frequencies are assigned on the basis of P2S64-units with C2h symmetry in the crystal. The assignment is supported by the correlation D3d (dissolved P2S64- ion) → C2h. DTA-data have been determined and interpreted.


1991 ◽  
Vol 30 (20) ◽  
pp. 3832-3836 ◽  
Author(s):  
Kan. Kanamori ◽  
Yukari. Ookubo ◽  
Kazuhito. Ino ◽  
Kiyoyasu. Kawai ◽  
Hitoshi. Michibata

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