ChemInform Abstract: X-RAY PHOTOELECTRON SPECTRA OF INORGANIC MOLECULES. 18. OBSERVATIONS ON SULFUR 2P BINDING ENERGIES IN TRANSITION METAL COMPLEXES OF SULFUR-CONTAINING LIGANDS

1977 ◽  
Vol 8 (46) ◽  
Author(s):  
S. A. BEST ◽  
P. BRANT ◽  
R. D. FELTHAM ◽  
T. B. RAUCHFUSS ◽  
D. M. ROUNDHILL ◽  
...  
Keyword(s):  
Transition Metal ◽  
Metal Complexes ◽  
Transition Metal Complexes ◽  
Binding Energies ◽  
Photoelectron Spectra ◽  
X Ray ◽  
Inorganic Molecules ◽  
Sulfur Containing

X-ray photoelectron spectra of inorganic molecules. 18. Observations on sulfur 2p binding energies in transition metal complexes of sulfur-containing ligands

1977 ◽  
Vol 16 (8) ◽  
pp. 1976-1979 ◽  
Author(s):  
Stephen A. Best ◽  
Patrick. Brant ◽  
Robert D. Feltham ◽  
Thomas B. Rauchfuss ◽  
D. Max. Roundhill ◽  
...  
Keyword(s):  
Transition Metal ◽  
Metal Complexes ◽  
Transition Metal Complexes ◽  
Binding Energies ◽  
Photoelectron Spectra ◽  
X Ray ◽  
Inorganic Molecules ◽  
Sulfur Containing

Röntgenphotoelektronenspektroskopische Untersuchungen an einigen planaren Pseudohalogeno-d8-Übergangsmetallkomplexen / X-ray Photoelectron Spectra of Some Planar Pseudohalogeno-d8-Transition Metal Complexes

1972 ◽  
Vol 27 (8) ◽  
pp. 884-887 ◽  
Author(s):  
F. Holsboer ◽  
W. Beck
Keyword(s):  
Transition Metal ◽  
Metal Complexes ◽  
Transition Metal Complexes ◽  
Binding Energies ◽  
Photoelectron Spectra ◽  
Mo Calculations ◽  
X Ray ◽  
Metal Cyanide ◽  
Linkage Isomerism ◽  
Bonding Mode

X-ray photoelectron spectra, pseudohalide complexes of gold (III), linkage isomerismCore binding energies of metals in the isomeric (Ph3As) 2Pd (NCS) 2 and (Ph3As) 2Pd (SCN) 2, and in [AsPh4] [AuX4] (X = CN-, tetrazolate, Cl-, N3-) are reported. S- and N-Bonding mode can be distinguished in accord with semiemperical MO-calculations. XPS-results are correlated with Mößbauer spectra and the metal-cyanide and metal-tetrazolate bonds are discussed.

Preparation, properties and structure of some intermediate nido- and arachno-monocarbaboranes

1981 ◽  
Vol 46 (10) ◽  
pp. 2345-2353 ◽  
Author(s):  
Karel Baše ◽  
Bohumil Štíbr ◽  
Jiří Dolanský ◽  
Josef Duben
Keyword(s):  
Transition Metal ◽  
Metal Complexes ◽  
Transition Metal Complexes ◽  
Nmr Spectra ◽  
Liquid Ammonia ◽  
X Ray Diffraction ◽  
X Ray ◽  
H Nmr ◽  
Starting Compound

The 6-N(CH3)3-6-CB9H11 carbaborane reacts with sodium in liquid ammonia with the formation of 6-CB9H12- which was used as a starting compound for preparing the 4-CB8H14, 9-L-6-CB9H13 (L = (CH3)2S, CH3CN and P(C6H5)3), 1-(η5-C5H5)-1,2-FeCB9H10-, and 2,3-(η5-C5H5)2-2,31-Co2CB9H10- carboranes. The 4-CB8H14 compound was dehydrogenated at 623 K to give 4-(7)-CB8H12 carborane. Base degradation of 6-N(CH3)3-6-CB9H11 in methanol resulted in the formation of 3,4-μ-N(CH3)3CH-B5H10. The structure of all compounds was proposed on the basis of their 11B and 1H NMR spectra and X-ray diffraction was used in the case of the transition metal complexes.

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