ChemInform Abstract: Synthesis of Trisubstituted Thiophenes via a Halogen Dance Reaction at 2-Bromo-5-methylthiophene.

ChemInform ◽  
2010 ◽  
Vol 27 (27) ◽  
pp. no-no
Author(s):  
J. FROEHLICH ◽  
C. HAMETNER ◽  
W. KALT
Keyword(s):  
Halogen Dance Reaction

Use of Thiazoles in the Halogen Dance Reaction:  Application to the Total Synthesis of WS75624 B

2004 ◽  
Vol 69 (7) ◽  
pp. 2381-2385 ◽  
Author(s):  
Eric L. Stangeland ◽  
Tarek Sammakia
Keyword(s):  
Total Synthesis ◽  
Halogen Dance Reaction

scholarly journals Ester Dance Reaction on the Aromatic Ring

2019 ◽  
Author(s):  
Kaoru Matsushita ◽  
Ryosuke Takise ◽  
Kei Muto ◽  
Junichiro Yamaguchi
Keyword(s):  
Carbon Atom ◽  
Aromatic Ring ◽  
Functional Group ◽  
State Of The Art ◽  
Palladium Catalysis ◽  
Ester Group ◽  
Halogen Atoms ◽  
Ester Moiety ◽  
Rearrangement Reactions ◽  
Halogen Dance Reaction

Aromatic rearrangement reactions are useful tools in the organic chemist’s toolbox when generating uncommon substitution patterns. However, it is difficult to precisely translocate a functional group in (hetero)arene systems, with the exception of halogen atoms in a halogen dance reaction. Herein, we describe an unprecedented “ester dance” reaction: a predictable translocation of an ester group from one carbon atom to another on an aromatic ring. Specifically, a phenyl carboxylate substituent can be shifted from one carbon to an adjacent carbon on a (hetero)aromatic ring under palladium catalysis to often give a thermodynamically favored, regioisomeric product with modest to good conversions. The obtained ester moiety can be further converted to various aromatic derivatives through the use of classic as well as state-of-the-art transformations including an amidation, acylations and decarbonylative couplings.

First Halogen Dance Reaction on Oxazoles. Synthesis of 4,5-Disubstituted 2-Phenyloxazoles.

ChemInform ◽  
2005 ◽  
Vol 36 (41) ◽  
Author(s):  
Peter Stanetty ◽  
Markus Spina ◽  
Marko D. Mihovilovic
Keyword(s):  
Halogen Dance Reaction

Base-Catalyzed Halogen Dance Reaction and Oxidative Coupling Sequence as a Convenient Method for the Preparation of Dihalo-bisheteroarenes

2010 ◽  
Vol 12 (9) ◽  
pp. 2136-2139 ◽  
Author(s):  
Yulia A. Getmanenko ◽  
Paul Tongwa ◽  
Tatiana V. Timofeeva ◽  
Seth R. Marder
Keyword(s):  
Convenient Method ◽  
Oxidative Coupling ◽  
Halogen Dance Reaction ◽  
Coupling Sequence

ChemInform Abstract: First Halogen-Dance Reaction in Quinoline Series: Application to a New Synthesis of Quindoline.

ChemInform ◽  
2010 ◽  
Vol 29 (48) ◽  
pp. no-no
Author(s):  
E. ARZEL ◽  
P. ROCCA ◽  
F. MARSAIS ◽  
A. GODARD ◽  
G. QUEGUINER
Keyword(s):  
New Synthesis ◽  
Quinoline Series ◽  
Halogen Dance Reaction

Synthesis of 2-Substituted 3,5-Dibromothiophenes via a Rearrangement Reaction: A New Example of a Base-Catalyzed Halogen Dance Reaction

Synthesis ◽  
1989 ◽  
Vol 1989 (10) ◽  
pp. 771-773 ◽  
Author(s):  
Fritz Sauter ◽  
Hannes Fröhlich ◽  
Wolfram Kalt
Keyword(s):  
Rearrangement Reaction ◽  
Halogen Dance Reaction

Total Synthesis of Caerulomycin C via the Halogen Dance Reaction

2002 ◽  
Vol 4 (14) ◽  
pp. 2385-2388 ◽  
Author(s):  
Tarek Sammakia ◽  
Eric L. Stangeland ◽  
Mark C. Whitcomb
Keyword(s):  
Total Synthesis ◽  
Caerulomycin C ◽  
Halogen Dance Reaction

First Halogen Dance Reaction on Oxazoles. Synthesis of 4,5-Disubstituted 2-Phenyloxazoles

Synlett ◽  
2005 ◽  
pp. 1433-1434 ◽  
Author(s):  
Peter Stanetty ◽  
Markus Spina ◽  
Marko D. Mihovilovic
Keyword(s):  
Halogen Dance Reaction

ChemInform Abstract: Synthesis of β-Substituted and α,β-Disubstituted δ-Carbolines Using a Halogen-Dance Reaction.

ChemInform ◽  
2010 ◽  
Vol 30 (24) ◽  
pp. no-no
Author(s):  
Erwan Arzel ◽  
Patrick Rocca ◽  
Francis Marsais ◽  
Alain Godard ◽  
G. Queguiner
Keyword(s):  
Halogen Dance Reaction
Sign in / Sign up

Export Citation Format

Share Document