The Iodine Atom Transfer Addition Reaction (I-ATRA) Initiated by AIBN: Optimization, Scope and Radical Reaction Pathways.

ChemInform ◽  
2006 ◽  
Vol 37 (23) ◽  
Author(s):  
Piotr Balczewski ◽  
Aldona Szadowiak ◽  
Tomasz Bialas
Keyword(s):  
Iodine Atom ◽  
Addition Reaction ◽  
Radical Reaction ◽  
Reaction Pathways ◽  
Atom Transfer

Two pathways of initiation in the intermolecular iodine atom transfer addition reaction (I-ATRA) initiated by AIBN

2005 ◽  
Vol 16 (3) ◽  
pp. 246-253 ◽  
Author(s):  
Piotr Ba?czewski ◽  
Aldona Szadowiak ◽  
Tomasz Bia?as
Keyword(s):  
Iodine Atom ◽  
Addition Reaction ◽  
Atom Transfer

Iodine Atom-Transfer Ring-Opening of 1,1-Difluoro-2-(1-iodoalkyl)cyclopropanes by Free-Radical Reaction

1990 ◽  
Vol 19 (3) ◽  
pp. 467-468 ◽  
Author(s):  
Tsutomu Morikawa ◽  
Masayuki Uejima ◽  
Kazuaki Yoda ◽  
Takeo Taguchi
Keyword(s):  
Free Radical ◽  
Iodine Atom ◽  
Ring Opening ◽  
Radical Reaction ◽  
Atom Transfer ◽  
Free Radical Reaction

Facile Covalent Attachment of Well-Defined Poly(t-butyl acrylate) on Carbon Nanotubes via Radical Addition Reaction

2008 ◽  
Vol 8 (9) ◽  
pp. 4598-4602 ◽  
Author(s):  
Saet Byeol Oh ◽  
Hye Lynn Kim ◽  
Jun Ho Chang ◽  
Yong-Won Lee ◽  
Jong Hun Han ◽  
...  
Keyword(s):  
Carbon Nanotubes ◽  
Raman Spectroscopy ◽  
Atom Transfer Radical Polymerization ◽  
Butyl Acrylate ◽  
Addition Reaction ◽  
Radical Reaction ◽  
Covalent Bonding ◽  
Radical Addition ◽  
Covalent Attachment ◽  
Atom Transfer

We developed a new method to covalently attach well-defined polymers onto carbon nanotubes (CNTs) using a radical reaction. Well-defined poly(t-butyl acrylate) [p(tBA)] was first prepared by atom transfer radical polymerization, which formed radicals at the end of the polymer chain through an atom transfer. The generated radicals at the chain ends added CNTs to generate covalently functionalized p(tBA)-grafted CNTs. The polymer-attached CNTs showed much improved solubility in organic solvents. The synthesized MWNT-g-p(tBA) and SWNT-g-p(tBA) were characterized by IR, TGA and Raman spectroscopy, clearly indicating the formation of covalent bonding between p(tBA) and CNTs.

A novel synthesis of diethyl 3-iodoalkyl- and 3-iodoalkenylphosphonates via the iodine atom transfer addition reaction

2000 ◽  
Vol 41 (19) ◽  
pp. 3687-3690 ◽  
Author(s):  
Piotr Bałczewski ◽  
Tomasz Białas ◽  
Marian Mikołajczyk
Keyword(s):  
Iodine Atom ◽  
Addition Reaction ◽  
Atom Transfer ◽  
Novel Synthesis
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