ChemInform Abstract: An Enantioselective Oxidative C-H/C-H Cross-Coupling Reaction: Highly Efficient Method to Prepare Planar Chiral Ferrocenes.

ChemInform ◽  
2016 ◽  
Vol 47 (34) ◽  
Author(s):  
De-Wei Gao ◽  
Qing Gu ◽  
Shu-Li You
Keyword(s):  
Efficient Method ◽  
Coupling Reaction ◽  
Cross Coupling ◽  
Highly Efficient ◽  
Cross Coupling Reaction

scholarly journals Palladium-catalyzed α-arylation of carbonyls in the de novo synthesis of aromatic heterocycles

2015 ◽  
Vol 13 (15) ◽  
pp. 4367-4373 ◽  
Author(s):  
Harish K. Potukuchi ◽  
Anatol P. Spork ◽  
Timothy J. Donohoe
Keyword(s):  
Efficient Method ◽  
De Novo ◽  
Coupling Reaction ◽  
Cross Coupling ◽  
De Novo Synthesis ◽  
Aromatic Rings ◽  
Aromatic Heterocycles ◽  
Highly Efficient ◽  
Cross Coupling Reaction ◽  
Palladium Catalyzed

The enolate cross coupling reaction is a highly efficient method for the de novo synthesis of aromatic rings.

scholarly journals Pd(CH3CN)2Cl2/Pipecolinic Acid as a Highly Efficient Catalytic System for Suzuki-Miyaura Cross-coupling Reaction of Bromoaryl Carboxylic Acids in Water

Catalysts ◽  
2019 ◽  
Vol 9 (1) ◽  
pp. 86 ◽  
Author(s):  
Xiaogang Li ◽  
Wenbin Zhang ◽  
Leiqing Fu ◽  
Mengping Guo
Keyword(s):  
Catalytic System ◽  
Coupling Reaction ◽  
Cross Coupling ◽  
Catalytic Performance ◽  
High Turnover ◽  
Mild Conditions ◽  
Highly Efficient ◽  
Cross Coupling Reaction ◽  
Pipecolinic Acid ◽  
Excellent Catalytic Performance

In this study, a convenient and highly efficient catalytic system for the Suzuki-Miyaura coupling reaction was investigated under mild conditions. A combination of Pd(CH3CN)2Cl2 and pipecolinic acid showed excellent catalytic performance and afforded high turnover numbers; turnover numbers were up to 4.9 × 105 for the coupling reaction of 4-bromobenzoic acid and tetraphenylboron sodium. The catalytic system was also effective for the indexes of 4-bromobenzoic acid, and high turnover numbers were obtained.

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