Mechanochemical Ring-Opening Polymerization of Lactide: Liquid-Assisted Grinding for the Green Synthesis of Poly(lactic acid) with High Molecular Weight

ChemSusChem ◽  
2017 ◽  
Vol 10 (18) ◽  
pp. 3529-3533 ◽  
Author(s):  
Nuri Ohn ◽  
Jihoon Shin ◽  
Sung Sik Kim ◽  
Jeung Gon Kim
Keyword(s):  
Molecular Weight ◽  
Lactic Acid ◽  
Green Synthesis ◽  
High Molecular Weight ◽  
Ring Opening ◽  
Ring Opening Polymerization ◽  
Poly Lactic Acid

scholarly journals Synthesis and Characterization of Polyphosphazenes Modified with Hydroxyethyl Methacrylate and Lactic Acid

2013 ◽  
Vol 2013 ◽  
pp. 1-7 ◽  
Author(s):  
Evelyn Carolina Martínez Ceballos ◽  
Ricardo Vera Graziano ◽  
Gonzalo Martínez Barrera ◽  
Oscar Olea Mejía
Keyword(s):  
Lactic Acid ◽  
Ring Opening ◽  
Room Temperature ◽  
Block Structure ◽  
Ring Opening Polymerization ◽  
Synthesis And Characterization ◽  
Poly Lactic Acid ◽  
Hydroxyethyl Methacrylate ◽  
H Nmr

Poly(dichlorophosphazene) was prepared by melt ring-opening polymerization of the hexachlorocyclotriphosphazene. Poly[bis(2-hydroxyethyl-methacrylate)-phosphazene] and poly[(2-hydroxyethyl-methacrylate)-graft-poly(lactic-acid)-phosphazene] were obtained by nucleophilic condensation reactions at different concentrations of the substituents. The properties of the synthesized copolymers were assessed by FTIR,1H-NMR and31P-NMR, thermal analysis (DSC-TGA), and electron microscopy (SEM). The copolymers have a block structure and show twoTg's below room temperature. They are stable up to a temperature of 100°C. The type of the substituents attached to the PZ backbone determines the morphology of the polymers.

Catalytic Ring-Opening Polymerization of Renewable Macrolactones to High Molecular Weight Polyethylene-like Polymers

2011 ◽  
Vol 44 (11) ◽  
pp. 4301-4305 ◽  
Author(s):  
Inge van der Meulen ◽  
Erik Gubbels ◽  
Saskia Huijser ◽  
Rafaël Sablong ◽  
Cor E. Koning ◽  
...  
Keyword(s):  
Molecular Weight ◽  
High Molecular Weight ◽  
Ring Opening ◽  
Ring Opening Polymerization

Surface-Modified Cellulose Nanofibers-graft-poly(lactic acid)s Made by Ring-Opening Polymerization of l-Lactide

2019 ◽  
Vol 27 (4) ◽  
pp. 847-861 ◽  
Author(s):  
Chaniga Chuensangjun ◽  
Kyohei Kanomata ◽  
Takuya Kitaoka ◽  
Yusuf Chisti ◽  
Sarote Sirisansaneeyakul
Keyword(s):  
Lactic Acid ◽  
Ring Opening ◽  
Cellulose Nanofibers ◽  
Ring Opening Polymerization ◽  
Poly Lactic Acid ◽  
Surface Modified ◽  
Modified Cellulose

Article

1998 ◽  
Vol 76 (4) ◽  
pp. 371-381 ◽  
Author(s):  
Ian Manners
Keyword(s):  
Molecular Weight ◽  
Transition Metal ◽  
High Molecular Weight ◽  
Ring Opening ◽  
Ring Opening Polymerization ◽  
Metal Catalysts ◽  
Transition Metal Catalysts ◽  
Organometallic Polymer ◽  
Wide Range ◽  
Initial Discovery

Ring-opening polymerization (ROP) of strained ring-tilted metallocenophanes can be achieved thermally, via anionic or cationic initiation, or by the use of transition-metal catalysts and provides access to a wide range of high molecular weight (Mw = 105-106, Mn > 105) poly(metallocenes). These materials possess a variety of interesting properties and many are very easy to prepare. This article provides an overview of our work, giving background to and an account of the initial discovery, and discusses work on the synthesis and properties of new poly(metallocenes) and related materials with particular emphasis on recent research directions.Key words: metallocene, ring-opening polymerization, ferrocenophane, organometallic polymer.

Sign in / Sign up

Export Citation Format

Share Document