A novel route to synthesize hydrogen storage material ammonia borane via copper (II)-ammonia complex liquid phase oxidization

An overview of recent advances in hydrogen storage is presented in this review. The main focus is on metal hydrides, liquid-phase hydrogen storage material, alkaline earth metal NC/polymer composites and lithium borohydride ammoniate. Boron-nitrogen-based liquid-phase hydrogen storage material is a liquid under ambient conditions, air- and moisture-stable, recyclable and releases H2controllably and cleanly. It is not a solid material. It is easy storage and transport. The development of a liquid-phase hydrogen storage material has the potential to take advantage of the existing liquid-based distribution infrastructure. An air-stable composite material that consists of metallic Mg nanocrystals (NCs) in a gas-barrier polymer matrix that enables both the storage of a high density of hydrogen and rapid kinetics (loading in <30 min at 200°C). Moreover, nanostructuring of Mg provides rapid storage kinetics without using expensive heavy-metal catalysts. The Co-catalyzed lithium borohydride ammoniate, Li(NH3)4/3BH4 releases 17.8 wt% of hydrogen in the temperature range of 135 to 250 °C in a closed vessel. This is the maximum amount of dehydrogenation in all reports. These will reduce economy cost of the global transition from fossil fuels to hydrogen energy.

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Ammonia borane with polyvinylpyrrolidone as a hydrogen storage material: Comparison of different molecular weights

Journal of Physics and Chemistry of Solids ◽

10.1016/j.jpcs.2017.05.033 ◽

2017 ◽

Vol 110 ◽

pp. 394-400 ◽

Cited By ~ 5

Author(s):

Ramanjaneyulu Seemaladinne ◽

Sahithya Pati ◽

Krishna Kharel ◽

Adarsh Bafana ◽

Amal al-Wahish ◽

...

Keyword(s):

Hydrogen Storage ◽

Ammonia Borane ◽

Hydrogen Storage Material ◽

Storage Material ◽

Molecular Weights

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The Route to a Feasible Hydrogen-Storage Material: MOFs versus Ammonia Borane

Chemistry - A European Journal ◽

10.1002/chem.201003364 ◽

2011 ◽

Vol 17 (37) ◽

pp. 10184-10207 ◽

Cited By ~ 55

Author(s):

Thomas Hügle ◽

Monika Hartl ◽

Dieter Lentz

Keyword(s):

Hydrogen Storage ◽

Ammonia Borane ◽

Hydrogen Storage Material ◽

Storage Material

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Hydrogen-mediated affinity of ions found in compressed potassium amidoborane, K[NH2BH3]

CrystEngComm ◽

10.1039/c4ce01221f ◽

2014 ◽

Vol 16 (45) ◽

pp. 10367-10370 ◽

Cited By ~ 4

Author(s):

Ewelina Magos-Palasyuk ◽

Taras Palasyuk ◽

Patryk Zaleski-Ejgierd ◽

Karol Fijalkowski

Keyword(s):

Hydrogen Storage ◽

Theoretical Investigation ◽

Ammonia Borane ◽

Hydrogen Storage Material ◽

Storage Material ◽

Bonding Properties ◽

Derivatives Of

The paper reports on the experimental and theoretical investigation of bonding properties of potassium amidoborane, (K[NH2BH3]), which is one of the most promising compounds for hydrogen storage material among metallated derivatives of ammonia borane (NH3BH3).

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