Synthesis, Structural Characterization and Thermal Stability of A One‐Dimensional Chain‐like Coordination Polymer, [Fe(bpno) 2 (NCS) 3 ]

2013 ◽  
Vol 60 (7) ◽  
pp. 719-724 ◽  
Author(s):  
Hsiu‐Hui Chiu ◽  
Mei‐Chi Shen ◽  
Chih‐Chieh Wang ◽  
Gene‐Hsiang Lee ◽  
Hwo‐Shuenn Sheu
Keyword(s):  
Thermal Stability ◽  
Coordination Polymer ◽  
Structural Characterization ◽  
Dimensional Chain ◽  
One Dimensional ◽  
Thermal Stability Of

The purine–carboxylate-containing coordination polymer poly[[μ4-1-(2-carboxylatoethyl)-6-oxo-6,9-dihydro-1H-purin-9-ido]zinc(II)]

2013 ◽  
Vol 69 (11) ◽  
pp. 1314-1316
Author(s):  
Wen-Juan Ma ◽  
Guo-Ting Li
Keyword(s):  
Thermal Stability ◽  
Coordination Polymer ◽  
Title Compound ◽  
Topological Structure ◽  
Three Dimensional ◽  
Two Dimensional ◽  
One Dimensional ◽  
Metal Organic ◽  
Very High ◽  
Thermal Stability Of

The title compound, [Zn(C8H6N4O3)]nor [Zn(L)]n[H2Lis 3-(6-oxo-6,9-dihydro-1H-purin-1-yl)propionic acid], crystallized as a nonmerohedral twin. The ZnIIcation is four-coordinated, ligated by two carboxylate O atoms from twoLligands and two N atoms from another two ligands. Each ligand bridges four ZnIIcentres, extending the structure into a three-dimensional polymer with a 4-connected (65,41) topological structure containing two-dimensional homochiral layers constructed from one-dimensional metal–organic helices. Investigation of the thermal stability of the compound shows that the network has very high thermostability and is stable up to 720 K.

Structure and magnetic properties of a mixed-ligand copper(II) complex

2015 ◽  
Vol 71 (1) ◽  
pp. 44-47 ◽  
Author(s):  
Rong-Guang Lin ◽  
Yu-Lin Wang ◽  
Qian Liang
Keyword(s):  
Thermal Stability ◽  
Magnetic Properties ◽  
Hydrothermal Synthesis ◽  
Mixed Ligand ◽  
Dimensional Chain ◽  
The Novel ◽  
Two Dimensional ◽  
One Dimensional ◽  
Novel Complex ◽  
Thermal Stability Of

The hydrothermal synthesis of the novel complex poly[[μ2-N1,N4-bis(pyridin-3-yl)naphthalene-1,4-dicarboxamide-κ2N3:N3′](μ4-phthalato-κ4O1:O1:O1′:O2′)copper(II)], [Cu(C8H4O4)(C22H16N4O2)]n, is described. With the phthalate ligand connecting neighbouring CuIIcations, an infinite one-dimensional chain is formed. Adjacent one-dimensional chains are connected by the dicarboxamide ligand, forming an intriguing two-dimensional framework. The magnetic properties and thermal stability of this complex are also described.

A smart sensing Zn (Ⅱ) coordination polymer based on a new viologen ligand exhibiting photochromic and thermochromic and multiple solid detection properties

2021 ◽  
Author(s):  
Heyi Zhang ◽  
Fangyuan He ◽  
Xiaonan Li ◽  
Zhi-Hui Wang ◽  
Hong Zhang
Keyword(s):  
Electron Transfer ◽  
Coordination Polymer ◽  
Self Assembly ◽  
Chain Structure ◽  
The Self ◽  
Dimensional Chain ◽  
One Dimensional ◽  
Smart Sensing

Through the self-assembly of 1,1'-bis(3-cyanobenzyl)-[4,4'-bipyridine] dichloride ligand, m-H2BDC and Zn(NO3)2·6H2O, a novel one-dimensional chain structure multifunctional coordination polymer was successfully synthesized. Due to electron transfer during irradiation and heating to...

Preparation and Structural Characterization of Chain Ni (II) Coordination Polymer Material

2011 ◽  
Vol 322 ◽  
pp. 369-372
Author(s):  
Zhi Xiang Ji
Keyword(s):  
Coordination Polymer ◽  
Polymer Material ◽  
Chain Structure ◽  
Monoclinic Space Group ◽  
Dimensional Chain ◽  
X Ray Diffraction ◽  
One Dimensional ◽  
X Ray ◽  
A Chain

A chain Ni (II) coordination polymer material was prepared and characterized by elemental analysis and single-crystal X-ray diffraction. It crystallizes in monoclinic, space group C2/c with a = 1.24348(13) nm, b = 1.29477(12) nm, c = 1.51480(17) nm and Dc = 1.401 g•cm-3. The results of structural analysis indicated that each Ni (II) ion forms six-coordinated with nitrogen atoms of pyridine and thiocyanate, and the Ni (II) coordination polymer material formed one dimensional chain structure by the interaction of pyridine rings.

Metallo-responsive self-assembly of lipophilic guanines in hydrocarbon solvents: a systematic SAXS structural characterization

Nanoscale ◽  
2020 ◽  
Vol 12 (2) ◽  
pp. 1022-1031 ◽  
Author(s):  
Adriano Gonnelli ◽  
Silvia Pieraccini ◽  
Enrico J. Baldassarri ◽  
Sergio Funari ◽  
Stefano Masiero ◽  
...  
Keyword(s):  
Thermal Stability ◽  
Structural Characterization ◽  
Self Assembly ◽  
Hydrocarbon Solvents ◽  
Thermal Stability Of

Elongation, flexibility and thermal stability of metallo-responsive architectures in dodecane.

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