A General Rotation–Contortion Hamiltonian with Structure Relaxation: Application to the Precessing Internal Rotor Model

1997 ◽  
Vol 183 (1) ◽  
pp. 157-162 ◽  
Author(s):  
Allan L.L. East ◽  
P.R. Bunker
Molecules ◽  
2020 ◽  
Vol 25 (17) ◽  
pp. 3963
Author(s):  
Jizhou Wu ◽  
Jie Ma ◽  
Yuqing Li ◽  
Wenliang Liu ◽  
Peng Li ◽  
...  

This article demonstrates new observation of the high-resolution ro-vibrational bichromatic photoassociation spectra (BPAS) of Cs2 in the 0u+ long-range state below the asymptotes 6S1/2 + 6P1/2. By combining with a modulation spectroscopic technique, precise references of the frequency differences have been engineered through the BPAS, with which the rotational constants of low-lying vibrational levels of the Cs20u+ long-range state have been accurately determined by fitting the frequency differences to the non-rigid-rotor model. The rotational constants for the newly observed seven ro-vibrational levels are summarized and disagreement for the level ῦ = 498 is clarified. The rotational constants of different vibrational levels demonstrate strong perturbations of the related energy structures. A simple analysis is performed and shows good agreement with experimental results.


1997 ◽  
Vol 392 (3-4) ◽  
pp. 243-248 ◽  
Author(s):  
Ashok K. Jain ◽  
Manisha Dudeja ◽  
Sham S. Malik ◽  
Zafar Ahmed

1970 ◽  
Vol 53 (2) ◽  
pp. 798-800 ◽  
Author(s):  
Narendra N. Roy ◽  
G. D. Halsey
Keyword(s):  

2016 ◽  
Vol 7 (3) ◽  
pp. 405-418 ◽  
Author(s):  
Riccardo Gori ◽  
Jacopo Serafini ◽  
Marco Molica Colella ◽  
Massimo Gennaretti

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