Amorphous silicon (a-Si) absorption edge and optical spectra

Author(s):  
1990 ◽  
Vol 192 ◽  
Author(s):  
George D. Cody

ABSTRACTOptical phenomena associated with the absorption edge of crystalline silicon (c-Si) and amorphous silicon hydride (a-Si:H) are presented and compared. The optical properties discussed include the energy dependence, dipole matrix element and density of states associated with the absorption edge; the temperature dependence of the relevant optical energy gaps, and finally the magnitude and temperature dependence of the slope of the Urbach edge for each material. The comparison suggests that the optical properties of the two materials are closely related and that the absorption edge of a-Si:H may be derived from the effect of site disorder on the zone center direct gap of c-Si.


2005 ◽  
Vol 862 ◽  
Author(s):  
G. D. Cody

AbstractThis paper presents a brief review of the research that began in the early '80s, continued through the '90s, and produced a “standard model” for the optical absorption edge of amorphous silicon. The research began as a response to the invention of a-Si:H solar cells by Carlson and Wronski at RCA laboratories in 1976, and the subsequent worldwide interest in the optical characterization of a-Si:H thin films. The immediate need was soon met, but the research continued as an effort to understand the physics of the optical absorption edge in a-Si:H, as well as to understand the differences between, and similarities to, the indirect optical absorption edge of c-Si. In this paper, we highlight the successes of this standard model, and briefly cover its experimental and theoretical development over the last 25 years. We summarize its current status, and suggest some experimental and theoretical opportunities for, and challenges to, what may now be called a standard model for the optical absorption edge of both a-Si:H and a-Ge:H.


1981 ◽  
Vol 42 (C4) ◽  
pp. C4-301-C4-304 ◽  
Author(s):  
G. D. Cody ◽  
T. Tiedje ◽  
B. Abeles ◽  
T. D. Moustakas ◽  
B. Brooks ◽  
...  

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