Equilibrium Constants for the Complexation of Metal Ions by Serum Transferrin

Author(s):  
Wesley R. Harris
Separations ◽  
2021 ◽  
Vol 8 (11) ◽  
pp. 211
Author(s):  
Keisuke Ohto ◽  
Nako Fuchiwaki ◽  
Hiroaki Furugou ◽  
Shintaro Morisada ◽  
Hidetaka Kawakita ◽  
...  

We prepared acetic acid derivatives using three different frameworks, calix[4]arene, alkenyltrimethylol, and trihydroxytriphenylmethane, which differ in the number and size of their coordination sites. We further investigated the extraction properties for aluminum group metal ions. All three extraction reagents exhibited increased extraction compared with the corresponding monomeric compounds, owing to structural effects. The extraction reaction and extraction equilibrium constants were determined using a slope analysis. Their extraction abilities, separation efficiencies, and potential coordination modes are discussed using the extraction equilibrium constants, half-pH values, and spectroscopic data. The calix[4]arene and trihydroxytriphenylmethane derivatives demonstrated allosteric co-extraction of indium ions (In3+) with an unexpected stoichiometry of 1:2.


2013 ◽  
Vol 28 (4) ◽  
pp. 521-528 ◽  
Author(s):  
Pingping Su ◽  
Kim Granholm ◽  
Leo Harju ◽  
Ari Ivaska

1956 ◽  
Vol 78 (9) ◽  
pp. 1816-1818 ◽  
Author(s):  
George B. Hares ◽  
W. Conard Fernelius ◽  
Bodie E. Douglas

1994 ◽  
Vol 33 (22) ◽  
pp. 4991-4998 ◽  
Author(s):  
Wesley R. Harris ◽  
Yong Chen ◽  
Kim Wein

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