Magnetic properties of chloro-{bis-[2-(3-5-dimethylpyrazol-1-yl)ethyl](pyrazol-1-yl)methyl]amine}cobalt(II) tetraphenylborate monoethanolate

2021 ◽  
pp. 719-721
Author(s):  
R. T. Pardasani ◽  
P. Pardasani
Keyword(s):  
Magnetic Properties ◽  
Methyl Amine

Dinuclear Cobalt Complexes with Redox Active Biphenyl Bridging Ligand [Co2(BP)(tqa)2](PF6)2 (H4BP = 4,4’-bis(3-tert-butyl-1,2-catechol), tqa = tris(2-quinolylmethyl)amine): Structure and Magnetic Properties

2021 ◽  
Author(s):  
Yusaku Suenaga ◽  
Takuto Mibu ◽  
Takashi Okubo ◽  
Masahiko Maekawa ◽  
T. Kuroda-Sowa ◽  
...  
Keyword(s):  
Magnetic Properties ◽  
Cobalt Complexes ◽  
Tert Butyl ◽  
Bridging Ligand ◽  
Methyl Amine ◽  
Redox Active ◽  
Amine Structure

The biscatechol, H4BP (4,4’-bis(3-tert-butyl-1,2-catechol)) that connects two redox active catechol moieties directly was synthesized. Also, tpa (tris(2-pyridylmethyl)amine), bpqa (bis(2-pyridylmethyl)(2-quinolylmethyl)amine), pbqa ((2-pyridylmethyl)bis(2-quinolyl methyl)amine), and tqa (tris(2-quinolylmethyl)amine) were synthesized as terminal ligands...

AEM analysis of crystallization in Ti-based amorphous alloys

1983 ◽  
Vol 41 ◽  
pp. 270-271
Author(s):  
A.R. Pelton ◽  
A.F. Marshall ◽  
Y.S. Lee
Keyword(s):  
Magnetic Properties ◽  
Amorphous Alloys ◽  
Amorphous Materials ◽  
Isothermal Annealing ◽  
Amorphous Matrix ◽  
Nucleation And Growth ◽  
Current Interest ◽  
Amorphous Films ◽  
Electrical And Magnetic Properties

Amorphous materials are of current interest due to their desirable mechanical, electrical and magnetic properties. Furthermore, crystallizing amorphous alloys provides an avenue for discerning sequential and competitive phases thus allowing access to otherwise inaccessible crystalline structures. Previous studies have shown the benefits of using AEM to determine crystal structures and compositions of partially crystallized alloys. The present paper will discuss the AEM characterization of crystallized Cu-Ti and Ni-Ti amorphous films.Cu60Ti40: The amorphous alloy Cu60Ti40, when continuously heated, forms a simple intermediate, macrocrystalline phase which then transforms to the ordered, equilibrium Cu3Ti2 phase. However, contrary to what one would expect from kinetic considerations, isothermal annealing below the isochronal crystallization temperature results in direct nucleation and growth of Cu3Ti2 from the amorphous matrix.

Microstructure in soft magnetic E3 (S1, Al) (Sendust) alloys

1988 ◽  
Vol 46 ◽  
pp. 770-771
Author(s):  
June D. Kim
Keyword(s):  
Electron Microscopy ◽  
Magnetic Properties ◽  
Ternary Phase Diagram ◽  
Vertical Tube ◽  
Vacuum Induction Melting ◽  
Induction Melting ◽  
Soft Magnetic ◽  
Quenching Temperature ◽  
Thin Foils ◽  
Vertical Tube Furnace

Iron-base alloys containing 8-11 wt.% Si, 4-8 wt.% Al, known as “Sendust” alloys, show excellent soft magnetic properties. These magnetic properties are strongly dependent on heat treatment conditions, especially on the quenching temperature following annealing. But little has been known about the microstructure and the Fe-Si-Al ternary phase diagram has not been established. In the present investigation, transmission electron microscopy (TEM) has been used to study the microstructure in a Sendust alloy as a function of temperature.An Fe-9.34 wt.% Si-5.34 wt.% Al (approximately Fe3Si0.6Al0.4) alloy was prepared by vacuum induction melting, and homogenized at 1,200°C for 5 hrs. Specimens were heat-treated in a vertical tube furnace in air, and the temperature was controlled to an accuracy of ±2°C. Thin foils for TEM observation were prepared by jet polishing using a mixture of perchloric acid 15% and acetic acid 85% at 10V and ∼13°C. Electron microscopy was performed using a Philips EM 301 microscope.

Magnetic properties of new charge-transfer complexes based on manganese porphyrins

1997 ◽  
Vol 90 (3) ◽  
pp. 407-413
Author(s):  
MARC KELEMEN ◽  
CHRISTOPH WACHTER ◽  
HUBERT WINTER ◽  
ELMAR DORMANN ◽  
RUDOLF GOMPPER ◽  
...  
Keyword(s):  
Magnetic Properties ◽  
Charge Transfer ◽  
Charge Transfer Complexes ◽  
Manganese Porphyrins

Influence of Ni-substitution on magnetic properties of annealed FeNiNbCuSiB alloys

1998 ◽  
Vol 08 (PR2) ◽  
pp. Pr2-111-Pr2-114 ◽  
Author(s):  
P. Vojtaník ◽  
E. Komová ◽  
R. Varga ◽  
R. Matejko ◽  
R. Grössinger ◽  
...  
Keyword(s):  
Magnetic Properties ◽  
Ni Substitution
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