Effective absolute rate constant for the formation of negatively-charged CO2 cluster ions by electron transfer from state-selected Rydberg atoms

1991 ◽  
Vol 18 (4) ◽  
pp. 403-407 ◽  
Author(s):  
T. Kraft ◽  
M. -W. Ruf ◽  
H. Hotop
Keyword(s):  
Electron Transfer ◽  
Rate Constant ◽  
Rydberg Atoms ◽  
Cluster Ions ◽  
Absolute Rate ◽  
Absolute Rate Constant

Chemistry of radical ions: the absolute rate constant of dimerization of radical anions of 1 ,1-diphenyl ethylene

1965 ◽  
Vol 288 (1413) ◽  
pp. 212-223 ◽  
Keyword(s):  
Electron Transfer ◽  
Rate Constant ◽  
Transfer Process ◽  
Aromatic Hydrocarbons ◽  
Radical Anions ◽  
Electron Affinities ◽  
Absolute Rate ◽  
Radical Ions ◽  
Electron Transfer Process ◽  
Absolute Rate Constant

The combination of the labile radical ions, (Ph 2 C:CH 2 )7~, Na+, into dimeric dianions Na + , C - (Ph) 2 .CH 2 .CH 2 .C(Ph) - 2, Na+ was investigated by a flow and a stopflow technique. The bimolecular rate constant of combination was found to be 2 to 3 x 106 1. mole-1 s-1. The reaction was initiated by an electron transfer naphthalene^ + (P/*,2C:CH2) naphthalene+ (P/*,2C:CH^) or terphenylener + (P7fc2C:CH2) ⇔ terphenylene + (Pfe2C:CH^). The equilibrium constant of the first electron transfer process was found to be 20 and of the second about 16. These results are consistent with recent determinations of electron affinities of aromatic hydrocarbons.

Absolute rate constant for the reaction OH + HBr → H2O + Br

1979 ◽  
Vol 63 (3) ◽  
pp. 479-484 ◽  
Author(s):  
A.R. Ravishankara ◽  
P.H. Wine ◽  
A.O. Langford
Keyword(s):  
Rate Constant ◽  
Absolute Rate ◽  
Absolute Rate Constant

Absolute Rate Constant for the O + NO Chemiluminescence in the Near Infrared

1973 ◽  
Author(s):  
Michael F. Golde ◽  
Aidan E. Roche ◽  
Frederick Kaufman
Keyword(s):  
Rate Constant ◽  
Near Infrared ◽  
Absolute Rate ◽  
Absolute Rate Constant
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