Ion exchange and solvent extraction of the thiourea complex cation of technetium-99 from mineral acid solutions

1979 ◽  
Vol 51 (2) ◽  
pp. 401-405 ◽  
Author(s):  
R. Kopunec ◽  
F. macášek ◽  
P. Rajec ◽  
D. Hudecová
1979 ◽  
Vol 51 (1) ◽  
pp. 85-95
Author(s):  
P. Rajec ◽  
V. Mukulaj ◽  
J. Kadrabová

2012 ◽  
Vol 28 (4) ◽  
pp. 1785-1790 ◽  
Author(s):  
A.V.L.N.S.H. HARIHARAN ◽  
CH. SUDHAKAR ◽  
B. VENKATESWARA RAO

Author(s):  
Ya. G. Avdeev ◽  
◽  
D.S. Kuznetsov ◽  
Yu.I. Kuznetsov ◽  
◽  
...  

1984 ◽  
Vol 49 (10) ◽  
pp. 2205-2209
Author(s):  
Jiří Příhoda ◽  
Alois Zeman

The extraction of hafnium(IV) with N-benzoyl-N-phenylhydroxylamine solutions in chloroform or toluene from strongly acid (HClO4) solutions of dimethyl sulfoxide or hexamethylphosphor triamide has been studied. These substances were found to suppress the conversion of the extraction mechanism from ion exchange to solvation: while in solutions free of these substances this conversion takes place at HClO4 concentrations of about 4 mol l-1, in the mixed aqueous-organic (polar) phase the requisite acid concentrations are considerably higher. The possible causes of this effect are discussed.


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