Crystal Structure and Spectral Characterization of a Rare Example of a Salen-Type Zinc Complex with Neutral Monodentate Oxygen Donor Ligands Coordination

2006 ◽  
Vol 137 (8) ◽  
pp. 997-1003 ◽  
Author(s):  
Małgorzata T. Kaczmarek ◽  
Maciej Kubicki ◽  
Wanda Radecka-Paryzek
Keyword(s):  
Crystal Structure ◽  
Zinc Complex ◽  
Spectral Characterization ◽  
Donor Ligands ◽  
Oxygen Donor

The new type of [Zr6(μ3-O)4(μ3-OH)4] cluster core: Crystal structure and spectral characterization of [Zr6O4(OH)4(OOCR)12] (R=But, C(CH3)2Et)

Polyhedron ◽  
2007 ◽  
Vol 26 (3) ◽  
pp. 679-685 ◽  
Author(s):  
P. Piszczek ◽  
A. Radtke ◽  
A. Grodzicki ◽  
A. Wojtczak ◽  
J. Chojnacki
Keyword(s):  
Crystal Structure ◽  
Spectral Characterization ◽  
Cluster Core ◽  
New Type

Crystal structure and spectral characterization of di-n-butyltin(IV) compound of vanillin

2015 ◽  
Vol 14 (4) ◽  
pp. 339-348 ◽  
Author(s):  
Sanasam Sachika Devi ◽  
Manojit Roy ◽  
Subhadip Roy ◽  
Keisham Surjit Singh
Keyword(s):  
Crystal Structure ◽  
Spectral Characterization

Crystal structure of a dysprosium trichloride complex with oxygen donor ligands

1987 ◽  
Vol 139 (1-2) ◽  
pp. 103-104 ◽  
Author(s):  
Xing-Wang Zhang ◽  
Xing-Fu Li ◽  
F. Benetollo ◽  
G. Bombieri
Keyword(s):  
Crystal Structure ◽  
Donor Ligands ◽  
Oxygen Donor

Reactions of bis(isoproplxanthato)nickel(II) with nitrogen or oxygen donor ligands—III. X-ray crystal structure of the complex with pyrazine

Polyhedron ◽  
1996 ◽  
Vol 15 (18) ◽  
pp. 2975-2981 ◽  
Author(s):  
Zdeněk Trávíček ◽  
Richard Pastorek ◽  
Zdeněk Šindelář ◽  
Jiří Kameníček ◽  
Jaromír Marek
Keyword(s):  
Crystal Structure ◽  
Donor Ligands ◽  
X Ray ◽  
Oxygen Donor

scholarly journals Crystal structures of chlorido[dihydroxybis(1-iminoethoxy)]arsanido-κ3 N,As,N′]platinum(II) and of a polymorph of chlorido[dihydroxybis(1-iminopropoxy)arsanido-κ3 N,As,N′]platinum(II)

2020 ◽  
Vol 76 (2) ◽  
pp. 180-185
Author(s):  
Nina R. Marogoa ◽  
D.V. Kama ◽  
Hendrik G. Visser ◽  
M. Schutte-Smith
Keyword(s):  
Crystal Structure ◽  
Hydrogen Bonding ◽  
Crystal Structures ◽  
Three Dimensional ◽  
Donor Ligands ◽  
Intermolecular Hydrogen Bonding ◽  
Π Interactions ◽  
Hydrogen Bonding Interactions ◽  
Oxygen Donor ◽  
Dimensional Network

Each central platinum(II) atom in the crystal structures of chlorido[dihydroxybis(1-iminoethoxy)arsanido-κ3 N,As,N′]platinum(II), [Pt(C4H10AsN2O4)Cl] (1), and of chlorido[dihydroxybis(1-iminopropoxy)arsanido-κ3 N,As,N′]platinum(II), [Pt(C6H14AsN2O4)Cl] (2), is coordinated by two nitrogen donor atoms, a chlorido ligand and to arsenic, which, in turn, is coordinated by two oxygen donor ligands, two hydroxyl ligands and the platinum(II) atom. The square-planar and trigonal–bipyramidal coordination environments around platinum and arsenic, respectively, are significantly distorted with the largest outliers being 173.90 (13) and 106.98 (14)° for platinum and arsenic in (1), and 173.20 (14)° and 94.20 (9)° for (2), respectively. One intramolecular and four classical intermolecular hydrogen-bonding interactions are observed in the crystal structure of (1), which give rise to an infinite three-dimensional network. A similar situation (one intramolecular and four classical intermolecular hydrogen-bonding interactions) is observed in the crystal structure of (2). Various π-interactions are present in (1) between the platinum(II) atom and the centroid of one of the five-membered rings formed by Pt, As, C, N, O with a distance of 3.7225 (7) Å, and between the centroids of five-membered (Pt, As, C, N, O) rings of neighbouring molecules with distances of 3.7456 (4) and 3.7960 (6) Å. Likewise, weak π-interactions are observed in (2) between the platinum(II) atom and the centroid of one of the five-membered rings formed by Pt, As, C, N, O with a distance of 3.8213 (2) Å, as well as between the Cl atom and the centroid of a symmetry-related five-membered ring with a distance of 3.8252 (12) Å. Differences between (2) and the reported polymorph [Miodragović et al. (2013). Angew. Chem. Int. Ed. 52, 10749–10752] are discussed.

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