scholarly journals Direct nanoscale mapping of open circuit voltages at local back surface fields for PERC solar cells

2020 ◽  
Vol 55 (25) ◽  
pp. 11501-11511
Author(s):  
Alexandra Longacre ◽  
Michael Martin ◽  
Thomas Moran ◽  
Oleg V. Kolosov ◽  
Eric Schneller ◽  
...  
Author(s):  
Alexandra Longacre ◽  
Kristopher O. Davis ◽  
Jennifer L. Braid ◽  
Roger H. French ◽  
Bryan D. Huey ◽  
...  

1999 ◽  
Vol 581 ◽  
Author(s):  
Doug Schulz ◽  
R. Ribelin ◽  
X. Wu ◽  
K.M. Jones ◽  
R.J. Matson ◽  
...  

ABSTRACTNano-sized dispersions have been employed as precursor inks for the spray deposition of contacts to both Si and CdTe materials. In the case of Si, nano-sized Al particles (nano-Al) were dispersed and spray deposited onto p-type Si. Annealing above the eutectic temperature causes alloy formation yielding a p+ layer with p ∼ 10−4 Ω•cm. For CdTe, nano-sized Te particles (nano-Te) were dispersed and sprayed onto CdTe/CdS/SnO2/glass heterostructures. Contact to the CdTe layer occurred during a 30 min anneal in He (T = 215 to 255 °C). These solar cells were finished by spin-coating the Te layer with Ag paint and subsequently annealing in air (100 °C / 1 h). This approach produces solar cells with open circuit voltages (Voc) from 720 to 800 mV, short circuit current densities (Jsc) from 18 to 20 mA/cm2 and efficiencies up to 10.3%. The performance of these cells was similar to those produced using the standard NREL contact.


Author(s):  
James P. Connolly

The analytical modelling of bulk and quantum well solar cells is reviewed. The analytical approach allows explicit estimates of dominant generation and recombination mechanisms at work in charge neutral and space charge layers of the cells. Consistency of the analysis of cell characteristics in the light and in the dark leaves a single free parameter, which is the mean Shockley-Read-Hall lifetime. Bulk PIN cells are shown to be inherently dominated by non-radiative recombination as a result of the doping related non-radiative fraction of the Shockley injection currents. Quantum well PIN solar cells on the other hand are shown to operate in the radiative limit as a result of the dominance of radiative recombination in the space charge region. These features are exploited using light trapping techniques leading to photon recycling and reduced radiative recombination. The conclusion is that the mirror backed quantum well solar cell device features open circuit voltages determined mainly by the higher bandgap neutral layers, with an absorption threshold determined by the lower gap quantum well superlattice.


2018 ◽  
Vol 6 (39) ◽  
pp. 19190-19200 ◽  
Author(s):  
Mary Allison Kelly ◽  
Qianqian Zhang ◽  
Zhengxing Peng ◽  
Victoria Noman ◽  
Chenhui Zhu ◽  
...  

Comparing the efficiency of terpolymers vs. ternary blends, this study focuses on two polymers with structurally similar backbones (monoCNTAZ and FTAZ) yet markedly different open circuit voltages.


2019 ◽  
Vol 7 (7) ◽  
pp. 3307-3316 ◽  
Author(s):  
Qisheng Tu ◽  
Changquan Tang ◽  
Qingdong Zheng

Novel wide-bandgap copolymers based on ladder-type dithienocyclopentadibenzothiophene were developed for polymer solar cells with 9.46% efficiency and excellent stability.


2012 ◽  
Vol 3 (2) ◽  
pp. 220-230 ◽  
Author(s):  
Eric T. Hoke ◽  
Koen Vandewal ◽  
Jonathan A. Bartelt ◽  
William R. Mateker ◽  
Jessica D. Douglas ◽  
...  

2012 ◽  
Vol 472-475 ◽  
pp. 1846-1850
Author(s):  
Shan Shan Dai ◽  
Gao Jie Zhang ◽  
Xiang Dong Luo ◽  
Jing Xiao Wang ◽  
Wen Jun Chen ◽  
...  

In this work, the effect of aluminum back surface field formed by screen printed various amount of Al paste on the effective rear surface recombination velocity (Seff) and the internal rear reflectance coeffeicient (Rb) of commercial mono-silicon solar cells was investigated. We demonstrated the effect of Seffand Rbon the performance of Al-BSF solar cells by simulating them with PC1D. The simulated results showed that the lower Seffcould get higher open circuit voltage (Voc), at the same time, the larger Rbcould get higher short-circuit current (Isc). Experimentally, we investigated the Seffand Rbthrough depositing Al paste with various amount (3.7, 5, 6, and 8 mg/cm2) for fabricating Al-BSF mono-silicon solar cells. Four group cells were characterized by light I-V, spectral response, hemispherical reflectance and scanning electron microscope (SEM) measurements. It was found that, a minimum Seffof 350 cm/s was gotten from the cells with Al paste of 8 mg/cm2, which was extracted by matching quantum efficiency (QE) from 800 nm to 1200 nm with PC1D, and a maximum Rbof 53.5% was obtained from Al paste of 5 mg/cm2by calculating at 1105 nm with PC1D. When the amount of Al paste was higher than 5mg/cm2, there were less Seffand lower Rb. On the other hand, when Al amount was 3.7mg/cm2, it was too little to form a closed BSF. Based on the SEM graphs and simulations with PC1D, a simple explaination was proposed for the experimental results.


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