Inversion of seismic intensity data for the determination of three-dimensional attenuation structures in the central gap region of Himalayas

2007 ◽  
Vol 43 (1) ◽  
pp. 1-22 ◽  
Author(s):  
A. Joshi

The crystal structure of ammonium oxamate (CONH 2 .COONH 4 ) has been studied using Cu Ka X-radiation, by means of a three-circle diffractometer incorporating a xenon-filled proportional counter. Accurate three-dimensional intensity data were collected and a least-squares refinement was carried out. The positions of the hydrogen atoms were obtained and refined. A peak of electron density, about half as high as a hydrogen atom, was observed at the centre of the C—C bond and a correction applied for it increased the length of the bond by 0.003 Å. The bond lengths were corrected for librational motion, and the values obtained are C—C =1.564 ±0.002 Å; C—N = 1.324± 0.002 Å; C—O (amidic) = 1.248± 0.002 A; C— O (carboxylate) = 1.257 + 0.003 Å and 1.256 ± 0.003 Å. The oxamate ion is found to be planar, and the ammonium ion tetrahedral. The length of the C—C bond is greater than any theoretical value yet suggested for the length of a single bond between trigonally hybridized carbons atoms.


2021 ◽  
Vol 24 (2) ◽  
pp. 24-36
Author(s):  
Serhii A. Palkov ◽  
◽  
Ihor A. Palkov ◽  

An algorithm to confirm the seismic resistance of equipment by a calculation method is proposed, and the limits of its application are determined. A mathematical model of the equipment is developed, and an example of the determination of natural frequencies and stresses for a three-dimensional structure is given. Two main types of calculation were used – static and dynamic. In the static calculation, the stress-strain state of a structure was determined. The values of the obtained stresses were compared with the allowable ones for the materials used, on the basis of which conclusions were made about the strength of the structure under seismic effects. The dynamic calculation resulted in the determination of the rigidity of the structure. The comparison of the stress values obtained for this equipment allowed us to make a conclusion regarding its resistance to seismic effects. The seismic resistance of the equipment was estimated on the example of the K-1000-60 / 1500 steam turbine condenser, and calculated at a seismic intensity of 6 points on the MSK-64 seismic intensity scale. In the course of solving this problem, results of the stress distribution in the housing and other structural elements of the condenser due to the action of combined normal operation and design-basis seismic loads were obtained. The seismic resistance of the equipment was calculated using the finite element method. This allowed us to present a solid body in the form of a set of individual finite elements that interact with each other in a finite number of nodal points. To these points are applied some interaction forces that characterize the influence of the distributed internal stresses applied along the real boundaries of adjacent elements. To perform such a calculation in CAD modeling software, a three-dimensional model was created. The obtained geometric model was imported into the software package, which significantly reduced complexity. The use of the calculation method allows us to significantly reduce the amount of testing when confirming the seismic resistance of equipment. Results of the assessment of the spatial complex stress state of the steam turbine condenser design due to the action of combined normal operation and design-basis seismic loads are obtained.


1997 ◽  
Vol 40 (1) ◽  
Author(s):  
G. N. Stavrakakis ◽  
G. Drakatos ◽  
G. Karantonis ◽  
D. Papanastassiou

The three-dimensional attenuation structure beneath the Aegean sea and the surrounding regions was determined by inversion of seismic intensity data. A large number of seismic intensity data have been accumulated in a uniform scale in the Aegean region, where the seismic activity is much higher than that of the other Mediterranean regions. Nearly 11000 seismic intensity data from 47 earthquakes that have occurred in these regions were used to determine the seismic attenuation structure. The resulting structure reveals a remarkable contrast of attenuation. In the top layer (depth 0-20 km), low Q is dominant in the central Aegean sea, while high Q is dominant in the surrounding land areas, except for Southwestern Turkey. The low-Q regions correspond to areas of Neogene-Quaternary grabens where the high seismicity of shallow earthquakes appears. In the lower layer (20-40 km) low-Q areas are located in the southeastern part of the Hellenic arc. Some low-Q spots corresponding to the distribution of volcanoes exist along the volcanic arc. The low-Q spots might correspond to diapirs causing subduction volcanism.


Author(s):  
M. Boublik ◽  
W. Hellmann ◽  
F. Jenkins

The present knowledge of the three-dimensional structure of ribosomes is far too limited to enable a complete understanding of the various roles which ribosomes play in protein biosynthesis. The spatial arrangement of proteins and ribonuclec acids in ribosomes can be analysed in many ways. Determination of binding sites for individual proteins on ribonuclec acid and locations of the mutual positions of proteins on the ribosome using labeling with fluorescent dyes, cross-linking reagents, neutron-diffraction or antibodies against ribosomal proteins seem to be most successful approaches. Structure and function of ribosomes can be correlated be depleting the complete ribosomes of some proteins to the functionally inactive core and by subsequent partial reconstitution in order to regain active ribosomal particles.


Author(s):  
Douglas L. Dorset

The quantitative use of electron diffraction intensity data for the determination of crystal structures represents the pioneering achievement in the electron crystallography of organic molecules, an effort largely begun by B. K. Vainshtein and his co-workers. However, despite numerous representative structure analyses yielding results consistent with X-ray determination, this entire effort was viewed with considerable mistrust by many crystallographers. This was no doubt due to the rather high crystallographic R-factors reported for some structures and, more importantly, the failure to convince many skeptics that the measured intensity data were adequate for ab initio structure determinations.We have recently demonstrated the utility of these data sets for structure analyses by direct phase determination based on the probabilistic estimate of three- and four-phase structure invariant sums. Examples include the structure of diketopiperazine using Vainshtein's 3D data, a similar 3D analysis of the room temperature structure of thiourea, and a zonal determination of the urea structure, the latter also based on data collected by the Moscow group.


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