Diacetone alcohol decomposition and benzaldehyde Cannizzaro reaction as test reactions for the basic strength measurements of alumina, magnesia, Amberlyst type resins (A-15, XN 1010, A-26, A-21), Nafion NR 50 and solid sulfuric acid

Marek Marczewski; Yuliya Kavalchuk; Urszula Ulkowska; Marek Gliński; Osazuwa Osawaru

doi:10.1007/s11144-018-1492-z

Diacetone alcohol decomposition and benzaldehyde Cannizzaro reaction as test reactions for the basic strength measurements of alumina, magnesia, Amberlyst type resins (A-15, XN 1010, A-26, A-21), Nafion NR 50 and solid sulfuric acid

Reaction Kinetics Mechanisms and Catalysis ◽

10.1007/s11144-018-1492-z ◽

2018 ◽

Vol 126 (1) ◽

pp. 199-217 ◽

Cited By ~ 1

Author(s):

Marek Marczewski ◽

Yuliya Kavalchuk ◽

Urszula Ulkowska ◽

Marek Gliński ◽

Osazuwa Osawaru

Keyword(s):

Sulfuric Acid ◽

Diacetone Alcohol ◽

Cannizzaro Reaction ◽

Test Reactions ◽

Basic Strength

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PROCEDURE FOR THE SEPARATION, DETECTION, AND IDENTIFICATION OF THE MORE COMMON VEGETABLE GUMS IN DAIRY PRODUCTS, WITH SPECIAL REFERENCE TO ALGINATES

Journal of Milk and Food Technology ◽

10.4315/0022-2747-17.3.79 ◽

1954 ◽

Vol 17 (3) ◽

pp. 79-105 ◽

Cited By ~ 11

Author(s):

Herman N. Bundesen ◽

Mathew J. Martinek

Keyword(s):

Sulfuric Acid ◽

Special Reference ◽

Magnesium Sulphate ◽

Dairy Products ◽

Saturated Solution ◽

Color Reaction ◽

Detection And Identification ◽

Test Reactions ◽

Acid Reagent

A procedure is presented for detecting the more common vegetable gums in dairy products. Alginates are separated, in the presence of other gums, by precipitation as algenic acid and redissolving from the protein precipitate with a saturated solution of magnesium sulphate. Alginates are identified by their color reaction with ferric sulfuric acid reagent. The characteristics and test reactions to aid in the detection and differentiation of other gums are given. The various gums can be idenitied in concentrations as low as 0.1 gram per 100 grams of product.

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Isopropylidenation of L-arabinose N,N-dimethylhydrazone

Collection of Czechoslovak Chemical Communications ◽

10.1135/cccc19851994 ◽

1985 ◽

Vol 50 (9) ◽

pp. 1994-1999 ◽

Cited By ~ 3

Author(s):

Miroslav Koóš ◽

Harry S. Mosher

Keyword(s):

Sulfuric Acid ◽

High Yield ◽

Cannizzaro Reaction ◽

Branched Chain

Direct isopropylidenation of L-arabinose N,N-dimethylhydrazone (I) was studied. Four major products whose structures were proven were produced in varying ratios depending upon the conditions. 2,2-Dimethoxypropane and sulfuric acid at 20 °C gave a 36% yield of 2,3:4,5-di-O-isopropylidene-L-arabinose N,N-dimethylhydrazone (II). Attempted aldol condensations directly on this hydrazone with paraformaldehyde were unsuccessful. This hydrazone was readily hydrolyzed to the corresponding protected aldehyde VI which underwent an aldol-Cannizzaro reaction to give the branched chain pentitol VII in high yield.

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Preparation of Thin Cadmium Telluride Samples for Electron Microscope Studies

Proceedings, annual meeting, Electron Microscopy Society of America ◽

10.1017/s0424820100052754 ◽

1974 ◽

Vol 32 ◽

pp. 548-549

Author(s):

T. J. Magee ◽

J. Peng ◽

J. Bean

Keyword(s):

Electron Microscope ◽

Sulfuric Acid ◽

Solid State ◽

Sample Preparation ◽

Cadmium Telluride ◽

Potassium Dichromate ◽

Optical Components ◽

The Past ◽

Solid State Devices

Cadmium telluride has become increasingly important in a number of technological applications, particularly in the area of laser-optical components and solid state devices, Microstructural characterizations of the material have in the past been somewhat limited because of the lack of suitable sample preparation and thinning techniques. Utilizing a modified jet thinning apparatus and a potassium dichromate-sulfuric acid thinning solution, a procedure has now been developed for obtaining thin contamination-free samples for TEM examination.

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Physical, Chemical, and Crystallographic Characterization of Anodic Coatings on High Strength Aluminum Base Alloys

Proceedings, annual meeting, Electron Microscopy Society of America ◽

10.1017/s0424820100093146 ◽

1976 ◽

Vol 34 ◽

pp. 636-637

Author(s):

R. E. Herfert ◽

N. T. McDevitt

Keyword(s):

Sulfuric Acid ◽

Salt Spray ◽

High Strength ◽

Environmental Stability ◽

Anodic Films ◽

Sodium Dichromate ◽

Corrosion Resistant ◽

Aerospace Applications ◽

Bond Strengths ◽

Adhesive Bonded Joints

Durability of adhesive bonded joints in moisture and salt spray environments is essential to USAF aircraft. Structural bonding technology for aerospace applications has depended for many years on the preparation of aluminum surfaces by a sulfuric acid/sodium dichromate (FPL etch) treatment. Recently, specific thin film anodizing techniques, phosphoric acid, and chromic acid anodizing have been developed which not only provide good initial bond strengths but vastly improved environmental durability. These thin anodic films are in contrast to the commonly used thick anodic films such as the sulfuric acid or "hard" sulfuric acid anodic films which are highly corrosion resistant in themselves, but which do not provide good initial bond strengths, particularly in low temperature peel.The objective of this study was to determine the characteristics of anodic films on aluminum alloys that make them corrosion resistant. The chemical composition, physical morphology and structure, and mechanical properties of the thin oxide films were to be defined and correlated with the environmental stability of these surfaces in humidity and salt spray. It is anticipated that anodic film characteristics and corrosion resistance will vary with the anodizing processing conditions.

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