Flower-like Li0.36V6O13 with superior cycling stability as a cathode material for lithium-ion batteries

Ionics ◽  
2019 ◽  
Vol 26 (3) ◽  
pp. 1181-1187
Author(s):  
Ting-ting Lv ◽  
Zheng-guang Zou ◽  
Yan-wei Li ◽  
Shu-chao Zhang
2020 ◽  
Vol 44 (7) ◽  
pp. 3004-3011
Author(s):  
Wei Shi ◽  
Jian Guo

Fe3O4@starch-derived carbon composites (Fe3O4@C-SD composites) were produced via chemical bowling, an economic and a scalable method, and a subsequent calcination with starch as the carbon resource and iron(iii) nitrate as the iron resource.


Materials ◽  
2021 ◽  
Vol 14 (16) ◽  
pp. 4751
Author(s):  
Lian-Bang Wang ◽  
He-Shan Hu ◽  
Wei Lin ◽  
Qing-Hong Xu ◽  
Jia-Dong Gong ◽  
...  

Lithium-rich manganese oxide is a promising candidate for the next-generation cathode material of lithium-ion batteries because of its low cost and high specific capacity. Herein, a series of xLi2MnO3·(1 − x)LiMnO2 nanocomposites were designed via an ingenious one-step dynamic hydrothermal route. A high concentration of alkaline solution, intense hydrothermal conditions, and stirring were used to obtain nanoparticles with a large surface area and uniform dispersity. The experimental results demonstrate that 0.072Li2MnO3·0.928LiMnO2 nanoparticles exhibit a desirable electrochemical performance and deliver a high capacity of 196.4 mAh g−1 at 0.1 C. This capacity was maintained at 190.5 mAh g−1 with a retention rate of 97.0% by the 50th cycle, which demonstrates the excellent cycling stability. Furthermore, XRD characterization of the cycled electrode indicates that the Li2MnO3 phase of the composite is inert, even under a high potential (4.8 V), which is in contrast with most previous reports of lithium-rich materials. The inertness of Li2MnO3 is attributed to its high crystallinity and few structural defects, which make it difficult to activate. Hence, the final products demonstrate a favorable electrochemical performance with appropriate proportions of two phases in the composite, as high contents of inert Li2MnO3 lower the capacity, while a sufficient structural stability cannot be achieved with low contents. The findings indicate that controlling the composition through a dynamic hydrothermal route is an effective strategy for developing a Mn-based cathode material for lithium-ion batteries.


2013 ◽  
Vol 39 (3) ◽  
pp. 3087-3094 ◽  
Author(s):  
Yan-Rong Zhu ◽  
Ting-Feng Yi ◽  
Rong-Sun Zhu ◽  
An-Na Zhou

RSC Advances ◽  
2017 ◽  
Vol 7 (55) ◽  
pp. 34442-34447 ◽  
Author(s):  
Liuqing Li ◽  
Haiyan Zhang ◽  
Zhaopeng Li ◽  
Weihao Zhong ◽  
Haiyang Liao ◽  
...  

SnO2/C nanospheres (∼500 nm) with ultrasmall SnO2 particles of 4 nm are prepared by using triphenyltin chloride as building blocks. The SnO2/C nanospheres show high lithium storage capacity and superior cycling stability.


Materials ◽  
2017 ◽  
Vol 10 (8) ◽  
pp. 859 ◽  
Author(s):  
Shanshan Liu ◽  
Hongyuan Zhao ◽  
Ming Tan ◽  
Youzuo Hu ◽  
Xiaohui Shu ◽  
...  

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