Corrosion Behavior of Fe-7Cr-1Mo-12Zr Metal Waste Form Alloy in Simulated Repository Environment

2019 ◽  
Vol 28 (9) ◽  
pp. 5902-5912
Author(s):  
R. Priya ◽  
S. Ningshen
1999 ◽  
Vol 608 ◽  
Author(s):  
S. G. Johnson ◽  
D. D. Keiser ◽  
S. M. Frank ◽  
T. DiSanto ◽  
A. R. Warren ◽  
...  

2013 ◽  
Vol 441 (1-3) ◽  
pp. 103-112 ◽  
Author(s):  
Jarrod V. Crum ◽  
Denis Strachan ◽  
Aashish Rohatgi ◽  
Mac Zumhoff

1998 ◽  
Vol 4 (S2) ◽  
pp. 560-561
Author(s):  
Edgar C. Buck

Secondary phases that form during the corrosion of nuclear waste forms may influence both the rate of waste form dissolution and the release of radionuclides [1]. The identification of these phases is critical in developing models for the corrosion behavior of nuclear waste forms. In particular, the secondary uranyl (VI) minerals that form during waste form alteration may control uranium solubility and release of radionuclides incorporated into these phases [2].The U6+ cation in uranyl minerals is almost always present as a linear (UO2)2+ ion [3]. This uranyl (Ur) ion is coordinated by four, five, or six anions (ϕ) in the equatorial plane resulting in the formation of square (Urϕ4), pentagonal (Urϕ5), and hexagonal (Urϕ6) bipyramids, respectively [3]. These bipyramid polyhedra may polymerize to form complex infinite sheet structures. The linking of Urϕ5 is observed in a number of uranyl minerals formed during waste glass and spent fuel corrosion [2,4], such as weeksite [Na,K(UO2)2(Si205)3*4H2O] and β-uranophane [Ca[(UO2)(SiO3OH)]2*5H2O].


2010 ◽  
Vol 52 (7) ◽  
pp. 2291-2302 ◽  
Author(s):  
Lipika Rani Bairi ◽  
S. Ningshen ◽  
U. Kamachi Mudali ◽  
Baldev Raj

2016 ◽  
Vol 482 ◽  
pp. 1-11 ◽  
Author(s):  
Jarrod V. Crum ◽  
James J. Neeway ◽  
Brian J. Riley ◽  
Zihua Zhu ◽  
Matthew J. Olszta ◽  
...  

Author(s):  
Masamichi Obata ◽  
Nobuhito Ogaki ◽  
Hironori Takabayashi ◽  
Yasushi Ooishi ◽  
Taichi Horimoto

High dose rate metal waste from core internals, such as BWR channel boxes or control rods are stored in fuel pool or site bunker pool. Waste form for final disposal of these high dose rate metal wastes should eliminate water to prevent hydrogen gas which can be caused by radiolysis of water. Toshiba’s newly developed drying system for high dose rate metal wastes enable short drying time and easy maintenance. Toshiba will provide the total system to fabricate the waste form for high dose rate metal wastes.


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