Organic phase enzyme electrodes

1991 ◽  
Vol 249 (1) ◽  
pp. 1-15 ◽  
Author(s):  
Selwayan Saini ◽  
Geoffrey F Hall ◽  
Mark E.A Downs ◽  
Anthony P.F Turner
Keyword(s):  
Organic Phase ◽  
Enzyme Electrodes

Organic phase enzyme electrodes: applications and theoretical studies

2001 ◽  
Vol 426 (2) ◽  
pp. 235-247 ◽  
Author(s):  
L Campanella ◽  
G Favero ◽  
L Persi ◽  
M.P Sammartino ◽  
M Tomassetti ◽  
...  
Keyword(s):  
Organic Phase ◽  
Theoretical Studies ◽  
Enzyme Electrodes

Organic phase enzyme electrodes: kinetics and analytical applications

1997 ◽  
Vol 12 (1) ◽  
pp. 53-75 ◽  
Author(s):  
Emmanuel I. Iwuoha ◽  
Malcolm R. Smyth ◽  
Michael E.G. Lyons
Keyword(s):  
Organic Phase ◽  
Enzyme Electrodes ◽  
Analytical Applications

Organic phase enzyme electrodes for the determination of hydrogen peroxide and phenol

1992 ◽  
Vol 7 (1-3) ◽  
pp. 408-411 ◽  
Author(s):  
Florian Schubert ◽  
Selwayan Saini ◽  
Anthony P.F. Turner ◽  
Frieder Scheller
Keyword(s):  
Hydrogen Peroxide ◽  
Organic Phase ◽  
Enzyme Electrodes

Organic phase enzyme electrodes

2006 ◽  
Vol 23 (4) ◽  
pp. 135-147 ◽  
Author(s):  
M. Sánchez-Paniagua López ◽  
E. López-Cabarcos ◽  
B. López-Ruiz
Keyword(s):  
Organic Phase ◽  
Enzyme Electrodes

Two OPEEs (organic phase enzyme electrodes) used to check the percentage water content in hydrophobic foods and drugs

The Analyst ◽  
2001 ◽  
Vol 126 (11) ◽  
pp. 1923-1928 ◽  
Author(s):  
L. Campanella ◽  
G. De Santis ◽  
G. Favero ◽  
M. P. Sammartino ◽  
M. Tomassetti
Keyword(s):  
Water Content ◽  
Organic Phase ◽  
Enzyme Electrodes ◽  
Percentage Water Content

Analysis of several real matrices using new mono-, bi-enzymatic, or inhibition organic phase enzyme electrodes

1999 ◽  
Vol 393 (1-3) ◽  
pp. 109-120 ◽  
Author(s):  
L. Campanella ◽  
G. Favero ◽  
M.P. Sammartino ◽  
M. Tomassetti
Keyword(s):  
Organic Phase ◽  
Enzyme Electrodes ◽  
Real Matrices

Organic Phase Enzyme Electrodes Based on Organohydrogel

1997 ◽  
Vol 69 (10) ◽  
pp. 1904-1908 ◽  
Author(s):  
Yizhu Guo ◽  
Shaojun Dong
Keyword(s):  
Organic Phase ◽  
Enzyme Electrodes

Three-Phase Electrochemistry of a Highly Lipophilic Neutral Ru-Complex Having a Tridentate Bis(benzimidazolate)pyridine Ligand

2020 ◽  
Author(s):  
Vishwanath R.S ◽  
Masa-aki Haga ◽  
Takumi Watanabe ◽  
Emilia Witkowska Nery ◽  
Martin Jönsson-Niedziolka
Keyword(s):  
Redox Potential ◽  
Organic Phase ◽  
Electron Donor ◽  
Ion Transfer ◽  
Neutral Complex ◽  
Pyridine Ligand ◽  
Electrochemical Testing ◽  
Ru Complex ◽  
Three Phase ◽  
Exceptional Stability

Here we describe the synthesis and electrochemical testing of a heteroleptic bis(tridentate) ruthenium(II) complex [Ru<sup>II</sup>(LR)(L)]<sup>0</sup> (LR =2,6-bis(1-(2-octyldodecan)benzimidazol-2-yl)pyridine, L = 2,6-bis(benzimidazolate)pyridine). It is a neutral complex which undergoes a quasireversible oxidation and reduction at relatively low potential. The newly synthetized compound was used for studies of ion-transfer at the three-phase junction because of the sensitivity of this method to cation expulsion. The [Ru<sup>II</sup>(LR)(L)]<sup>0</sup> shows exceptional stability during cycling and is sufficiently lipophilic even after oxidation to persist in the organic phase also using very hydrophilic anions such as Cl<sup>−</sup>. Given its low redox potential and strong lipophilicity this compound will be of interest as an electron donor in liquid-liquid electrochemistry.

Three-Phase Electrochemistry of a Highly Lipophilic Neutral Ru-Complex Having a Tridentate Bis(benzimidazolate)pyridine Ligand

2020 ◽  
Author(s):  
Vishwanath R.S ◽  
Masa-aki Haga ◽  
Takumi Watanabe ◽  
Emilia Witkowska Nery ◽  
Martin Jönsson-Niedziolka
Keyword(s):  
Redox Potential ◽  
Organic Phase ◽  
Electron Donor ◽  
Ion Transfer ◽  
Neutral Complex ◽  
Pyridine Ligand ◽  
Electrochemical Testing ◽  
Ru Complex ◽  
Three Phase ◽  
Exceptional Stability

Here we describe the synthesis and electrochemical testing of a heteroleptic bis(tridentate) ruthenium(II) complex [Ru<sup>II</sup>(LR)(L)]<sup>0</sup> (LR =2,6-bis(1-(2-octyldodecan)benzimidazol-2-yl)pyridine, L = 2,6-bis(benzimidazolate)pyridine). It is a neutral complex which undergoes a quasireversible oxidation and reduction at relatively low potential. The newly synthetized compound was used for studies of ion-transfer at the three-phase junction because of the sensitivity of this method to cation expulsion. The [Ru<sup>II</sup>(LR)(L)]<sup>0</sup> shows exceptional stability during cycling and is sufficiently lipophilic even after oxidation to persist in the organic phase also using very hydrophilic anions such as Cl<sup>−</sup>. Given its low redox potential and strong lipophilicity this compound will be of interest as an electron donor in liquid-liquid electrochemistry.

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