Conformational study of allyl fluoride, allyl alcohol and allyl amine through the matrix-isolation technique

1973 ◽  
Vol 18 (4) ◽  
pp. 561-562 ◽  
Author(s):  
B. Silvi ◽  
F. Froment ◽  
J. Corset ◽  
J.P. Perchard
Keyword(s):  
Allyl Alcohol ◽  
Matrix Isolation ◽  
Conformational Study ◽  
Isolation Technique ◽  
The Matrix ◽  
Allyl Amine

Direct observation, by the matrix isolation technique, of nitric oxide effects in low-pressure silane discharges

1988 ◽  
Vol 127 (1-3) ◽  
pp. 385-392 ◽  
Author(s):  
L. Abouaf-marguin ◽  
A. Lloret ◽  
M. Oria ◽  
B. Seoudi
Keyword(s):  
Nitric Oxide ◽  
Direct Observation ◽  
Matrix Isolation ◽  
Low Pressure ◽  
Isolation Technique ◽  
The Matrix

Krypton Fluoride: Preparation by the Matrix Isolation Technique

Science ◽  
1963 ◽  
Vol 140 (3570) ◽  
pp. 974-975
Author(s):  
J. J. Turner ◽  
George C. Pimentel
Keyword(s):  
Matrix Isolation ◽  
Krypton Fluoride ◽  
Isolation Technique ◽  
The Matrix

Infrared Studies of Hydrogen Bonding of Water by the Matrix Isolation Technique

1957 ◽  
Vol 27 (2) ◽  
pp. 486-490 ◽  
Author(s):  
Mathias Van Thiel ◽  
Edwin D. Becker ◽  
George C. Pimentel
Keyword(s):  
Hydrogen Bonding ◽  
Matrix Isolation ◽  
Isolation Technique ◽  
Infrared Studies ◽  
The Matrix

Infrared Studies of Dimethylsilylamine and Methyldisilylamine by the Matrix‐Isolation Technique

1967 ◽  
Vol 46 (9) ◽  
pp. 3384-3388 ◽  
Author(s):  
Theodore D. Goldfarb ◽  
Bishun N. Khare
Keyword(s):  
Matrix Isolation ◽  
Isolation Technique ◽  
Infrared Studies ◽  
The Matrix

Infrared Studies of Hydrogen Bonding of Methanol by the Matrix Isolation Technique

1957 ◽  
Vol 27 (1) ◽  
pp. 95-99 ◽  
Author(s):  
Matthias Van Thiel ◽  
Edwin D. Becker ◽  
George C. Pimentel
Keyword(s):  
Hydrogen Bonding ◽  
Matrix Isolation ◽  
Isolation Technique ◽  
Infrared Studies ◽  
The Matrix

Infrared detection by the matrix-isolation technique of radicals produced in deposition plasmas: germane

1991 ◽  
Vol 179 (4) ◽  
pp. 329-333 ◽  
Author(s):  
A. Lloret ◽  
M. Oria ◽  
B. Séoudi ◽  
L. Abouaf-Marguin
Keyword(s):  
Matrix Isolation ◽  
Infrared Detection ◽  
Isolation Technique ◽  
The Matrix

scholarly journals Identification of the early intermediates formed in ozonolysis of cis-2-butene and limonene: a theoretical and matrix isolation study

RSC Advances ◽  
2019 ◽  
Vol 9 (35) ◽  
pp. 20100-20106
Author(s):  
Shan-shan Li ◽  
Xiao-yang Yang ◽  
Yi-sheng Xu ◽  
Lei Jiang
Keyword(s):  
Quantum Chemical Calculations ◽  
Quantum Chemical ◽  
Matrix Isolation ◽  
Isolation Technique ◽  
The Matrix

This study combined quantum chemical calculations and the matrix isolation technique to identify the formation of primary intermediates from the ozonolysis of cis-2-butene and limonene.

Spectroscopy and Metal Atom Chemistry

1976 ◽  
Vol 30 (6) ◽  
pp. 573-586 ◽  
Author(s):  
Geoffrey A. Ozin
Keyword(s):  
Transition Metal ◽  
Metal Atom ◽  
Matrix Isolation ◽  
Metal Vapor ◽  
Alternative Methods ◽  
Isolation Technique ◽  
Metal Atoms ◽  
Transition Metal Atoms ◽  
The Matrix ◽  
Atom Chemistry

In the burgeoning field of cryochemistry, analytical spectroscopy has played an important role in helping us to understand the reactions of high temperature chemical species in low temperature condensation reactions. Reactions with transition metal atoms in particular have become an important synthetic method in inorganic and organometallic chemistry. Fascinating new compounds for which there are often no alternative methods of synthesis have been obtained by this technique. The potential importance of the work in terms of catalytic applications and chemical synthesis is very great indeed. Commercial evaporators and cryogenic equipment in compact and convenient forms are now commonly available and it will not be very long before metal vapor synthesis will enter the category of a routine laboratory procedure. Even at this early stage ICI (UK), duPont de Nemours (USA) and Merck (Germany) have initiated exploratory programs in metal vapor chemistry and it is only a matter of time before industrial evaporation plants are modified for large-scale metal vapor synthesis. As the field develops it is becoming increasingly evident that the seemingly unrelated methods of the preparative cryochemist and the matrix spectroscopist are intimately related. In areas such as reaction intermediates, product identification, reaction pathways, thermodynamics and kinetics, reaction feasibility and yields matrix and preparative cryochemistry cover much common ground. An intelligent marriage of the two techniques is proving to be most fruitful. In this survey lecture I will attempt to place in perspective some of the contributions that matrix isolation spectroscopy can make to the field of metal atom chemistry. In order to do this effectively in a 60-minute lecture I will restrict the reaction chemistry to that of Cu, Ag, and Au atoms. The areas to be described will include the controlled aggregation of transition metal atoms, the synthesis and characterization of coordinatively unsaturated transition metal molecular fragments and elusive binuclear compounds, and reaction kinetics using the matrix isolation technique.

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