Segregation and conformational transitions in triblock copolymers in dilute solution: 3. Viscometric investigations in solvent mixtures

Polymer ◽  
1975 ◽  
Vol 16 (10) ◽  
pp. 698-702 ◽  
Author(s):  
Anastasios Dondos ◽  
Paul Rempp ◽  
Henri Benoit
Keyword(s):  
Triblock Copolymers ◽  
Conformational Transitions ◽  
Solvent Mixtures ◽  
Dilute Solution

Oxyethylene-oxypropylene-oxyethylene triblock copolymers crystallised from dilute solution

1983 ◽  
Vol 19 (2) ◽  
pp. 107-114 ◽  
Author(s):  
Yun-Zhu Luo ◽  
R.B. Stubbersfield ◽  
C. Booth
Keyword(s):  
Triblock Copolymers ◽  
Dilute Solution

Dielectric Properties of Binary Solvent Mixtures

2020 ◽  
Author(s):  
Noritoshi Nambu
Keyword(s):  
Dominant Factor ◽  
Binary Solvent ◽  
Solvent Mixtures ◽  
Ideal Solution ◽  
Dilute Solution ◽  
Effective Dipole Moment ◽  
Straight Line ◽  
Kister Equation ◽  
Factor Governing ◽  
The Ideal

The relative permittivity is a measure of the solvent’s ability to insulate opposite charges from each other and has a very significant effect on the strength of the interactions between ions especially in dilute solution. I describe the relative permittivities, εr(sln) of nonaqueous mixtures as a function of the composition at 25 ºC. Experimental data were fitted with the Redlich-Kister equation. I explained the deviation from the ideal solution in terms of the magnitude of the coefficient a0. a0 is a dominant factor governing the Redlich-Kister equation. The decrease in a0 made a plot of εr(sln) vs. x2 close to a straight line, which corresponded to the ideal solution. The cohesive forces between dissimilar components resulted in the increased effective dipole moment and, consequently, in the small negative value of a0.

Triblock Copolymers in a Selective Solvent. 1. Aggregation Process in Dilute Solution

1994 ◽  
Vol 27 (11) ◽  
pp. 2956-2964 ◽  
Author(s):  
E. Raspaud ◽  
D. Lairez ◽  
M. Adam ◽  
J.-P. Carton
Keyword(s):  
Triblock Copolymers ◽  
Aggregation Process ◽  
Dilute Solution ◽  
Selective Solvent

Adsorption of di-and triblock copolymers with functionalized butadiene-styrene blocks from dilute solution

Polymer ◽  
1995 ◽  
Vol 36 (16) ◽  
pp. 3229-3233 ◽  
Author(s):  
D.F. Siqueira ◽  
M. Stamm ◽  
U. Breiner ◽  
R. Stadler
Keyword(s):  
Triblock Copolymers ◽  
Dilute Solution ◽  
Butadiene Styrene
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