Procedure for calibration of a coulometric system used for total inorganic carbon measurements of seawater

1992 ◽  
Vol 38 (1-2) ◽  
pp. 37-51 ◽  
Author(s):  
Catherine Goyet ◽  
Sally D Hacker
2018 ◽  
Vol 15 (16) ◽  
pp. 5221-5236 ◽  
Author(s):  
Thibaut Wagener ◽  
Nicolas Metzl ◽  
Mathieu Caffin ◽  
Jonathan Fin ◽  
Sandra Helias Nunige ◽  
...  

Abstract. The western tropical South Pacific was sampled along a longitudinal 4000 km transect (OUTPACE cruise, 18 February, 3 April 2015) for the measurement of carbonate parameters (total alkalinity and total inorganic carbon) between the Melanesian Archipelago (MA) and the western part of the South Pacific gyre (WGY). This paper reports this new dataset and derived properties: pH on the total scale (pHT) and the CaCO3 saturation state with respect to aragonite (Ωara). We also estimate anthropogenic carbon (CANT) distribution in the water column using the TrOCA method (Tracer combining Oxygen, inorganic Carbon and total Alkalinity). Along the OUTPACE transect a deeper penetration of CANT in the intermediate waters was observed in the MA, whereas highest CANT concentrations were detected in the subsurface waters of the WGY. By combining our OUTPACE dataset with data available in GLODAPv2 (1974–2009), temporal changes in oceanic inorganic carbon were evaluated. An increase of 1.3 to 1.6 µmol kg−1 a−1 for total inorganic carbon in the upper thermocline waters is estimated, whereas CANT increases by 1.1 to 1.2 µmol kg−1 a−1. In the MA intermediate waters (27 kg m−3 <σθ<27.2 kg m−3) an increase of 0.4 µmol kg−1 a−1 CANT is detected. Our results suggest a clear progression of ocean acidification in the western tropical South Pacific with a decrease in the oceanic pHT of up to −0.0027 a−1 and a shoaling of the saturation depth for aragonite of up to 200 m since the pre-industrial period.


1992 ◽  
Vol 109 (3-4) ◽  
pp. 383-390 ◽  
Author(s):  
Toshitaka Gamo ◽  
Hitoshi Sakai ◽  
Jun-ichiro Ishibashi ◽  
Kiminori Shitashima ◽  
Jacques Boulègue

2002 ◽  
Vol 18 (3) ◽  
pp. 247-253 ◽  
Author(s):  
Hideshi KIMOTO ◽  
Ken NOZAKI ◽  
Setsuko KUDO ◽  
Ken KATO ◽  
Akira NEGISHI ◽  
...  

2000 ◽  
Vol 83 (3) ◽  
pp. 584-587 ◽  
Author(s):  
Susan M Grimes ◽  
Helen C Ngwang

Abstract A photoreactor was developed to study products of photochemical oxidation in a wide range of organic compounds. Analysis of the products from the reactor were used to determine the extent of mineralization of the organic material, to characterize any intermediate compounds formed, and to obtain information on the decomposition mechanism. Appropriate methods for separation and characterization include LC, UV spectrophotometry, gas chromatography/mass spectrometry, total organic carbon, and total inorganic carbon. The uses of the reactor are described for the photocatalytic decomposition of phenol and of its major decomposition intermediates 1,2- and 1,4-dihydroxybenzene.


Radiocarbon ◽  
2013 ◽  
Vol 55 (3) ◽  
pp. 1790-1800
Author(s):  
C D Shen ◽  
W X Yi ◽  
P Ding ◽  
K X Liu ◽  
X M Xu

The concentrations of 10Be and 14C and values of δ13C in samples collected during a major dust storm in Beijing on 16–17 April 2006 were studied. The 10Be concentrations ranged from 1.69 × 108 to 2.07 × 108 atom/g, 14C ages for black carbon (BC) ranged from 3001 to 5181 yr BP and for total inorganic carbon (TIC) from 8464 to 9119 yr BP, and δ13C values for BC ranged from -23.15% to -23.80% and for TIC from -5.39% to -5.98%. A comparison of BC content and δ13C value between the dust, surface soil in the dust source region, and aerosols in Beijing indicated that BC in the dust deposited in Beijing is significantly incorporated by aerosol BC during the dust transportation. Based on the 14C ages of BC, the proportion of fossil-fuel-derived BC was 0.35–0.49 of the total. In contrast to BC, the TIC deposited in Beijing can be firmly related to the source area and δ13C was not significantly modified during its transportation. According to the 14C ages of TIC, the proportion of the secondary carbonate in the dust was from 0.63 to 0.70. The results confirm that 14C of TIC is another useful tracer to indicate the source region of dust besides the content and δ13C value of TIC from the arid and semi-arid regions of China.


2000 ◽  
Vol 14 (3) ◽  
pp. 979-994 ◽  
Author(s):  
Kitack Lee ◽  
Rik Wanninkhof ◽  
Richard A. Feely ◽  
Frank J. Millero ◽  
Tsung-Hung Peng

2008 ◽  
Vol 41 (2) ◽  
pp. 14582-14587 ◽  
Author(s):  
Giuliana Becerra-Celis ◽  
Sihem Tebbani ◽  
Claire Joannis-Cassan ◽  
Arsène Isambert ◽  
Patrick Boucher

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