Two-dimensional negative-temperature systems described by means of analytical solutions of the Poisson–Boltzmann equation are investigated. It is shown that two kinds of doubly periodic self-consistent structures can exist. The structures obtained confirm the prediction of equilibrium statistical mechanics that no spatially homogeneous thermal equilibrium state for negative-temperature systems exists. The structures investigated are similar to the two kinds of structures in a two-dimensional, two-component positive-temperature Coulomb gas but the location of the elements of the system within the region of the elementary cell of the structure is different. By means of the approach developed in this paper the parameters of the structures, the self-consistent potential, the corresponding charge density, and the energy of the negative-temperature structures can be calculated.