Mechanical reinforcement of room-temperature-vulcanized silicone rubber using modified cellulose nanocrystals as cross-linker and nanofiller

2020 ◽  
Vol 229 ◽  
pp. 115509 ◽  
Author(s):  
Xinxin Yang ◽  
Zhaoshuang Li ◽  
Zhaoyu Jiang ◽  
Siheng Wang ◽  
He Liu ◽  
...  
Keyword(s):  
Silicone Rubber ◽  
Cellulose Nanocrystals ◽  
Room Temperature ◽  
Mechanical Reinforcement ◽  
Cross Linker ◽  
Modified Cellulose

scholarly journals A novel crosslinking agent of polymethyl(ketoxime)siloxane for room temperature vulcanized silicone rubbers: synthesis, properties and thermal stability

RSC Advances ◽  
2018 ◽  
Vol 8 (23) ◽  
pp. 12517-12525 ◽  
Author(s):  
Xibing Zhan ◽  
Xiqing Cai ◽  
Junying Zhang
Keyword(s):  
Thermal Stability ◽  
Silicone Rubber ◽  
Room Temperature ◽  
Crosslinking Agent ◽  
Synthesis Properties ◽  
Cross Linker ◽  
Silicone Rubbers ◽  
Rtv Silicone Rubber

A novel cross-linker polymethyl(ketoxime)siloxane was synthesized and then was cured with hydroxyl-terminated polydimethylsiloxane matrix to fabricate a series of novel RTV silicone rubber. Their properties was comparatively investigated.

scholarly journals Synthesis and Characterization of Room Temperature Vulcanized Silicone Rubber Using Methoxyl-Capped MQ Silicone Resin as Self-Reinforced Cross-Linker

Polymers ◽  
2019 ◽  
Vol 11 (7) ◽  
pp. 1142 ◽  
Author(s):  
Jianye Ji ◽  
Xin Ge ◽  
Xiaoyan Pang ◽  
Ruoling Liu ◽  
Shuyi Wen ◽  
...  
Keyword(s):  
Silicone Rubber ◽  
Room Temperature ◽  
Degradation Rate ◽  
Light Transmission ◽  
Characteristic Temperature ◽  
Cross Linking ◽  
Silicone Resin ◽  
Cross Linker ◽  
Rtv Silicone Rubber

Methoxyl-capped MQ silicone resin (MMQ) was first synthesized by the hydrosilylation of vinyl-containing MQ silicone resin and trimethoxysilane and then used in condensed room-temperature vulcanized (RTV) silicone rubber as a self-reinforced cross-linker. Results show that modified silicone rubber exhibits good light transmission. Compared with unmodified silicone rubber, the hardness, tensile strength and elongation of MMQ at the break are increased by 26.4 A, 2.68 MPa and 65.1%, respectively. In addition, the characteristic temperature of 10% mass loss is delayed from 353.5 °C to 477.1 °C, the temperature at maximum degradation rate is also delayed from 408.9 °C to 528.4 °C and the residual mass left at 800 °C is increased from 1.2% to 27.7%. These improved properties are assigned to the synergistic effect of the rigid structure of MMQ, the formation of a dense cross-linking structure in polymers and the uniform distribution of MMQ cross-linking agent in RTV silicone rubber.

Octadecylamine as chemical modifier for tuned hydrophobicity of surface modified cellulose: toward organophilic cellulose nanocrystals

Cellulose ◽  
2021 ◽  
Author(s):  
Mohammed Majdoub ◽  
Younes Essamlali ◽  
Othmane Amadine ◽  
Ikram Ganetri ◽  
Anass Hafnaoui ◽  
...  
Keyword(s):  
Cellulose Nanocrystals ◽  
Chemical Modifier ◽  
Surface Modified ◽  
Modified Cellulose

scholarly journals Properties of Silicone Rubber-Based Composites Reinforced with Few-Layer Graphene and Iron Oxide or Titanium Dioxide

Polymers ◽  
2021 ◽  
Vol 13 (10) ◽  
pp. 1550
Author(s):  
Vineet Kumar ◽  
Anuj Kumar ◽  
Minseok Song ◽  
Dong-Joo Lee ◽  
Sung-Soo Han ◽  
...  
Keyword(s):  
Magnetic Properties ◽  
Titanium Dioxide ◽  
Iron Oxide ◽  
Stress Relaxation ◽  
Silicone Rubber ◽  
Room Temperature ◽  
Relaxation Rates ◽  
Layer Graphene ◽  
Few Layer Graphene ◽  
Mechanical Actuation

The increasing demand for polymer composites with novel or improved properties requires novel fillers. To meet the challenges posed, nanofillers such as graphene, carbon nanotubes, and titanium dioxide (TiO2) have been used. In the present work, few-layer graphene (FLG) and iron oxide (Fe3O4) or TiO2 were used as fillers in a room-temperature-vulcanized (RTV) silicone rubber (SR) matrix. Composites were prepared by mixing RTV-SR with nanofillers and then kept for vulcanization at room temperature for 24 h. The RTV-SR composites obtained were characterized with respect to their mechanical, actuation, and magnetic properties. Fourier-transform infrared spectroscopy (FTIR) analysis was performed to investigate the composite raw materials and finished composites, and X-ray photoelectron spectroscopy (XPS) analysis was used to study composite surface elemental compositions. Results showed that mechanical properties were improved by adding fillers, and actuation displacements were dependent on the type of nanofiller used and the applied voltage. Magnetic stress-relaxation also increased with filler amount and stress-relaxation rates decreased when a magnetic field was applied parallel to the deformation axes. Thus, this study showed that the inclusion of iron oxide (Fe3O4) or TiO2 fillers in RTV-SR improves mechanical, actuation, and magnetic properties.

scholarly journals Recyclable Self-Healing Polyurethane Cross-Linked by Alkyl Diselenide with Enhanced Mechanical Properties

Polymers ◽  
2019 ◽  
Vol 11 (5) ◽  
pp. 773 ◽  
Author(s):  
Yuqing Qian ◽  
Xiaowei An ◽  
Xiaofei Huang ◽  
Xiangqiang Pan ◽  
Jian Zhu ◽  
...  
Keyword(s):  
Mechanical Properties ◽  
Room Temperature ◽  
Amide Bond ◽  
Self Healing ◽  
Healing Efficiency ◽  
Polyurethane Networks ◽  
Combined Action ◽  
Cross Linker ◽  
Dynamic Structures ◽  
External Interventions

Dynamic structures containing polymers can behave as thermosets at room temperature while maintaining good mechanical properties, showing good reprocessability, repairability, and recyclability. In this work, alkyl diselenide is effectively used as a dynamic cross-linker for the design of self-healing poly(urea–urethane) elastomers, which show quantitative healing efficiency at room temperature, without the need for any catalysts or external interventions. Due to the combined action of the urea bond and amide bond, the material has better mechanical properties. We also compared the self-healing effect of alkyl diselenide-based polyurethanes and alkyl disulfide-based polyurethanes. The alkyl diselenide has been incorporated into polyurethane networks using a para-substituted amine diphenyl alkyl diselenide. The resulting materials not only exhibit faster self-healing properties than the corresponding disulfide-based materials, but also show the ability to be processed at temperatures as low as 60 °C.

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