Correlation between structural, electrical and electrochemical performance of Zn doped high voltage spinel LiNi0.5-xZnxMn1.5O4 porous microspheres as a cathode material for Li-Ion batteries

Author(s):  
V. Gajraj ◽  
R. Azmi ◽  
M.S.D. Darma ◽  
S. Indris ◽  
H. Ehrenberg ◽  
...  
MRS Advances ◽  
2018 ◽  
Vol 3 (60) ◽  
pp. 3513-3518 ◽  
Author(s):  
Taner Zerrin ◽  
Mihri Ozkan ◽  
Cengiz S. Ozkan

ABSTRACTIncreasing the operation voltage of LiCoO2 (LCO) is a direct way to enhance the energy density of the Li-ion batteries. However, at high voltages, the cycling stability degrades very fast due to the irreversible changes in the electrode structure, and formation of an unstable solid electrolyte interface layer. In this work, Ag thin film was prepared on commercial LCO cathode by using magnetron sputtering technique. Ag coated electrode enabled an improved electrochemical performance with a better cycling capability. After 100 cycles, Ag coated LCO delivers a discharge capacity of 106.3 mAh g-1 within 3 - 4.5 V at C/5, which is increased by 45 % compared to that of the uncoated LCO. Coating the electrode surface with Ag thin film also delivered an improved Coulombic efficiency, which is believed to be an indication of suppressed parasitic reactions at the electrode interface. This work may lead to new methods on surface modifications of LCO and other cathode materials to achieve high-capacity Li-ion batteries for high-voltage operations.


2015 ◽  
Vol 152 ◽  
pp. 496-504 ◽  
Author(s):  
Lu-Lu Zhang ◽  
Hua-Bin Sun ◽  
Xue-Lin Yang ◽  
Yan-Wei Wen ◽  
Yun-Hui Huang ◽  
...  

2017 ◽  
Vol 19 (15) ◽  
pp. 9983-9991 ◽  
Author(s):  
Feng Ma ◽  
Fushan Geng ◽  
Anbao Yuan ◽  
Jiaqiang Xu

The SnO2-modified LiNi0.5Mn1.5O4 high-voltage Li-ion cathode material exhibits superior electrochemical performance, and the synthetic method has the advantage of being facile.


2017 ◽  
Vol 5 (6) ◽  
pp. 2701-2709 ◽  
Author(s):  
Chang Su ◽  
Huihui He ◽  
Lihuan Xu ◽  
Kai Zhao ◽  
Chuncui Zheng ◽  
...  

A novel polytriphenylamine derivative has been prepared, which, as a cathode, exhibits a well-defined multistage discharge voltage plateau, an improved capacity and an enhanced rate performance.


2015 ◽  
Vol 3 (1) ◽  
pp. 404-411 ◽  
Author(s):  
Xuan-Wen Gao ◽  
Yuan-Fu Deng ◽  
David Wexler ◽  
Guo-Hua Chen ◽  
Shu-Lei Chou ◽  
...  

Conductive polypyrrole (PPy)-coated LiNi0.5Mn1.5O4(LNMO) composites are applied as cathode materials in Li-ion batteries, and their electrochemical properties are explored at both room and elevated temperature.


2015 ◽  
Vol 27 (7) ◽  
pp. 2600-2611 ◽  
Author(s):  
Prasant Kumar Nayak ◽  
Judith Grinblat ◽  
Mikhael D. Levi ◽  
Ortal Haik ◽  
Elena Levi ◽  
...  

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