Vapor–liquid equilibria for ethyl acetate+methanol and ethyl acetate+ethanol mixtures: Experimental verification and prediction

2014 ◽  
Vol 92 (12) ◽  
pp. 2861-2866 ◽  
Author(s):  
Cícero Sena Moreira Gomes ◽  
Humberto Neves Maia de Oliveira ◽  
Osvaldo Chiavone-Filho ◽  
Edson Luiz Foletto
Keyword(s):  
Ethyl Acetate ◽  
Experimental Verification ◽  
Vapor Liquid Equilibria ◽  
Vapor Liquid

Vapor-Liquid Equilibria for the Ternary System Ethyl Acetate-Acetonitrile-1-Octyl-3-Methylimidazolium Tetrafluoroborate

2013 ◽  
Vol 791-793 ◽  
pp. 141-144
Author(s):  
Xiu Min Shi ◽  
Min Wang
Keyword(s):  
Ionic Liquid ◽  
Ternary System ◽  
Ethyl Acetate ◽  
Mole Fraction ◽  
Salt Effect ◽  
Extractive Distillation ◽  
Relative Volatility ◽  
Azeotropic Point ◽  
Vapor Liquid Equilibria ◽  
Vapor Liquid

In order to research the possibility of separating the azeotrope of ethyl acetate + acetonitrile with ionic liquid as the extractant. Isobaric vapor-liquid equilibria for the ternary system ethyl acetate + acetonitrile + 1-octyl-3-methylimidazolium tetrafluoroborate ([OMIBF4) were measured at 101.32 kPa using a recirculation still. The results showed that the VLE of the ternary system was different from that of the binary system. The ionic liquid (IL) studied showed a slight crossover salt effect, which changed the relative volatility of ethyl acetate to acetonitrile and eliminated the azeotropic point when the mole fraction of IL in the liquid phase was greater than 0.05. Therefore, [OMIBF4 can be used as the extractant of extractive distillation for ethyl acetate + acetonitrile system, the suitable mole fraction of [OMIBF4 is about 10%.

Vapor-liquid equilibria of binary systems containing alcohols. Methanol-ethyl acetate and methanol-isopropyl ether

1967 ◽  
Vol 12 (3) ◽  
pp. 440-442 ◽  
Author(s):  
Koichiro Nakanishi ◽  
Koichi Nakasato ◽  
Ritsuji Toba ◽  
Hideko Shirai
Keyword(s):  
Ethyl Acetate ◽  
Binary Systems ◽  
Isopropyl Ether ◽  
Vapor Liquid Equilibria ◽  
Vapor Liquid

The isobaric vapor liquid equilibria of ethyl acetate + acetonitrile + bis(trifluoromethylsulfonyl)imide-based ionic liquids at 101.3 kPa

2016 ◽  
Vol 425 ◽  
pp. 289-296 ◽  
Author(s):  
Jiujuan Zhu ◽  
Qunsheng Li ◽  
Manman Li ◽  
Xiaoling Song ◽  
Hongjian Tang ◽  
...  
Keyword(s):  
Ionic Liquids ◽  
Ethyl Acetate ◽  
Vapor Liquid Equilibria ◽  
Vapor Liquid

Isothermal Vapor−Liquid Equilibria of Ethyl Acetate + Dibromomethane or + Bromochloromethane or + 1,2-Dichloroethane or +1-Bromo-2-chloroethane atT= 313.15 K

2004 ◽  
Vol 49 (6) ◽  
pp. 1574-1576 ◽  
Author(s):  
Pilar García-Giménez ◽  
Vanesa Gil-Hernández ◽  
Manuela Artal ◽  
José Muñoz Embid ◽  
Santos Otín
Keyword(s):  
Ethyl Acetate ◽  
Vapor Liquid Equilibria ◽  
Vapor Liquid

Isobaric Vapor-Liquid Equilibria of Hexamethyl Disiloxane + Ethyl Acetate System at Normal Pressure

2011 ◽  
Vol 396-398 ◽  
pp. 968-972
Author(s):  
Wen Lin Zhang ◽  
Nan Meng ◽  
Ru Yi Sun ◽  
Chun Li Li
Keyword(s):  
Experimental Data ◽  
Ethyl Acetate ◽  
Normal Pressure ◽  
Liquid Equilibrium ◽  
Vapor Liquid Equilibrium ◽  
Equilibrium Data ◽  
Vle Data ◽  
Vapor Liquid Equilibria ◽  
Ethyl Acetate System ◽  
Vapor Liquid

Vapor-liquid equilibrium data of hexamethyl disiloxane + ethyl acetate system at 101.3kPa were measured by using double circulating vapor-liquid equilibrium still. The thermodynamic consistency of the VLE data was examined by Herrington method. Experimental data was correlated by NRTL and UNIQUAC parameter models. Both of the models satisfactorily correlated with the VLE data. The result showed that the NRTL model was the most suitable one to represent experimental data satisfactorily and the system had a minimum temperature azeotrope at 350.31 K and the mole azeotropic composition was 0.0330.

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