Organic modifier induced interfacial transformation, morphology and physico-mechanical properties of PP/NR based blend nanocomposites

2020 ◽  
Vol 194 ◽  
pp. 108045 ◽  
Author(s):  
N. Chandran ◽  
C. Sarathchandran ◽  
S. Jose ◽  
S. Thankappan ◽  
S. Thomas
Polymers ◽  
2021 ◽  
Vol 13 (9) ◽  
pp. 1502
Author(s):  
Eliezer Velásquez ◽  
Sebastián Espinoza ◽  
Ximena Valenzuela ◽  
Luan Garrido ◽  
María José Galotto ◽  
...  

The deterioration of the physical–mechanical properties and loss of the chemical safety of plastics after consumption are topics of concern for food packaging applications. Incorporating nanoclays is an alternative to improve the performance of recycled plastics. However, properties and overall migration from polymer/clay nanocomposites to food require to be evaluated case-by-case. This work aimed to investigate the effect of organic modifier types of clays on the structural, thermal and mechanical properties and the overall migration of nanocomposites based on 50/50 virgin and recycled post-consumer polypropylene blend (VPP/RPP) and organoclays for food packaging applications. The clay with the most hydrophobic organic modifier caused higher thermal stability of the nanocomposites and greater intercalation of polypropylene between clay mineral layers but increased the overall migration to a fatty food simulant. This migration value was higher from the 50/50 VPP/RPP film than from VPP. Nonetheless, clays reduced the migration and even more when the clay had greater hydrophilicity because of lower interactions between the nanocomposite and the fatty simulant. Conversely, nanocomposites and VPP/RPP control films exhibited low migration values in the acid and non-acid food simulants. Regarding tensile parameters, elongation at break values of PP film significantly increased with RPP addition, but the incorporation of organoclays reduced its ductility to values closer to the VPP.


2021 ◽  
Vol 33 (10) ◽  
pp. 2287-2292
Author(s):  
K. Vijayashree ◽  
K. Sheshappa Rai

Insertion of metal-oxide nanoparticles to polymers stipulate the modification of physical properties of polymers over and above the accomplishment of new features in the polymer matrix. In the current study, an attempt was made to disperse the CuO nanoparticles in the polyvinyl alcohol and hydroxypropyl methylcellulose (HPMC) blend to investigate the structural, mechanical and optical properties of the nanocomposite. Blend was prepared in different ratios using PVA and HPMC, viz. 25:50, 50:50 and 75:25 wt%. The CuO nanoparticles were added to the 75:25 PVA:HPMC blend in different percentage like 0.5,1 and 1.5%. The polymer with and without CuO incorporation were subjected to X-ray diffraction, Fourier transform infrared spectroscopy, scanning electron microscopy, UV-visible spectral analyses and mechanical strength, etc. The results revealed that the incorporation of the CuO nanoparticles enhanced the structural and mechanical properties of the polymer by forming successful nanocomposite.


RSC Advances ◽  
2017 ◽  
Vol 7 (52) ◽  
pp. 32731-32731 ◽  
Author(s):  
Santosh Kr. Tiwari ◽  
Kartikey Verma ◽  
Pupulata Saren ◽  
Ramesh Oraon ◽  
Amrita De Adhikari ◽  
...  

Correction for ‘Manipulating selective dispersion of reduced graphene oxide in polycarbonate/nylon 66 based blend nanocomposites for improved thermo-mechanical properties’ by Santosh Kr. Tiwari et al., RSC Adv., 2017, 7, 22145–22155.


2007 ◽  
Vol 56 (5) ◽  
pp. 686-693 ◽  
Author(s):  
C Javier Pérez ◽  
Vera A Alvarez ◽  
Iñaki Mondragón ◽  
Analía Vázquez

2015 ◽  
Vol 3 (45) ◽  
pp. 22730-22738 ◽  
Author(s):  
Jae-Hun Yang ◽  
Wei Zhang ◽  
Hyunju Ryu ◽  
Ji-Hee Lee ◽  
Dae-Hwan Park ◽  
...  

The thermal stability of PP was significantly improved after the formation of PP nanocomposites with organo-LDH, which was affected by the type of organic modifier in organo-LDH and the loading amount of organo-LDH.


2013 ◽  
Vol 45 (1) ◽  
pp. 459-465 ◽  
Author(s):  
David García-López ◽  
José Francisco Fernández ◽  
Juan Carlos Merino ◽  
José María Pastor

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