Environment-assisted failure of alloy C-276 burst disks in a batch supercritical water oxidation reactor

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R.W. Bradshaw
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John A. Misquith ◽  
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Stuart J. Moore ◽  
John C. Kramlich ◽  
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Desalination ◽  
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Jiaming Zhang ◽  
...  

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Anmol L. Purohit ◽  
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Per G. Reinhall ◽  
...  

2020 ◽  
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Anmol L. Purohit ◽  
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John Kramlich ◽  
...  

<p>A small-scale supercritical water oxidation reactor is designed and fabricated to study the destruction of hazardous wastes. The downward bulk flow is heated with the introduction of pilot fuel (ethanol/water mixture), and oxidant (H<sub>2</sub>O<sub>2</sub>/water mixture). Both streams are introduced coaxially. The fuel dilution is varied from 2 to 7 mol% ethanol/water, and the oxidant-to-fuel stoichiometric equivalence ratio (Φ<sub>AF</sub>), is varied from 1.1 to 1.5. Higher ethanol concentrations in the pilot fuel stream and operation near-stoichiometric results in a more stratified temperature profile, i.e., highest local fluid temperatures near the top and the lowest temperatures at the bottom of the reactor. Steady operation at 603.5 °C is achieved with a nominal residence time of 25.3 s at 7 mol% fuel dilution and Φ<sub>AF</sub> of 1.1. At the lowest pilot fuel dilution (2 mol%), the temperature profile is nearly uniform, approaching a distributed reaction regime.</p>


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