Application of time-domain NMR as a methodology to quantify adulteration of diesel fuel with soybean oil and frying oil

Fuel ◽  
2019 ◽  
Vol 252 ◽  
pp. 567-573 ◽  
Author(s):  
Danyelle A. Cunha ◽  
Álvaro C. Neto ◽  
Luiz A. Colnago ◽  
Eustáquio V.R. Castro ◽  
Lúcio L. Barbosa
2020 ◽  
pp. 22-30
Author(s):  
SERGEY N. DEVYANIN ◽  
◽  
VLADIMIR A. MARKOV ◽  
ALEKSANDR G. LEVSHIN ◽  
TAMARA P. KOBOZEVA ◽  
...  

The paper presents the results of long-term research on the oil productivity and chemical composition of soybean oil of the Northern ecotype varieties in the Central Non-Black Earth Region. The authors consider its possible use for biodiesel production. Experiments on growing soybeans were carried out on the experimental fi eld of Russian State Agrarian University –Moscow Timiryazev Agricultural Academy (2008-2019) on recognized ultra-early ripening varieties of the Northern ecotype Mageva, Svetlaya, Okskaya (ripeness group 000). Tests were set and the research results were analyzed using standard approved methods. It has been shown that in conditions of high latitudes (57°N), limited thermal resources of the Non-Chernozem zone of Russia (the sum of active temperatures of the growing season not exceeding 2000°С), the yield and productivity of soybeans depend on the variety and moisture supply. Over the years, the average yield of soybeans amounted to 1.94 … 2.62 t/ha, oil productivity – 388 … 544 kg/ha, oil content – 19…20%, the content of oleic and linoleic fatty acids in oil – 60%, and their output from seeds harvested – 300 kg/ha. It has been established that as soybean oil and diesel fuel have similar properties,they can be mixed by conventional methods in any proportions and form stable blends that can be stored for a long time. Experimental studies on the use of soybean oil for biodiesel production were carried out on a D-245 diesel engine (4 ChN11/12.5). The concentrations of toxic components (CO, CHx, and NOx) in the diesel exhaust gases were determined using the SAE-7532 gas analyzer. The smoke content of the exhaust gases was measured with an MK-3 Hartridge opacimeter. It has been experimentally established that the transfer of a diesel engine from diesel fuel to a blend of 80% diesel fuel and 20% lubrication oil leads to a change in the integral emissions per test cycle: nitrogen oxides in 0.81 times, carbon monoxide in 0.89 times and unburned hydrocarbons in 0.91 times, i.e. when biodiesel as used as a motor fuel in a serial diesel engine, emissions of all gaseous toxic components are reduced. The study has confi rmed the expediency of using soybeans of the Northern ecotype for biofuel production.


Author(s):  
M Canakci

Biodiesel is an alternative diesel fuel that can be produced from renewable feedstocks such as vegetable oils, waste frying oils, and animal fats. It is an oxygenated, non-toxic, sulphur-free, biodegradable, and renewable fuel. Many engine manufacturers have included this fuel in their warranties since it can be used in diesel engines without significant modification. However, the fuel properties such as cetane number, heat of combustion, specific gravity, and kinematic viscosity affect the combustion, engine performance and emission characteristics. In this study, the engine performance and emissions characteristics of two different petroleum diesel fuels (No. 1 and No. 2 diesel fuels) and biodiesel from soybean oil and its 20 per cent blends with No. 2 diesel fuel were compared. The results showed that the engine performance of the neat biodiesel and its blend was similar to that of No. 2 diesel fuel with nearly the same brake fuel conversion efficiency, and slightly higher fuel consumption. CO2 emission for the biodiesel was slightly higher than for the No. 2 diesel fuel. Compared with diesel fuels, biodiesel produced lower exhaust emissions, except NO x.


1992 ◽  
Vol 6 (2) ◽  
pp. 262-268 ◽  
Author(s):  
Chester G. McWhorter ◽  
William L. Barrentine ◽  
James E. Hanks

Variables affecting ultra-low-volume (ULV) application of herbicides for postemergence grass control in soybeans were evaluated in field experiments from 1988 to 1990. Air-assist applications of clethodim at 2.3 and 4.7 L ha–1were compared with 94 and 187 L ha–1applications with a conventional hydraulic sprayer. Rate of herbicide, volume of diluent, type of diluent, air pressure, and four other herbicides were evaluated. Clethodim at 28, 56, and 112 g ha–1applied in paraffinic oil at 2.3 L ha–1controlled johnsongrass better 10 wk after treatment than equivalent rates applied at 2.3 or 187 L ha–1in water. At 2.3 L ha–1, barnyardgrass control was improved by applying clethodim in paraffinic oil rather than water. Johnsongrass control 10 wk after treatment was better with clethodim at 28 g ha–1applied in paraffinic oil than when applied in soybean oil, cottonseed oil, No. 2 diesel fuel, kerosene, or jet A fuel. Low air pressures of 14 or 28 kPa resulted in better control of johnsongrass and barnyardgrass than higher pressures of 56 and 112 kPa. Clethodim, fluazifop-P, haloxyfop, quizalofop, or sethoxydim were more effective on johnsongrass and barnyardgrass when applied in paraffinic oil than in water at 2.3 and 4.7 L ha–1with an air-assist sprayer.


1996 ◽  
Vol 57 (1) ◽  
pp. 31-36 ◽  
Author(s):  
L.G. Schumacher ◽  
S.C. Borgelt ◽  
D. Fosseen ◽  
W. Goetz ◽  
W.G. Hires

2021 ◽  
Vol 4 (1) ◽  
pp. 44-50
Author(s):  
Rhiby Ainur Basit Hariyanto ◽  
R. Arizal Firmansyah ◽  
R. Y. Perry Burhan ◽  
Yulfi Zetra

The desulphurization process of diesel fuel is carried out to reduce the amount of SO2 emissions that can cause acid rain. However, the desulphurization process in diesel fuel not only removes the sulfur compounds but polyaromatic and polar compounds are also eliminated during this process. The loss of these two compounds can reduce the lubricity properties of diesel fuel. Therefore, it is necessary to add an additive compound that can increase the lubricity properties. In this research, 2-hydroxyethyl ester (HEE) was synthesized as an additive to increase the lubricity of diesel fuel. This compound was synthesized through the transesterification reaction of soybean oil and ethylene glycol with K2CO3 as the base catalyst. The composition of the synthesized additives was analyzed using the Gas Chromatography-Mass Spectrometry (GC-MS). Based on the results of GC-MS spectrum analysis, it is known that the 2-hydroxyethyl ester compound has been formed with a yield of 66.5% (relative to the area of the chromatogram peak). The HEE compound obtained is a mixture of 2 hydroxyethyl palmitate, 2 hydroxyethyl linoleate, 2 hydroxyethyl stearate, 2 hydroxyethyl arachidonate, 2 hydroxyethyl nervate, and 2 hydroxyethyl behenate.


1996 ◽  
Vol 73 (11) ◽  
pp. 1549-1555 ◽  
Author(s):  
David Y. Z. Chang ◽  
Jon H. Van Gerpen ◽  
Inmok Lee ◽  
Lawrence A. Johnson ◽  
Earl G. Hammond ◽  
...  

2017 ◽  
Vol 46 (11) ◽  
pp. 1125004
Author(s):  
张文涛 Zhang Wentao ◽  
李跃文 Li Yuewen ◽  
占平平 Zhan Pingping ◽  
熊显名 Xiong Xianming

1983 ◽  
Vol 60 (8) ◽  
pp. 1598-1601 ◽  
Author(s):  
M. J. Nye ◽  
T. W. Williamson ◽  
W. Deshpande ◽  
J. H. Schrader ◽  
W. H. Snively ◽  
...  

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