NaNH 2 –NaBH 4 hydrogen storage composite materials synthesized via liquid phase ball-milling: Influence of Co–Ni–B catalyst on the dehydrogenation performances

In order to improve the hydrogen storage performance of La2Mg17 alloy, with high energy ball-milling in argon atmosphere prepared La2Mg17-Ni composite materials, and mixed in a little NbF5. Through automatSubscript textic control Sieverts equipment tested hydrogen absorption kinetic characteristics of sample. X-ray diffraction (XRD) analyzed the microstructure of material after hydrogenated, and estimated the phase composition of hydrogenated powder material. The results showed that hydrogen storage properties of composite materials improved significantly because of the mechanical ball-milling approach, and the hydrogenated capabilities also increased dramatically with rising of temperature. Further explained the material hydriding property is largely ameliorate because of the Ni powder and NbF5 prompted amorphous or nanocrystalline particle formation, but temperature controlling the generation of new hydride phase is as well the reason of hydrogenated performance to advance.

Download Full-text

Light-weight NaNH2–NaBH4 hydrogen storage material synthesized via liquid phase ball milling

International Journal of Hydrogen Energy ◽

10.1016/j.ijhydene.2014.03.095 ◽

2014 ◽

Vol 39 (25) ◽

pp. 13576-13582 ◽

Cited By ~ 12

Author(s):

Ying Bai ◽

Lu-lu Zhao ◽

Yue Wang ◽

Xin Liu ◽

Feng Wu ◽

...

Keyword(s):

Liquid Phase ◽

Hydrogen Storage ◽

Ball Milling ◽

Light Weight ◽

Hydrogen Storage Material ◽

Storage Material

Download Full-text

Sintering and properties of composite materials ZrO2—Al2O3 with sodium silicate liquid phase

Materials Science ◽

10.31044/1684-579x-2019-0-6-32-36 ◽

2019 ◽

Vol 0 (6) ◽

pp. 32-36 ◽

Cited By ~ 1

Author(s):

Valeriy Smirnov ◽

◽

Sergey Smirnov ◽

Tatiana Obolkina ◽

Olga Antonova ◽

...

Keyword(s):

Composite Materials ◽

Liquid Phase ◽

Sodium Silicate ◽

Silicate Liquid

Download Full-text

High Ionic Conductivity of Liquid-Phase-Synthesized Li3PS4 Solid Electrolyte, Comparable to That Obtained via Ball Milling

ACS Applied Energy Materials ◽

10.1021/acsaem.0c02771 ◽

2021 ◽

Author(s):

Kentaro Yamamoto ◽

Seunghoon Yang ◽

Masakuni Takahashi ◽

Koji Ohara ◽

Tomoki Uchiyama ◽

...

Keyword(s):

Liquid Phase ◽

Ionic Conductivity ◽

Solid Electrolyte ◽

Ball Milling ◽

High Ionic Conductivity

Download Full-text

Engineering Challenges of Solution and Slurry-Phase Chemical Hydrogen Storage Materials for Automotive Fuel Cell Applications

Molecules ◽

10.3390/molecules26061722 ◽

2021 ◽

Vol 26 (6) ◽

pp. 1722

Author(s):

Troy Semelsberger ◽

Jason Graetz ◽

Andrew Sutton ◽

Ewa C. E. Rönnebro

Keyword(s):

Liquid Phase ◽

Hydrogen Storage ◽

System Level ◽

Transport Systems ◽

Automotive Applications ◽

Storage Media ◽

Slurry Phase ◽

Research Findings ◽

Chemical Hydrogen Storage ◽

Phase Chemical

We present the research findings of the DOE-funded Hydrogen Storage Engineering Center of Excellence (HSECoE) related to liquid-phase and slurry-phase chemical hydrogen storage media and their potential as future hydrogen storage media for automotive applications. Chemical hydrogen storage media other than neat liquid compositions will prove difficult to meet the DOE system level targets. Solid- and slurry-phase chemical hydrogen storage media requiring off-board regeneration are impractical and highly unlikely to be implemented for automotive applications because of the formidable task of developing solid- or slurry-phase transport systems that are commercially reliable and economical throughout the entire life cycle of the fuel. Additionally, the regeneration cost and efficiency of chemical hydrogen storage media is currently the single most prohibitive barrier to implementing chemical hydrogen storage media. Ideally, neat liquid-phase chemical hydrogen storage media with net-usable gravimetric hydrogen capacities of greater than 7.8 wt% are projected to meet the 2017 DOE system level gravimetric and volumetric targets. The research presented herein is a collection of research findings that do not in and of themselves warrant a dedicated manuscript. However, the collection of results do, in fact, highlight the engineering challenges and short-comings in scaling up and demonstrating fluid-phase ammonia borane and alane compositions that all future materials researchers working in hydrogen storage should be aware of.

Download Full-text

A fixed directions damage model for composite materials dedicated to hyperbaric type IV hydrogen storage vessel – Part II: Validation on notched structures

International Journal of Hydrogen Energy ◽

10.1016/j.ijhydene.2015.06.014 ◽

2015 ◽

Vol 40 (38) ◽

pp. 13174-13182 ◽

Cited By ~ 11

Author(s):

Juan Pedro Berro Ramirez ◽

Damien Halm ◽

Jean-Claude Grandidier ◽

Stéphane Villalonga

Keyword(s):

Composite Materials ◽

Hydrogen Storage ◽

Damage Model ◽

Storage Vessel ◽

Type Iv ◽

Hydrogen Storage Vessel

Download Full-text

Recent Advances in Hydrogen Storage Materials

Advanced Materials Research ◽

10.4028/www.scientific.net/amr.512-515.1438 ◽

2012 ◽

Vol 512-515 ◽

pp. 1438-1441 ◽

Cited By ~ 2

Author(s):

Hong Min Kan ◽

Ning Zhang ◽

Xiao Yang Wang ◽

Hong Sun

Keyword(s):

Liquid Phase ◽

Hydrogen Storage ◽

Earth Metal ◽

Solid Material ◽

Hydrogen Energy ◽

Hydrogen Storage Material ◽

Ambient Conditions ◽

Storage Material ◽

Lithium Borohydride ◽

Recent Advances

An overview of recent advances in hydrogen storage is presented in this review. The main focus is on metal hydrides, liquid-phase hydrogen storage material, alkaline earth metal NC/polymer composites and lithium borohydride ammoniate. Boron-nitrogen-based liquid-phase hydrogen storage material is a liquid under ambient conditions, air- and moisture-stable, recyclable and releases H2controllably and cleanly. It is not a solid material. It is easy storage and transport. The development of a liquid-phase hydrogen storage material has the potential to take advantage of the existing liquid-based distribution infrastructure. An air-stable composite material that consists of metallic Mg nanocrystals (NCs) in a gas-barrier polymer matrix that enables both the storage of a high density of hydrogen and rapid kinetics (loading in <30 min at 200°C). Moreover, nanostructuring of Mg provides rapid storage kinetics without using expensive heavy-metal catalysts. The Co-catalyzed lithium borohydride ammoniate, Li(NH3)4/3BH4 releases 17.8 wt% of hydrogen in the temperature range of 135 to 250 °C in a closed vessel. This is the maximum amount of dehydrogenation in all reports. These will reduce economy cost of the global transition from fossil fuels to hydrogen energy.

Download Full-text