Three-dimensional 3d–4f heterometallic coordination polymer containing Sm2Mn4 clusters: Synthesis, crystal structure and properties

2009 ◽  
Vol 12 (6) ◽  
pp. 523-526 ◽  
Author(s):  
Qi Zhang ◽  
Yong-Xin Zheng ◽  
Chen-Xu Liu ◽  
Ya-Guang Sun ◽  
En-Jun Gao
Keyword(s):  
Crystal Structure ◽  
Coordination Polymer ◽  
Three Dimensional ◽  
Structure And Properties ◽  
Heterometallic Coordination Polymer

Synthesis, crystal structure, and properties of a three-dimensional coordination polymer [Cd(PMP)2] n

2010 ◽  
Vol 21 (5) ◽  
pp. 1085-1091 ◽  
Author(s):  
Rui-Bo Xu ◽  
Xing-You Xu ◽  
Shu-An Li ◽  
Ming-Yan Wang ◽  
Xu-Jie Yang ◽  
...  
Keyword(s):  
Crystal Structure ◽  
Coordination Polymer ◽  
Three Dimensional ◽  
Structure And Properties

scholarly journals Crystal structure of poly[diaquabis(μ5-benzene-1,3-dicarboxylato)(N,N-dimethylformamide)cadmium(II)disodium(I)]

2017 ◽  
Vol 73 (11) ◽  
pp. 1599-1602 ◽  
Author(s):  
Matimon Sangsawang ◽  
Kittipong Chainok ◽  
Nanthawat Wannarit
Keyword(s):  
Crystal Structure ◽  
Coordination Polymer ◽  
Hydrogen Bonds ◽  
Three Dimensional ◽  
Water Molecules ◽  
Asymmetric Unit ◽  
Carboxylate Groups ◽  
Benzene Rings ◽  
Coordinated Water ◽  
Coordinate Geometry

The title compound, [CdNa2(C8H4O4)2(C3H7NO)(H2O)2]nor [CdNa2(1,3-bdc)2(DMF)(H2O)2]n, is a new CdII–NaIheterobimetallic coordination polymer. The asymmetric unit consists of one CdIIatom, two NaIatoms, two 1,3-bdc ligands, two coordinated water molecules and one coordinated DMF molecule. The CdIIatom exhibits a seven-coordinate geometry, while the NaIatoms can be considered to be pentacoordinate. The metal ions and their symmetry-related equivalents are connectedviachelating–bridging carboxylate groups of the 1,3-bdc ligands to generate a three-dimensional framework. In the crystal, there are classical O—H...O hydrogen bonds involving the coordinated water molecules and the 1,3-bdc carboxylate groups and π–π stacking between the benzene rings of the 1,3-bdc ligands present within the frameworks.

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