Impact of fluid–rock chemical interactions on tracer transport in fractured rocks

2013 ◽  
Vol 154 ◽  
pp. 42-52 ◽  
Author(s):  
Sumit Mukhopadhyay ◽  
H.-H. Liu ◽  
N. Spycher ◽  
B.M. Kennedy
1991 ◽  
Vol 257 ◽  
Author(s):  
Luis Moreno ◽  
Ivars Neretnieks

ABSTRACTA model is proposed to describe flow and transport in fractured rocks. It is based on the concept of a network of channels. This approach is backed by observations in drifts and tunnels that flow in fractured rocks takes place in sparse narrow channels with widths typically less than 10 cm and a channel frequency of one channel per a few square meters to one channel per more than a hundred square meters. Observations in boreholes also indicate that there are large distances, tens to hundreds of meters, between the most conductive sections in boreholes.For visualization purposes our model is displayed on a rectangular grid. The individual channels are given stochastically selected conductances and volumes. Flowrate calculations have been performed in grids of sizes 20*20*20 channels in most cases but larger grids have also been used. For large standard.deviations in conductances, greater than 1.6 in the log normal distribution (base 10), channeling becomes pronounced with most of the water flowing in a few paths. The effluent patterns and flowrate distributions obtained in the simulations have been compared to three different field measurements in drifts and tunnels. Standard deviations of channels conductances were found to be between 1.6 and 2.4 or more in some cases. Channel lengths were found to vary between 1.2 m and 10.2 m in the different sites. In one site where detailed borehole measurements were available the channel length could be assessed independently and was found to be 1.2 m as compared to the 1.7 m obtained from the drift inflow measurements.A particle tracking technique was used to simulate solute transport in the network. Nonsorbing as well as sorbing tracer transport can be simulated and by a special technique also tracers which diffuse into the rock matrix can be simulated.Tracer measurements in one site, Stripa, were used to compare dispersivities. These were found to be large, having Peclet numbers less than 5 both in simulations and the field results. From the Stripa tracer data it was also found that the tracers were taken up into the rock matrix by molecular diffusion. The surface area needed for this uptake was estimated to be between 0.2-20 m2/m3 for different tracers. The wetted surface for the model estimated from flowrate distribution data indicate a wetted surface of 0.2- 0.4 m2/m3.


2006 ◽  
Vol 19 (107) ◽  
pp. 27-31 ◽  
Author(s):  
Alan Ramić ◽  
Marica Medić-Šarić ◽  
Srećko Turina ◽  
Ivona Jasprica

Author(s):  
E. Calendi ◽  
A. Di Marco ◽  
M. Reggiani ◽  
B. Scarpinato ◽  
L. Valentini

2021 ◽  
Author(s):  
Angana Borbora ◽  
Uttam Manna

Different chemical interactions/bonding allowed LbL deposition of selected constituents, and further post-chemical modifications of chemically reactive multilayered microcapsules allowed to associate desired chemical functionalities.


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