Reversible Al3+ storage mechanism in anatase TiO2 cathode material for ionic liquid electrolyte-based aluminum-ion batteries

2020 ◽  
Vol 51 ◽  
pp. 72-80 ◽  
Author(s):  
Na Zhu ◽  
Feng Wu ◽  
Zhaohua Wang ◽  
Liming Ling ◽  
Haoyi Yang ◽  
...  
Keyword(s):  
Ionic Liquid ◽  
Cathode Material ◽  
Liquid Electrolyte ◽  
Anatase Tio2 ◽  
Ionic Liquid Electrolyte ◽  
Storage Mechanism ◽  
Aluminum Ion

A Quinone-Based Electrode for High-Performance Rechargeable Aluminum-Ion Batteries with a Low-Cost AlCl3/Urea Ionic Liquid Electrolyte

2020 ◽  
Vol 12 (23) ◽  
pp. 25853-25860 ◽  
Author(s):  
Yu-Ting Kao ◽  
Shivaraj B. Patil ◽  
Chi-Yao An ◽  
Shao-Ku Huang ◽  
Jou-Chun Lin ◽  
...  
Keyword(s):  
Ionic Liquid ◽  
High Performance ◽  
Low Cost ◽  
Liquid Electrolyte ◽  
Ionic Liquid Electrolyte ◽  
Aluminum Ion

Polyterthiophene/CNT composite as a cathode material for lithium batteries employing an ionic liquid electrolyte

2009 ◽  
Vol 54 (27) ◽  
pp. 6844-6849 ◽  
Author(s):  
S.R. Sivakkumar ◽  
Patrick C. Howlett ◽  
Bjorn Winther-Jensen ◽  
Maria Forsyth ◽  
Douglas R. MacFarlane
Keyword(s):  
Ionic Liquid ◽  
Cathode Material ◽  
Lithium Batteries ◽  
Liquid Electrolyte ◽  
Ionic Liquid Electrolyte

scholarly journals Redox-active ionic liquid electrolyte with multi energy storage mechanism for high energy density supercapacitor

RSC Advances ◽  
2017 ◽  
Vol 7 (88) ◽  
pp. 55702-55708 ◽  
Author(s):  
Duck-Jae You ◽  
Zhenxing Yin ◽  
Yong-keon Ahn ◽  
Seong-Hun Lee ◽  
Jeeyoung Yoo ◽  
...  
Keyword(s):  
Ionic Liquid ◽  
Energy Density ◽  
Size Variation ◽  
High Energy ◽  
Liquid Electrolyte ◽  
High Energy Density ◽  
Halide Ions ◽  
Ionic Liquid Electrolyte ◽  
Storage Mechanism ◽  
Redox Active

A bimodal redox-active ionic liquid electrolyte for high energy density supercapacitors was fabricated by the redox reaction of halide ions and size variation of ions.

Ternary AlCl3-Urea-[EMIm]Cl Ionic Liquid Electrolyte for Rechargeable Aluminum-Ion Batteries

2017 ◽  
Vol 164 (13) ◽  
pp. A3093-A3100 ◽  
Author(s):  
Junfeng Li ◽  
Jiguo Tu ◽  
Handong Jiao ◽  
Chen Wang ◽  
Shuqiang Jiao
Keyword(s):  
Ionic Liquid ◽  
Liquid Electrolyte ◽  
Ionic Liquid Electrolyte ◽  
Aluminum Ion

Electrochemical properties of an aluminum anode in an ionic liquid electrolyte for rechargeable aluminum-ion batteries

2017 ◽  
Vol 19 (13) ◽  
pp. 8653-8656 ◽  
Author(s):  
Sangwon Choi ◽  
Hyungho Go ◽  
Gibaek Lee ◽  
Yongsug Tak
Keyword(s):  
Ionic Liquid ◽  
Oxide Film ◽  
Electrochemical Properties ◽  
High Capacity ◽  
Liquid Electrolyte ◽  
Aluminum Anode ◽  
Ionic Liquid Electrolyte ◽  
Aluminum Ion ◽  
Surface Corrosion ◽  
Stable Surface

An electro-polished aluminum anode without the oxide film exhibits high capacity and stable surface corrosion.

Enhanced Ion Transport in an Ether Aided Super Concentrated Ionic Liquid Electrolyte for Long-Life Practical Lithium Metal Battery Applications

2020 ◽  
Author(s):  
Urbi Pal ◽  
Fangfang Chen ◽  
Derick Gyabang ◽  
Thushan Pathirana ◽  
Binayak Roy ◽  
...  
Keyword(s):  
Ionic Liquid ◽  
Ion Transport ◽  
Current Density ◽  
Coulombic Efficiency ◽  
High Energy ◽  
Liquid Electrolyte ◽  
High Mass ◽  
Lithium Metal ◽  
Ionic Liquid Electrolyte ◽  
Lithium Metal Battery

We explore a novel ether aided superconcentrated ionic liquid electrolyte; a combination of ionic liquid, <i>N</i>-propyl-<i>N</i>-methylpyrrolidinium bis(fluorosulfonyl)imide (C<sub>3</sub>mpyrFSI) and ether solvent, <i>1,2</i> dimethoxy ethane (DME) with 3.2 mol/kg LiFSI salt, which offers an alternative ion-transport mechanism and improves the overall fluidity of the electrolyte. The molecular dynamics (MD) study reveals that the coordination environment of lithium in the ether aided ionic liquid system offers a coexistence of both the ether DME and FSI anion simultaneously and the absence of ‘free’, uncoordinated DME solvent. These structures lead to very fast kinetics and improved current density for lithium deposition-dissolution processes. Hence the electrolyte is used in a lithium metal battery against a high mass loading (~12 mg/cm<sup>2</sup>) LFP cathode which was cycled at a relatively high current rate of 1mA/cm<sup>2</sup> for 350 cycles without capacity fading and offered an overall coulombic efficiency of >99.8 %. Additionally, the rate performance demonstrated that this electrolyte is capable of passing current density as high as 7mA/cm<sup>2</sup> without any electrolytic decomposition and offers a superior capacity retention. We have also demonstrated an ‘anode free’ LFP-Cu cell which was cycled over 50 cycles and achieved an average coulombic efficiency of 98.74%. The coordination chemistry and (electro)chemical understanding as well as the excellent cycling stability collectively leads toward a breakthrough in realizing the practical applicability of this ether aided ionic liquid electrolytes in lithium metal battery applications, while delivering high energy density in a prototype cell.

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