Design a novel type of excess electron compounds with large nonlinear optical responses using group 12 elements (Zn, Cd and Hg)

2021 ◽  
pp. 108003
Author(s):  
Bicheng Zhang ◽  
Jiaqi Wen ◽  
Yuze Zhang ◽  
Yongkang Xiong ◽  
Xiaohan Huang ◽  
...  
Keyword(s):  
Nonlinear Optical ◽  
Excess Electron ◽  
Optical Responses ◽  
Group 12 ◽  
Electron Compounds

A theoretical study on novel alkaline earth-based excess electron compounds: unique alkalides with considerable nonlinear optical responses

2015 ◽  
Vol 17 (6) ◽  
pp. 4524-4532 ◽  
Author(s):  
Wei-Ming Sun ◽  
Di Wu ◽  
Ying Li ◽  
Jia-Yuan Liu ◽  
Hui-Min He ◽  
...  
Keyword(s):  
Alkali Metal ◽  
Nonlinear Optical ◽  
Alkaline Earth ◽  
Theoretical Study ◽  
Excess Electron ◽  
Optical Responses ◽  
Electron Compounds ◽  
Metal Anions

A series of novel excess electron compounds M(NH3)6NaCl and M(NH3)6Na2 (M = Mg and Ca) were designed, in which the lowest-energy M(NH3)6Na2 compounds are the first alkalides containing double alkali metal anions.

Coinage metalides: a new class of excess electron compounds with high stability and large nonlinear optical responses

2020 ◽  
Vol 22 (16) ◽  
pp. 8476-8484
Author(s):  
Xiang-Hui Li ◽  
Xiao-Ling Zhang ◽  
Qiao-Hong Chen ◽  
Li Zhang ◽  
Jing-Hua Chen ◽  
...  
Keyword(s):  
High Stability ◽  
Nonlinear Optical ◽  
Electron Acceptors ◽  
Excess Electron ◽  
Coinage Metal ◽  
New Class ◽  
Optical Responses ◽  
Metal Atoms ◽  
Electron Compounds

A new class of NLO molecules, termed coinage metalides, was designed by using coinage metal atoms as excess electron acceptors.

Designing a new class of excess electron compounds with unique electronic structures and extremely large non-linear optical responses

2020 ◽  
Vol 44 (16) ◽  
pp. 6411-6419
Author(s):  
Xiang-Hui Li ◽  
Li Zhang ◽  
Xiao-Ling Zhang ◽  
Bi-Lian Ni ◽  
Chun-Yan Li ◽  
...  
Keyword(s):  
Electronic Structures ◽  
Excess Electron ◽  
New Class ◽  
Optical Responses ◽  
Non Linear ◽  
Linear Optical ◽  
Electron Compounds

New Ca+-1-M′− (M′ = Li, Na, and K) compounds with typical alkalide features and electride-like characteristics have been obtained.

Remarkable second and third order nonlinear optical properties of organometallic C6Li6–M3O electrides

2020 ◽  
Vol 44 (23) ◽  
pp. 9822-9829 ◽  
Author(s):  
Faizan Ullah ◽  
Khurshid Ayub ◽  
Tariq Mahmood
Keyword(s):  
Optical Properties ◽  
Nonlinear Optical ◽  
Nonlinear Optical Properties ◽  
Excess Electron ◽  
Third Order ◽  
Electron Compounds

Electrides are excess electron compounds with excellent nonlinear optical properties.

Remarkable nonlinear optical response of excess electron compounds: theoretically designed alkali-doped aziridine M–(C2NH5)n

2017 ◽  
Vol 19 (35) ◽  
pp. 23951-23959 ◽  
Author(s):  
Bo Li ◽  
Chao Xu ◽  
Xuan Xu ◽  
Chaoyuan Zhu ◽  
Feng Long Gu
Keyword(s):  
Nonlinear Optical ◽  
Optical Response ◽  
Excess Electron ◽  
Nonlinear Optical Response ◽  
First Hyperpolarizability ◽  
Nlo Response ◽  
Electron Compounds

Newly theoretically designed alkali-doped aziridine M–(C2NH5)4 shows a remarkable NLO response and its first hyperpolarizability is 10 to 100 times larger than those of M@Calix[4]pyrrole.

scholarly journals Germanium-based superatom clusters as excess electron compounds with significant static and dynamic NLO response; a DFT study

RSC Advances ◽  
2022 ◽  
Vol 12 (1) ◽  
pp. 365-377
Author(s):  
Atazaz Ahsin ◽  
Ahmed Bilal Shah ◽  
Khurshid Ayub
Keyword(s):  
Optical Properties ◽  
Nonlinear Optical ◽  
Nonlinear Optical Properties ◽  
Excess Electron ◽  
Dft Study ◽  
Nlo Response ◽  
Zintl Clusters ◽  
Electron Compounds

Herein, the geometric, electronic, and nonlinear optical properties of excess electron zintl clusters Ge5AM3, Ge9AM5, and Ge10AM3 (AM = Li, Na, and K) are investigated.

Can Coinage Metal Atoms Be Capable of Serving as an Excess Electron Source of Alkalides with Considerable Nonlinear Optical Responses?

2017 ◽  
Vol 56 (8) ◽  
pp. 4594-4600 ◽  
Author(s):  
Wei-Ming Sun ◽  
Xiang-Hui Li ◽  
Juan Wu ◽  
Jian-Ming Lan ◽  
Chun-Yan Li ◽  
...  
Keyword(s):  
Nonlinear Optical ◽  
Electron Source ◽  
Excess Electron ◽  
Coinage Metal ◽  
Optical Responses ◽  
Metal Atoms
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