Compressive strength and hydration process of sodium carbonate-activated superfine slag/marble powder binders

2021 ◽  
pp. 103121
Author(s):  
Chao Du ◽  
Hongbo Tan ◽  
Shouwei Jian ◽  
Jie Wang ◽  
Tao Shi
Keyword(s):  
Compressive Strength ◽  
Sodium Carbonate ◽  
Hydration Process ◽  
Marble Powder

Study on the antiseepage mechanism of the PBFC slurry for landfill site

2017 ◽  
Vol 31 (16-19) ◽  
pp. 1744087 ◽  
Author(s):  
Guozhong Dai ◽  
Weicheng Shi ◽  
Xiaoshu Jiang ◽  
Guicai Shi ◽  
Yaxing Zhang
Keyword(s):  
Heavy Metal ◽  
Compressive Strength ◽  
Fly Ash ◽  
Polyvinyl Alcohol ◽  
Metal Ions ◽  
Sodium Carbonate ◽  
Heavy Metal Ions ◽  
Landfill Site ◽  
Low Permeability ◽  
Coefficient Of Permeability

In order to develop a kind of slurry with low permeability which has some adsorption and retardation to the pollutants in leachate to be used in antiseepage engineering of leachate for landfill site, experiments based on orthogonal method were performed. The optimal PBFC slurry was selected: bentonite 18–26%, cement 16–24%, fly ash 18–20%, TOJ800-10 water reducing agent 0.01–0.03%, polyvinyl alcohol 0.2–0.8%, sodium carbonate 0.8–1.5% and water 680–780/1000 mL seriflus. The material has good groutability and a concretion stone ratio which is greater than 99.6%. The coefficient of permeability of 28-day concretion body is 0.53 × 10[Formula: see text]–1.86 × 10[Formula: see text] cm/s and the compressive strength is 0.64–1.04 MPa. The slurry has good adsorption and retardation properties. The block rate of NH4-N and phosphorus reached 98.28%, and the block rate of CODCr and BOD5 reached 85.67%. The block rate of Hg, Pb and other heavy metal ions reached 99.8%. The PBFC slurry improved the retardation capability of the pollutants of the leachate at the landfill site by its infiltration sedimentation and adsorption fixation.

scholarly journals Microstructural and Mechanical Properties of Alkali Activated Materials from Two Types of Blast Furnace Slags

Materials ◽  
2019 ◽  
Vol 12 (13) ◽  
pp. 2089 ◽  
Author(s):  
Jun Xing ◽  
Yingliang Zhao ◽  
Jingping Qiu ◽  
Xiaogang Sun
Keyword(s):  
Mechanical Properties ◽  
Compressive Strength ◽  
Blast Furnace ◽  
Thermal Stabilization ◽  
Hydration Process ◽  
Reaction Products ◽  
Basic Oxide ◽  
X Ray ◽  
Physical And Chemical ◽  
Alkali Activated

This paper investigated the effect of blast furnace slags (BFS) characteristics on the properties achievement after being alkali activated. The physical and chemical characteristics of BFS were determined by X-ray fluorescence (XRF), X-ray Diffraction (XRD) and laser granulometry. Multi-technical characterizations using calorimetry, XRD, Fourier Transform Infrared Spectroscopy (FTIR), Thermogravimetry (TG-DTG), scanning electron microscope (SEM), nitrogen sorption and uniaxial compressive strength (UCS) were applied to give an in-depth understanding of the relationship between the reaction products, microstructure and BFS characteristics. The test results show that the microstructure and mechanical properties of alkali activated blast furnace slags (BFS) highly depend on the characteristics of BFS. Although the higher content of basic oxide could accelerate the hydration process and result in higher mechanical properties, a poor thermal stabilization was observed. On the other hand, with a higher content of Fe, the hydration process in alkali activated BFS2 lasts for a longer time, contributing to a delayed compressive strength achievement.

scholarly journals The Influence of Superabsorbent Polymers and Nanosilica on the Hydration Process and Microstructure of Cementitious Mixtures

Materials ◽  
2020 ◽  
Vol 13 (22) ◽  
pp. 5194
Author(s):  
Gerlinde Lefever ◽  
Dimitrios G. Aggelis ◽  
Nele De Belie ◽  
Marc Raes ◽  
Tom Hauffman ◽  
...  
Keyword(s):  
Compressive Strength ◽  
Isothermal Calorimetry ◽  
Autogenous Shrinkage ◽  
Hydration Process ◽  
Microstructural Development ◽  
Self Healing ◽  
Hydration Kinetics ◽  
Superabsorbent Polymers ◽  
Water To Cement Ratio ◽  
Supplementary Material

Superabsorbent polymers (SAPs) are known to mitigate the development of autogenous shrinkage in cementitious mixtures with a low water-to-cement ratio. Moreover, the addition of SAPs promotes the self-healing ability of cracks. A drawback of using SAPs lies in the formation of macropores when the polymers release their absorbed water, leading to a reduction of the mechanical properties. Therefore, a supplementary material was introduced together with SAPs, being nanosilica, in order to obtain an identical compressive strength with respect to the reference material without additives. The exact cause of the similar compressive behaviour lies in the modification of the hydration process and subsequent microstructural development by both SAPs and nanosilica. Within the present study, the effect of SAPs and nanosilica on the hydration progress and the hardened properties is assessed. By means of isothermal calorimetry, the hydration kinetics were monitored. Subsequently, the quantity of hydration products formed was determined by thermogravimetric analysis and scanning electron microscopy, revealing an increased amount of hydrates for both SAP and nanosilica blends. An assessment of the pore size distribution was made using mercury intrusion porosimetry and demonstrated the increased porosity for SAP mixtures. A correlation between microstructure and the compressive strength displayed its influence on the mechanical behaviour.

The Influence of Aggregates on the Properties of Concrete

2014 ◽  
Vol 1000 ◽  
pp. 277-280 ◽  
Author(s):  
Pavel Šiler ◽  
Ondřej Bezděk ◽  
Iva Kolářová ◽  
Eva Bartoníčková ◽  
Tomáš Opravil ◽  
...  
Keyword(s):  
Mechanical Properties ◽  
Particle Size ◽  
Compressive Strength ◽  
Flexural Strength ◽  
Portland Cement ◽  
Particle Size Analysis ◽  
Hydration Process ◽  
Silica Sand ◽  
Size Analysis ◽  
Isoperibolic Calorimetry

This work is focused on the influence of aggregates on the mechanical properties of concrete and hydration process. The flexural strength and compressive strength were observed after 1, 7 and 28 days of curing. The process of hydration was monitored using isoperibolic calorimetry. Laser particle size analysis of aggregates was also performed. The following materials were used: Portland cement CEM I 42,5 R-Sc, finely ground silica sand, calcinated bauxite, fine, medium and rough testing sand (defined in ČSN EN 196-1).

scholarly journals Hydration process and compressive strength of cement pastes containing natural zeolite

2016 ◽  
Vol 59 (2) ◽  
pp. 29-45 ◽  
Author(s):  
Miroslava Radeka ◽  
Tiana Milovic ◽  
Mirjana Malesev ◽  
Vlastimir Radonjanin ◽  
Mirjana Laban
Keyword(s):  
Compressive Strength ◽  
Natural Zeolite ◽  
Hydration Process ◽  
Cement Pastes

scholarly journals Study of Fly Ash, Rice Husk Ash and Marble Powder as Partial Replacement to Cement in Concrete

2020 ◽  
Vol 13 (3) ◽  
pp. 315-321
Author(s):  
Dhiraj Ahiwale ◽  
Rushikesh Khartode
Keyword(s):  
Compressive Strength ◽  
Fly Ash ◽  
Flexural Strength ◽  
Rice Husk ◽  
Coarse Aggregate ◽  
Rice Husk Ash ◽  
Partial Replacement ◽  
Scale Production ◽  
Environmental Threat ◽  
Marble Powder

Now days, the waste rice husk from rice mill, marble powder from tile industry and fly ash from steam power plant are necessary to utilize as partial replacement of cement for concrete production. Large scale production of cement required consumption of raw materials and energy as well as emissions to air which posse’s environmental threat in various areas of country. Apart from the environmental threat, there still exists the problem of shortage in many areas. Therefore, substitute material for concrete needs to be considered. The paper aims to analyze the compressive strength of concrete cubes and flexural strength of concrete beams made from partially replaced cement, sand, and coarse aggregate. This research study adopted in laboratory on 48 total specimens of grade M25 concrete cubes of size 150x150x150mm and concrte beams of size 100x100x500mm were casted. Out of the 48 concrete specimens cast, 6 each were made out 10%, 20%, and 30 % replacement of fly ash, rice husk ash and marble powder to cement in concrete. It was found that the compressive strength and flexural strength of concrete made from the mixture of 20 % partially replaced cement, sand and coarse aggregate was similar than the concrete made from without replaced cement , sand and coarse aggregate.

scholarly journals Alkali-Activated Hybrid Cements Based on Fly Ash and Construction and Demolition Wastes Using Sodium Sulfate and Sodium Carbonate

Molecules ◽  
2021 ◽  
Vol 26 (24) ◽  
pp. 7572
Author(s):  
William Valencia-Saavedra ◽  
Rafael Robayo-Salazar ◽  
Ruby Mejía de Gutiérrez
Keyword(s):  
Compressive Strength ◽  
Fly Ash ◽  
Portland Cement ◽  
Sodium Carbonate ◽  
Sodium Sulfate ◽  
Room Temperature ◽  
Ordinary Portland Cement ◽  
Mechanical Performance ◽  
Construction And Demolition Wastes ◽  
Alkali Activated

This article demonstrates the possibility of producing alkali-activated hybrid cements based on fly ash (FA), and construction and demolition wastes (concrete waste, COW; ceramic waste, CEW; and masonry waste, MAW) using sodium sulfate (Na2SO4) (2–6%) and sodium carbonate (Na2CO3) (5–10%) as activators. From a mixture of COW, CEW, and MAW in equal proportions (33.33%), a new precursor called CDW was generated. The precursors were mixed with ordinary Portland cement (OPC) (10–30%). Curing of the materials was performed at room temperature (25 °C). The hybrid cements activated with Na2SO4 reached compressive strengths of up to 31 MPa at 28 days of curing, and the hybrid cements activated with Na2CO3 yielded compressive strengths of up to 22 MPa. Based on their mechanical performance, the optimal mixtures were selected: FA/30OPC-4%Na2SO4, CDW/30OPC-4%Na2SO4, FA/30OPC-10%Na2CO3, and CDW/30OPC-10%Na2CO3. At prolonged ages (180 days), these mixtures reached compressive strength values similar to those reported for pastes based on 100% OPC. A notable advantage is the reduction of the heat of the reaction, which can be reduced by up to 10 times relative to that reported for the hydration of Portland cement. These results show the feasibility of manufacturing alkaline-activated hybrid cements using alternative activators with a lower environmental impact.

scholarly journals Influence of Water-Cement Ratio and Type of Mixing Water on the Early Hydration Performance of Calcium Sulphoaluminate (CSA) Cement

2021 ◽  
Vol 2021 ◽  
pp. 1-10
Author(s):  
Chuanlin Wang ◽  
Meimei Song
Keyword(s):  
Compressive Strength ◽  
Physical Properties ◽  
Setting Time ◽  
Hydration Process ◽  
Chemical Shrinkage ◽  
Cement Ratio ◽  
Water Cement Ratio ◽  
Influence Of Water ◽  
Calcium Sulphoaluminate ◽  
Mixing Water

The present work studies the influence of water-cement ratio and types of mixing water on the hydration process and microstructure of calcium sulphoaluminate (CSA) cement. Experimental tests on the setting time, physical properties, compressive strength, chemical shrinkage, X-ray diffraction (XRD), and scanning electron microscopy (SEM) of CSA cement paste were carried out. The XRD analysis confirmed that the main hydration product is ettringite in both freshwater and seawater mixed CSA cement with different w/c ratios. The SEM analysis and physical properties test show that both low w/c ratio and seawater can improve the microstructure of CSA cement. The test results also find out that the high w/c ratio can accelerate the hydration process, extend the setting time, lower the compressive strength, and increase the chemical shrinkage of CSA cement, and the seawater presents a similar influence except for the mechanical property. The seawater increases the compressive strength of CSA cement in the early stage of hydration but will increase the microcracks at the later hydration stage of CSA cement and reduce its mechanical properties.

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