Solvent-free mechanochemical synthesis of a carbazole-based porous organic polymer with high CO2 capture and separation

2020 ◽  
Vol 287 ◽  
pp. 121327 ◽  
Author(s):  
Rongrong Yuan ◽  
Zhuojun Yan ◽  
Alateng Shaga ◽  
Hongming He
Keyword(s):  
Co2 Capture ◽  
Mechanochemical Synthesis ◽  
Solvent Free ◽  
Organic Polymer ◽  
High Co2 ◽  
Porous Organic Polymer

Bioinspired porous organic polymer-functionalized membranes for efficient CO2 capture

2020 ◽  
Vol 4 (3) ◽  
pp. 1191-1198
Author(s):  
Zhen Wang ◽  
Yiming Zhang ◽  
Jing Wang ◽  
Yatao Zhang
Keyword(s):  
Co2 Capture ◽  
Organic Polymer ◽  
Mixed Matrix Membranes ◽  
Organic Polymers ◽  
Mixed Matrix ◽  
Porous Organic Polymers ◽  
Porous Organic Polymer ◽  
Functionalized Membranes ◽  
Matrix Membranes

Biomimetic enzyme loaded on porous organic polymers has used to develop mixed matrix membranes for efficient CO2 capture.

scholarly journals A readily accessible porous organic polymer facilitates high-yielding Knoevenagel condensation at room temperature both in water and under solvent-free mechanochemical conditions

2021 ◽  
Vol 154 ◽  
pp. 106304
Author(s):  
Parishmita Sarma ◽  
Kashyap Kumar Sarmah ◽  
Dharittri Kakoti ◽  
Sanjeev Pran Mahanta ◽  
Nadeesh Madusanka Adassooriya ◽  
...  
Keyword(s):  
Room Temperature ◽  
Knoevenagel Condensation ◽  
Solvent Free ◽  
Organic Polymer ◽  
Porous Organic Polymer

Efficient CO2 capture by a task-specific porous organic polymer bifunctionalized with carbazole and triazine groups

2014 ◽  
Vol 50 (59) ◽  
pp. 7933 ◽  
Author(s):  
Xiang Zhu ◽  
Shannon M. Mahurin ◽  
Shu-Hao An ◽  
Chi-Linh Do-Thanh ◽  
Chengcheng Tian ◽  
...  
Keyword(s):  
Co2 Capture ◽  
Organic Polymer ◽  
Porous Organic Polymer

Fabrication of acylsemicarbazide-based porous organic polymer for selective enrichment of glycopeptides

2017 ◽  
Vol 35 (7) ◽  
pp. 688
Author(s):  
Hongwei WANG ◽  
Zhongshan LIU ◽  
Xiaojun PENG ◽  
Junjie OU ◽  
Mingliang YE
Keyword(s):  
Organic Polymer ◽  
Selective Enrichment ◽  
Porous Organic Polymer

scholarly journals Mechanochemical synthesis of poly(trimethylene carbonate)s: an example of rate acceleration

2019 ◽  
Vol 15 ◽  
pp. 963-970 ◽  
Author(s):  
Sora Park ◽  
Jeung Gon Kim
Keyword(s):  
Ball Milling ◽  
Mechanochemical Synthesis ◽  
Polymeric Materials ◽  
Solvent Free ◽  
Energy Output ◽  
Polymerization Temperature ◽  
Mechanical Degradation ◽  
Trimethylene Carbonate ◽  
Rate Acceleration ◽  
Conventional Solution

Mechanochemical polymerization is a rapidly growing area and a number of polymeric materials can now be obtained through green mechanochemical synthesis. In addition to the general merits of mechanochemistry, such as being solvent-free and resulting in high conversions, we herein explore rate acceleration under ball-milling conditions while the conventional solution-state synthesis suffer from low reactivity. The solvent-free mechanochemical polymerization of trimethylene carbonate using the organocatalysts 1,8-diazabicyclo[5.4.0]undec-7-ene (DBU) and 1,5,7-triazabicyclo[4.4.0]dec-5-ene (TBD) are examined herein. The polymerizations under ball-milling conditions exhibited significant rate enhancements compared to polymerizations in solution. A number of milling parameters were evaluated for the ball-milling polymerization. Temperature increases due to ball collisions and exothermic energy output did not affect the polymerization rate significantly and the initial mixing speed was important for chain-length control. Liquid-assisted grinding was applied for the synthesis of high molecular weight polymers, but it failed to protect the polymer chain from mechanical degradation.

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