O2 plasma and cation tuned nickel phosphide nanosheets for highly efficient overall water splitting

Nano Energy ◽  
2018 ◽  
Vol 54 ◽  
pp. 82-90 ◽  
Author(s):  
Khang Ngoc Dinh ◽  
Xiaoli Sun ◽  
Zhengfei Dai ◽  
Yun Zheng ◽  
Penglun Zheng ◽  
...  
2018 ◽  
Vol 6 (4) ◽  
pp. 1682-1691 ◽  
Author(s):  
Liting Yan ◽  
Huimin Jiang ◽  
Yanlong Xing ◽  
Ying Wang ◽  
Dandan Liu ◽  
...  

Ultrasmall Ni2P/rGO was synthesized using template-confinement strategy of MOFs and served as a highly efficient electrocatalyst for overall water splitting.


2021 ◽  
Vol 12 (1) ◽  
Author(s):  
Xixi Ji ◽  
Yanhong Lin ◽  
Jie Zeng ◽  
Zhonghua Ren ◽  
Zijia Lin ◽  
...  

AbstractDevelopment of excellent and cheap electrocatalysts for water electrolysis is of great significance for application of hydrogen energy. Here, we show a highly efficient and stable oxygen evolution reaction (OER) catalyst with multilayer-stacked hybrid structure, in which vertical graphene nanosheets (VGSs), MoS2 nanosheets, and layered FeCoNi hydroxides (FeCoNi(OH)x) are successively grown on carbon fibers (CF/VGSs/MoS2/FeCoNi(OH)x). The catalyst exhibits excellent OER performance with a low overpotential of 225 and 241 mV to attain 500 and 1000 mA cm−2 and small Tafel slope of 29.2 mV dec−1. Theoretical calculation indicates that compositing of FeCoNi(OH)x with MoS2 could generate favorable electronic structure and decrease the OER overpotential, promoting the electrocatalytic activity. An alkaline water electrolyzer is established using CF/VGSs/MoS2/FeCoNi(OH)x anode for overall water splitting, which generates a current density of 100 mA cm−2 at 1.59 V with excellent stability over 100 h. Our highly efficient catalysts have great prospect for water electrolysis.


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