scholarly journals A hole-transporting material with substituted fluorene as end groups for high-performance perovskite solar cells

2021 ◽  
pp. 106325
Author(s):  
Tian Qin ◽  
Fei Wu ◽  
Linna Zhu ◽  
Weijie Chi ◽  
Yi Zhang ◽  
...  
2021 ◽  
Author(s):  
Kun-Mu Lee ◽  
Jui-Yu Yang ◽  
Ping-Sheng Lai ◽  
Ke-Jyun Luo ◽  
Ting Yu Yang ◽  
...  

A new cyclopentadithiophene (CPDT)-based organic small molecule serves as an efficient dopant-free hole transporting material (HTM) for perovskite solar cells (PSCs). Upon incorporation of two carbazole groups, the resulting CPDT-based...


2021 ◽  
Vol 119 (13) ◽  
pp. 133904
Author(s):  
Binbin Wang ◽  
Lingwei Xue ◽  
Shiqi Wang ◽  
Yao Li ◽  
Lele Zang ◽  
...  

Processes ◽  
2021 ◽  
Vol 9 (12) ◽  
pp. 2249
Author(s):  
Sanghyun Paek

Recently, perovskite solar cells have been in the spotlight due to several of their advantages. Among the components of PSCs, hole transporting materials (HTMs) re the most important factors for achieving high performance and a stable device. Here, we introduce a new D–π–D type hole transporting material incorporating Tips-anthracene as a π–conjugation part and dimethoxy-triphenylamine as a donor part (which can be easily synthesized using commercially available materials). Through the measurement of various optical properties, the new HTM not only has an appropriate energy level but also has excellent hole transport capability. The device with PEH-16 has a photovoltaic conversion efficiency of 17.1% under standard one sun illumination with negligible hysteresis, which can be compared to a device using Spiro_OMeTAD under the same conditions. Ambient stability for 1200 h shown that 98% of PEH-16 device from the initial PCE was retained, indicating that the devices had good long-term stability.


2016 ◽  
Vol 94 (4) ◽  
pp. 352-359 ◽  
Author(s):  
Andrew M. Namespetra ◽  
Arthur D. Hendsbee ◽  
Gregory C. Welch ◽  
Ian G. Hill

Three low-cost propeller-shaped small molecules based on a triphenylamine core and the high-performance donor molecule 7,7′-[4,4-bis(2-ethylhexyl)-4H-silolo[3,2-b:4,5-b′]dithiophene-2,6-diyl]bis[6-fluoro-4-(5′-hexyl-[2,2′-bithiophen]-5-yl)benzo[c][1,2,5]thiadiazole] (DTS(FBTTh2)2) were investigated as hole-transporting materials in perovskite solar cells. Each hole-transporting material was designed with highly modular side arms, allowing for different bandgaps and thin-film properties while maintaining a consistent binding energy of the highest occupied molecular orbitals to facilitate hole extraction from the perovskite active layer. Perovskite solar cell devices were fabricated with each of the three triphenylamine-based hole-transporting materials and DTS(FBTTh2)2 and were compared to devices with 2,2′,7,7′-tetrakis(N,N-di-p-methoxyphenylamine)-9,9′-spirobifluorene (spiro-OMeTAD) hole-transporting layers. Each of our triphenylamine hole-transporting materials and DTS(FBTTh2)2 displayed surface morphologies that were considerably rougher than that of spiro-OMeTAD; a factor that may contribute to lower device performance. It was found that using inert, insulating polymers as additives with DTS(FBTTh2)2 reduced the surface roughness, resulting in devices with higher photocurrents.


Nanoscale ◽  
2016 ◽  
Vol 8 (12) ◽  
pp. 6290-6299 ◽  
Author(s):  
Mingzhu Long ◽  
Zefeng Chen ◽  
Tiankai Zhang ◽  
Yubin Xiao ◽  
Xiaoliang Zeng ◽  
...  

We report a molecule/polymer composite hole transporting material (HTM) with a periodic microstructure for optical and electronic enhancement for high performance perovskite solar cells.


Nanoscale ◽  
2017 ◽  
Vol 9 (36) ◽  
pp. 13506-13514 ◽  
Author(s):  
Yan-Hui Lou ◽  
Zhao-Kui Wang

Poly(3,4-ethylene dioxythiophene):poly(4-styrenesulfonate) (PEDOT:PSS) is a widely utilized hole-transporting material (HTM) in planar photovoltaic devices, such as organic solar cells (OSCs) and perovskite solar cells (PSCs).


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