Clarification of the confusion concerning the crystal-field quantities vs. the zero-field splitting quantities in magnetism studies: Part I—Survey of literature dealing with specific compounds

Physica B Condensed Matter ◽

10.1016/j.physb.2007.10.219 ◽

2008 ◽

Vol 403 (10-11) ◽

pp. 1882-1897 ◽

Author(s):

C. Rudowicz

Keyword(s):

Crystal Field ◽

Zero Field Splitting ◽

Field Splitting

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Analysis of low symmetry aspects revealed by the zero-field splitting parameters and the crystal field parameters for Cr3+ ions doped into yttrium aluminum borate YAl3(BO3)4 crystal

Optical Materials ◽

10.1016/j.optmat.2014.03.025 ◽

2014 ◽

Vol 36 (8) ◽

pp. 1342-1349 ◽

Author(s):

Muhammed Açıkgöz ◽

Paweł Gnutek ◽

Czesław Rudowicz

Keyword(s):

Crystal Field ◽

Aluminum Borate ◽

Zero Field Splitting ◽

Field Splitting ◽

Yttrium Aluminum ◽

Yttrium Aluminum Borate ◽

Crystal Field Parameters ◽

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EPR Study of Low Symmetry Mn2+ Centers in LiNbO3. Superposition Model and Crystal Field Analysis of the Zero-Field Splitting Parameters

physica status solidi (b) ◽

10.1002/pssb.2221850212 ◽

1994 ◽

Vol 185 (2) ◽

pp. 417-428 ◽

Author(s):

T. H. Yeom ◽

S. H. Choh ◽

Y. M. Chang ◽

C. Rudowicz

Keyword(s):

Crystal Field ◽

Field Analysis ◽

Superposition Model ◽

Zero Field Splitting ◽

Field Splitting ◽

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Determination of the Zero-Field Splitting Parameter and Hyperfine Interaction of Paramagnetic Ions of Half-Integral Spin (S ≧ 3/2) in a Strong Axial Crystal Field

physica status solidi (b) ◽

10.1002/pssb.2220710154 ◽

1975 ◽

Vol 71 (1) ◽

pp. K49-K53 ◽

Author(s):

O. S. Torosyan ◽

E. G. Sharoyan

Keyword(s):

Hyperfine Interaction ◽

Crystal Field ◽

Zero Field Splitting ◽

Field Splitting ◽

Zero Field Splitting Parameter ◽

Integral Spin ◽

Splitting Parameter ◽

Paramagnetic Ions

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Clarification of terminological confusion concerning the crystal field quantities vs. the effective spin Hamiltonian and zero-field splitting quantities in the papers by Bayrakçeken et al. [Spectrochim. Acta Part A 66 (2007) 462 and 1291]

Spectrochimica Acta Part A Molecular and Biomolecular Spectroscopy ◽

10.1016/j.saa.2008.04.025 ◽

2008 ◽

Vol 71 (4) ◽

pp. 1623-1626 ◽

Author(s):

Czesław Rudowicz

Keyword(s):

Crystal Field ◽

Spin Hamiltonian ◽

Zero Field Splitting ◽

Field Splitting ◽

Effective Spin ◽

Terminological Confusion

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Modeling the zero-field splitting parameters and local structure of Co2+ ions doped into PbMoO4 crystal based on crystal field approach and superposition model analysis

Optical Materials ◽

10.1016/j.optmat.2018.07.003 ◽

2018 ◽

Vol 84 ◽

pp. 466-474 ◽

Author(s):

Danuta Piwowarska ◽

Paweł Gnutek ◽

Czesław Rudowicz

Keyword(s):

Crystal Field ◽

Local Structure ◽

Model Analysis ◽

Superposition Model ◽

Zero Field Splitting ◽

Field Splitting ◽

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Crystal field levels and zero-field splitting parameters of Cr2+ in the mixed system Rb2MnxCr1−xCl4

Physica B Condensed Matter ◽

10.1016/0921-4526(93)90092-k ◽

1993 ◽

Vol 191 (3-4) ◽

pp. 323-333 ◽

Author(s):

Czeslaw Rudowicz ◽

Maolu Du ◽

Yau-yuen Yeung ◽

Yi-yang Zhou

Keyword(s):

Crystal Field ◽

Mixed System ◽

Zero Field Splitting ◽

Field Splitting

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Zero-Field Splitting in Transition Metal Complexes: Ab Initio Calculations, Effective Hamiltonians, Model Hamiltonians, and Crystal-Field Models

Handbook of Relativistic Quantum Chemistry ◽

10.1007/978-3-642-40766-6_37 ◽

2016 ◽

pp. 765-796

Author(s):

Rémi Maurice ◽

Ria Broer ◽

Nathalie Guihéry ◽

Coen de Graaf

Keyword(s):

Transition Metal ◽

Ab Initio Calculations ◽

Metal Complexes ◽

Ab Initio ◽

Crystal Field ◽

Transition Metal Complexes ◽

Zero Field Splitting ◽

Field Splitting ◽

Effective Hamiltonians

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Analytical Investigations of Spin-Spin, Spin-Other-Orbit and Combined Mechanisms of Zero-Field Splitting for 3d3 Ions at Trigonal Symmetry

Zeitschrift für Naturforschung A ◽

10.1515/zna-2009-9-1017 ◽

2009 ◽

Vol 64 (9-10) ◽

pp. 646-652

Author(s):

Qun Wei

Keyword(s):

Crystal Field ◽

Magnetic Interaction ◽

Zero Field Splitting ◽

Field Splitting ◽

Trigonal Symmetry ◽

Diagonalization Method ◽

Crystal Field Parameters ◽

Analytical Expressions

A new method of obtaining approximate analytical expressions of zero-field splitting (ZFS) has been proposed. By analyzing the magnetic interaction mechanisms which affect the properties of ZFS of ground 4A2 state for 3d3 ions at trigonal symmetry, and comparing with the calculated results of complete diagonalization method, the approximate analytical expressions of the contribution to zero-field splitting of 4A2 state from spin-spin (SS), spin-other-orbit (SOO), and combined mechanisms have been obtained. Also the applicability of these approximate analytical expressions has been analyzed. It is shown that the approximate analytical expressions are suitable in a wide crystal field parameters range.

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Terminological confusions and problems at the interface between the crystal field Hamiltonians and the zero-field splitting Hamiltonians—Survey of the CF=ZFS confusion in recent literature

Physica B Condensed Matter ◽

10.1016/j.physb.2014.06.018 ◽

2014 ◽

Vol 451 ◽

pp. 134-150 ◽

Author(s):

Czesław Rudowicz ◽

Mirosław Karbowiak

Keyword(s):

Crystal Field ◽

Recent Literature ◽

Zero Field Splitting ◽

Field Splitting

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Implications of Invalid Conversions between Crystal-Field Parameters and Zero-Field Splitting Ones Used in Superposition Model

Acta Physica Polonica A ◽

10.12693/aphyspola.125.1215 ◽

2014 ◽

Vol 125 (5) ◽

pp. 1215-1219 ◽

Author(s):

C. Rudowicz ◽

M. Karbowiak

Keyword(s):

Crystal Field ◽

Superposition Model ◽

Zero Field Splitting ◽

Field Splitting ◽

Crystal Field Parameters

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