Phosphorus-containing diamine for flame retardancy of high functionality epoxy resins. Part II. The thermal and mechanical properties of mixed amine systems

Polymer ◽  
2006 ◽  
Vol 47 (6) ◽  
pp. 2091-2098 ◽  
Author(s):  
Weichang Liu ◽  
Russell J. Varley ◽  
George P. Simon
RSC Advances ◽  
2021 ◽  
Vol 11 (49) ◽  
pp. 30943-30954
Author(s):  
Wei Peng ◽  
Yu-xuan Xu ◽  
Shi-bin Nie ◽  
Wei Yang

Phosphorus-containing flame retardants have received huge interest for improving the flame retardant behavior of epoxy resins (EP) over the past few decades.


Polymers ◽  
2021 ◽  
Vol 13 (5) ◽  
pp. 741
Author(s):  
Zorana Kovačević ◽  
Sandra Flinčec Grgac ◽  
Sandra Bischof

This paper summarizes the results obtained in the course of the development of a specific group of biocomposites with high functionality of flame retardancy, which are environmentally acceptable at the same time. Conventional biocomposites have to be altered through different modifications, to be able to respond to the stringent standards and environmental requests of the circular economy. The most commonly produced types of biocomposites are those composed of a biodegradable PLA matrix and plant bast fibres. Despite of numerous positive properties of natural fibres, flammability of plant fibres is one of the most pronounced drawbacks for their wider usage in biocomposites production. Most recent novelties regarding the flame retardancy of nanocomposites are presented, with the accent on the agents of nanosize (nanofillers), which have been chosen as they have low or non-toxic environmental impact, but still offer enhanced flame retardant (FR) properties. The importance of a nanofiller’s geometry and shape (e.g., nanodispersion of nanoclay) and increase in polymer viscosity, on flame retardancy has been stressed. Although metal oxydes are considered the most commonly used nanofillers there are numerous other possibilities presented within the paper. Combinations of clay based nanofillers with other nanosized or microsized FR agents can significantly improve the thermal stability and FR properties of nanocomposite materials. Further research is still needed on optimizing the parameters of FR compounds to meet numerous requirements, from the improvement of thermal and mechanical properties to the biodegradability of the composite products. Presented research initiatives provide genuine new opportunities for manufacturers, consumers and society as a whole to create a new class of bionanocomposite materials with added benefits of environmental improvement.


2019 ◽  
Vol 305 (1) ◽  
pp. 1900587 ◽  
Author(s):  
Jingjing Meng ◽  
Yushun Zeng ◽  
Pengfei Chen ◽  
Jie Zhang ◽  
Cheng Yao ◽  
...  

2015 ◽  
Vol 1110 ◽  
pp. 69-72
Author(s):  
Fu Ke Wang ◽  
Chao Bin He

The dispersion and exfoliation of graphene oxides in polymer matrix remains a challenge for graphene oxides based epoxy nanocomposites fabrication. In the present paper, we reported a simple and facile solvent exchange technique to successfully transfer graphene oxides (GOs) from aqueous solution to ethanol. In addition, we found that GO dispersion in epoxy resins was affected by the curing agents. Good dispersion of GOs in epoxy resin together with enhanced thermal and mechanical properties were observed when epoxy was cured with aliphatic curing agents. For aromatic curing agent, high loading of GOs leaded to GOs aggregation, but well dispersed GOs was observed at low loading of GOs. Especially, a 12 °C increase of glass transition temperature of the epoxy resin was observed with only 0.1 wt% GOs was added to the epoxy resin.


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