scholarly journals Performance of Tetraphenylsulfonato Disilane in Catalytic Transesterification of Crude Palm Oil and Esterification of Fatty Acids with Secondary Alcohols

2015 ◽  
Vol 14 ◽  
pp. 295-300
Author(s):  
Nimpan Bangun ◽  
Wiyanti Manullang ◽  
Lois Panggabean ◽  
Seri Bima Sembiring ◽  
Rizal Simangunsong ◽  
...  
2019 ◽  
Vol 23 (3) ◽  
Author(s):  
Mohamad Makrus Ali ◽  
◽  
Tun Tedja Irawadi ◽  
Noviyan Darmawan ◽  
Mohammad Khotib ◽  
...  

2013 ◽  
Vol 13 (2) ◽  
pp. 142-148
Author(s):  
Nafly C. Tiven ◽  
Lies Mira Yusiati ◽  
Rusman Rusman ◽  
Umar Santoso

This research aimed to determine the effect of crude palm oil protected with formaldehyde on the hydrogenation of unsaturated fatty acids in the rumen and its effect on blood and meat fatty acids. Fifteenth local male lambs aged 9-12 months weighing 14-17 kg, were divided into 3 groups ration treatment. The first group received only the basal ration (R0), the 2nd group received the basal ration and 3% CPO (R1), while the 3rd group received the basal ration and 3% CPO protected with 2% formaldehyde (R2). Basal feed consisted of 60% grass, 30% bran and 10% soybean meal, with the nutrient content of 62.98% TDN, 45.5% DM, 14.48% CP, 4.70% EE and 21.93% CF. Parameters observed were the fatty acid from rumen fluid, blood and meat of sheep. Data were analyzed by complete randomized design direction patterns. Differences between treatments were tested further using Duncan's New Multiple Range Test. The results showed that treatment of R2 can increase unsaturated fatty acids in the rumen, blood and meat (P


2020 ◽  
Vol 23 (4) ◽  
pp. 124-128
Author(s):  
Rahmiwati Hilma ◽  
Eka Tri Setya Wulandari ◽  
Zaldi Arman

Fruit stalk of chili pepper (Capsicum annum L.) so far is still an untapped waste. The content of active compounds in fruit and fruit stalk of chili pepper (C. annum L.) is known to have good antioxidant activity. The purpose of this study was to evaluate the extract of fruit stalk of chili pepper in inhibiting the oxidation of crude palm oil (CPO). In this study, the extraction of fruit stalk of chili pepper (C. annum L.) was carried out with n-hexane (from now on referred to as CHE) solvent and with ethanol solvent (from now on referred to as CEE). CHE and CEE were analyzed for total phenolic and flavonoid analyzes. Next, an evaluation of antioxidant activity was carried out using the DPPH method. The effectiveness test of adding the two extracts to the quality of CPO was carried out for ten days using a Completely Randomized Design (CRD) analysis. The parameters observed were peroxide numbers, free fatty acids, and iodine numbers. Data were analyzed by ANOVA and followed by a Least Significance Different (LSD) test. The results show that the total phenolic value is 0.257 mg QE/g dry weight in CEE and 0.003 mg QE/g dry weight in CHE. Total flavonoid values are 0.155 mg QE/g dry weight in CEE and 0.003 mg QE/g in CHE. IC50 values for DPPH test extract are 223.72 μg/mL in CEE and 953.77 μg/mL in CHE. The test results of the effectiveness of the two extracts against CPO show thin CEE, and CHE significantly (P <0.05) influences to CPO free fatty acids, peroxide number, and iodine number. Both extracts can protect CPO from oxidation. CEE is more effective in maintaining CPO quality for ten days with free fatty acid values (2.1%), peroxide value values 0.48 meq/kg, and iodine number 54.8. Furthermore, this result meets the CPO quality standard, according to SNI-01-2901-2006.


Agriculture ◽  
2021 ◽  
Vol 11 (11) ◽  
pp. 1030
Author(s):  
Arutchelvam Balakrishnan ◽  
Mohd Ibnur Syawal Zakaria ◽  
Bee Aik Tan ◽  
Jaime Yoke Sum Low ◽  
Shwu Fun Kua ◽  
...  

The processing of oil palm fresh fruit bunches (FFB), together with loose fruits, in the current mill operation contributes to oil loss and high free fatty acids (FFA), affecting crude palm oil quality. Fruit detachment induced by ethephon and ethylene may mitigate the current processing issues. This study shows that a 0.50% (v/v) ethephon application by the evaporation method induced the highest fruit detachment of 30.8 ± 1.1% after 24 h at room temperature, with the FFA content in the extracted crude palm oil at 0.34 ± 0.09%. Ethephon application was effective on bunches between 14 and 28 kg, and fruit detachment was higher in ripe and underripe bunches at 24.1 ± 0.9% and 23.2 ± 0.1%, respectively. A significant fruit detachment of 47.2 ± 2.4% was achieved when the bunches were also stripped mechanically, but the FFA content increased almost 4-fold, from 1.0 ± 0.2% to 3.8 ± 1.2%. The application of ethylene gas at 750 ppm yielded 29.4 ± 1.9% fruit detachment. The findings present the possibility of using ethylene as an indirect method for minimizing oil loss without increasing the FFA content in future crude palm oil production systems.


2021 ◽  
Vol 8 (1) ◽  
pp. 243-251
Author(s):  
St Nova Meirizha ◽  
Dian Kristina

Quality is the overall characteristics and characteristics of a product or service whose ability to satisfy needs, both expressed and implied (Irwan & Haryono, 2015). In this era of increasingly competitive industrialization, every business person who wants to win the competition in the industrial world will pay full attention to quality. QCC is a new concept to improve the quality and productivity of industrial/service work. It is evident that one of the success factors of industrialization in Japan is the effective implementation of QCC. In this research journal, the quality of crude palm oil (CPO) levels is decreasing. There are 3 types of defects, namely levels of FFA (Free Fatty Acids), levels of Moisture (Water) and levels of Dirt (Stool). Of these three, the most dominant are FFA levels and Moisture levels. Free fatty acid content (FFA) of 158 samples tested contained 150 samples of free fatty acids (FFA) which were outside the company standard. Then followed by moisture content with a total defect of 45 samples from 158 test samples. At the level of dirt (Dirt) there are absolutely no samples that are outside the company's standards.


2021 ◽  
Vol 14 (2) ◽  
Author(s):  
Murad Bahadi ◽  
Nadia Salih ◽  
Jumat Salimon

Oleic acid (OA) rich vegetable oils is important for the daily essential dietary oils intake but restrict to particular oil such as olive oil. However OA enrichment to other vegetable oil such as palm oil is always possible. OA can be obtained from cheap resources such as high free fatty acid crude palm oil (HFFA-CPO). OA concentrate from HFFA-CPO fatty acids mixture requires efficient and low cost technique. Urea complex crystallization fractionation is a classic method for fractionating saturated and monounsaturated fatty acids from polyunsaturated fatty acids of many vegetable oils. In this work, the separation and purification of oleic acid (OA) from unsaturated fatty acids mixture fraction (USFA) of HFFA-CPO fatty acids mixture by urea complex fractionation (UCF) was studied. The crystallization reaction conditions of urea inclusion for the non-urea complex fraction (NUCF) were optimized using the response surface methodology (RSM) and the optimal model was developed. The results showed high content of OA (88%) in urea complex fraction (UCF) with 86% yield at optimal conditions of urea-to-USFAs ratio of 4.62 : 1 (w/w), crystallization temperature at –10°C and crystallization time of 24 h. The results have demonstrated that urea complex crystallization fractionation method is a very effective with low cost, stable, obtainable, and comparatively ease to recover of OA from polyunsaturated fatty acids (PUFA) of an oil fatty acids mixture. Pure OA is plausible to be used back for the OA enrichment modification into palm oil for new dietary oil.


2016 ◽  
Vol 6 (1) ◽  
pp. 50 ◽  
Author(s):  
Fabrice F. D. Dongho ◽  
Inocent Gouado ◽  
Lambert M. Sameza ◽  
Raymond S. Mouokeu ◽  
Adelaïde M. Demasse ◽  
...  

Crude palm oil (CPO) is an essential ingredient of Cameroonian recipes. However, its quality is subject to doubt, considering the very often inadequate conditions of extraction, conditioning, storage, and selling in the fast growing small holder sector or in the market. This work aimed to evaluate the influence of seasons and containers on the microbiologic, physicochemical quality and the carotenoids content of CPO sold in Douala. A total of 194 samples of CPO were randomly collected in seven markets among which: 95 during the rainy season and 99 during dry season; 93 from CPO contained in opened containers and 101 in closed containers. In these samples, aerobic count colony (ACC) load, total yeasts and moulds load, peroxide value (PV), free fatty acids content (FFA), impurity level and carotenoids content were assayed.The samples tested had ACC load of 4.48±1.86x105 CFU/ml, total yeasts and moulds load of 0.30±0.14x105 CFU/ml, PV of 1.81±0.74 meqO2/kg, FFA of 4.30±1.82%, impurity level of 0.34±0.16% and carotenoids content of 756.41±110.67 mg/l. Also, none of these parameters had varied according to the market. Moreover, among these parameters, PV and carotenoids content were not varied whatever CPO is sold during rainy or dry season, in open or closed containers while others parameters analysed were significantly (P<0.05) higher during dry season or when the CPO was contained in open containers. Consequently, traders should make efforts to avoid CPO contamination during the selling. They could package it first and store it in an adequate space particularly during dry season. 


2021 ◽  
Vol 11 (15) ◽  
pp. 7094
Author(s):  
Erislene S. de Almeida ◽  
Daniela da Silva Damaceno ◽  
Laiane Carvalho ◽  
Priscilla Araújo Victor ◽  
Rafaela Menezes dos Passos ◽  
...  

Interspecific hybridization of oil palms (E. guineensis × E. oleifera) was initially exploited to provide disease resistance and, consequently, increased oleic acid content. Besides the growing importance of this cultivar to the market, there is little information about this oil’s properties. In this context, this study aimed to determine a comprehensive physicochemical and thermal characterization of hybrid palm oil (HOPO) compared with the better-known African palm oil (APO). Differences in the distribution of fatty acids, carotenoids, and tocols were observed. Minor differences in density and viscosity were found between the oils, with no relevance for the materials’ processing design. Nevertheless, HOPO showed unique crystallization behavior, which potentially can affect industrial operations, such as fractionation. HOPO did not present the two thermal characteristic regions of APO, attributed to olein and stearin fractions. The HOPO demonstrated a decrease in the melting point of more than 3 °C in relation to APO, and a reduction in the crystallization point of more than 6 °C. Furthermore, besides the higher content of unsaturated fatty acids, HOPO was more stable than APO due to a higher antioxidant content. These results could be useful to establish operation conditions for processes using palm oil from hybrid oil palm.


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