scholarly journals Recent advances in thermoplastic elastomers from living polymerizations: Macromolecular architectures and supramolecular chemistry

2019 ◽  
Vol 95 ◽  
pp. 1-31 ◽  
Author(s):  
Weiyu Wang ◽  
Wei Lu ◽  
Andrew Goodwin ◽  
Huiqun Wang ◽  
Panchao Yin ◽  
...  
1991 ◽  
Vol 64 (3) ◽  
pp. 450-468 ◽  
Author(s):  
Roderic P. Quirk ◽  
Jungahn Kim

Abstract A variety of living polymerization systems are now available for the controlled synthesis of block copolymers. Although living anionic polymerization remains as the method of choice for the most precise structural control, living polymerizations proceeding via other mechanistic types provide extremely useful extensions of this methodology to a wider variety of monomers.


1981 ◽  
Vol 54 (3) ◽  
pp. 627-640 ◽  
Author(s):  
Adel F. Halasa

Abstract In summary, one can say that the versatility of living polymerization makes it a very useful and unique technique. Synthetic polymer chemists can utilize the lithium at the end of the chain to add polymer-like conjugated monomers, in order to tailor-make the polymer chain, or they can use chelating diamines to change the microstructure of the polymer chain. They can also run hydrogenation on anionically prepared polydienes to produce thermoplastic elastomers. They can transform anionically made polymer chain ends by adding ethylene oxide, carbon dioxide and halogens. This paper has emphasized recent advances in this field.


Molecules ◽  
2021 ◽  
Vol 27 (1) ◽  
pp. 150
Author(s):  
Geeta A. Zalmi ◽  
Ratan W. Jadhav ◽  
Harshad A. Mirgane ◽  
Sheshanath V. Bhosale

The emergence and development of aggregation induced emission (AIE) have attracted worldwide attention due to its unique photophysical phenomenon and for removing the obstacle of aggregation-caused quenching (ACQ) which is the most detrimental process thereby making AIE an important and promising aspect in various fields of fluorescent material, sensing, bioimaging, optoelectronics, drug delivery system, and theranostics. In this review, we have discussed insights and explored recent advances that are being made in AIE active materials and their application in sensing, biological cell imaging, and drug delivery systems, and, furthermore, we explored AIE active fluorescent material as a building block in supramolecular chemistry. Herein, we focus on various AIE active molecules such as tetraphenylethylene, AIE-active polymer, quantum dots, AIE active metal-organic framework and triphenylamine, not only in terms of their synthetic routes but also we outline their applications. Finally, we summarize our view of the construction and application of AIE-active molecules, which thus inspiring young researchers to explore new ideas, innovations, and develop the field of supramolecular chemistry in years to come.


2015 ◽  
Vol 51 (28) ◽  
pp. 6050-6075 ◽  
Author(s):  
Sebastián Alberti ◽  
Galo J. A. A. Soler-Illia ◽  
Omar Azzaroni

This Feature Article discusses recent advances in the design of mesoporous silica nanoarchitectures that can control mass transport on command through the combination of flexible supramolecular routes.


2021 ◽  
Author(s):  
Bin Huang ◽  
Lijun Mao ◽  
Xueliang Shi ◽  
Hai-Bo Yang

Supramolecular radical chemistry has been emerging as a cutting-edge interdisciplinary field of traditional supramolecular chemistry and radical chemistry in recent years. The purpose of such fundamental research field is to...


2006 ◽  
Vol 59 (1) ◽  
pp. 3 ◽  
Author(s):  
Chun-Long Chen ◽  
Bei-Sheng Kang ◽  
Cheng-Yong Su

The supramolecular chemistry of Ag(i) coordination assemblies continues to attract attention due to their versatile structural diversity and potential physical and chemical functions. This article provides a short review of recent advances in the design and construction of Ag(i) coordination polymers with special emphasis on the Ag(i) ion coordination geometry, ligand functionality, and supramolecular interactions. The potential functions of Ag(i) coordination polymers are briefly summarized.


2021 ◽  
Author(s):  
Weiwei Xu ◽  
Ming Cheng ◽  
Siyun Zhang ◽  
Qifa Wu ◽  
Zhuo Liu ◽  
...  

Chiral discrimination has gained much focus in supramolecular chemistry, since it is one of the fundamental processes in biological systems, enantiomeric separation and biochemical sensors. Though most of the biochemical...


2021 ◽  
Vol 427 ◽  
pp. 213588
Author(s):  
Henry A. Nkabyo ◽  
Ilse Barnard ◽  
Klaus R. Koch ◽  
Robert C. Luckay

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