Synthesis, crystal structure, cationic mobility, thermal evolution and spectroscopic study of Cs8(UO2)4(WO4)4(WO5)2 containing infinite uranyl tungstate chains

2007 ◽  
Vol 9 (10) ◽  
pp. 933-943 ◽  
Author(s):  
Saïd Yagoubi ◽  
Saïd Obbade ◽  
Mohamed Benseghir ◽  
Francis Abraham ◽  
Mohamed Saadi
1999 ◽  
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pp. 536-549 ◽  
Author(s):  
Edward S. Grew ◽  
Guenther J. Redhammer ◽  
Georg Amthauer ◽  
Mark A. Cooper ◽  
Frank C. Hawthorne ◽  
...  

2003 ◽  
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Guan-Yeow Yeap ◽  
Sie-Tiong Ha ◽  
Nobuo Ishizawa ◽  
Katsumi Suda ◽  
Peng-Lim Boey ◽  
...  

2005 ◽  
Vol 752 (1-3) ◽  
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Author(s):  
Hui Chai ◽  
Guangfei Liu ◽  
Lang Liu ◽  
Dianzeng Jia ◽  
Zaiping Guo ◽  
...  

Polyhedron ◽  
1998 ◽  
Vol 17 (13-14) ◽  
pp. 2379-2410 ◽  
Author(s):  
N.C. Baenziger ◽  
W.E. Bennett ◽  
D.M. Soboroff ◽  
P.S. O'Donnell ◽  
J.R. Doyle

2018 ◽  
Vol 5 (6) ◽  
pp. 180368 ◽  
Author(s):  
S. L. Skjærvø ◽  
K. Høydalsvik ◽  
A. B. Blichfeld ◽  
M.-A. Einarsrud ◽  
T. Grande

The thermal evolution of the crystal structure and phase transitions of KNbO 3 were investigated by high-temperature powder X-ray diffraction and Rietveld refinement of the diffraction data. Two phase transitions from orthorhombic ( Amm 2) to tetragonal ( P 4 mm ) and from tetragonal to cubic ( P m 3 ¯ m ) were confirmed, both on heating and cooling. Both phase transitions are first order based on the observed hysteresis. The mixed displacive and order–disorder nature of the tetragonal to cubic transition is argued based on symmetry and apparent divergence of the atomic positions from pseudo-cubic values. The transition between the orthorhombic and tetragonal phase shows no temperature-dependence for atomic positions and only thermal expansion of the unit cell parameters and is thus discussed in relation to a lattice dynamical instability.


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