Evidence for through-bond interaction between mutually perpendicular PI systems

Rolf Gleiter; Rudolf Haider; Jens Spanget-Larsen; Peter Bischof

doi:10.1016/s0040-4039(00)86389-3

Evidence for through-bond interaction between mutually perpendicular PI systems

Tetrahedron Letters ◽

10.1016/s0040-4039(00)86389-3 ◽

1983 ◽

Vol 24 (11) ◽

pp. 1149-1152 ◽

Cited By ~ 5

Author(s):

Rolf Gleiter ◽

Rudolf Haider ◽

Jens Spanget-Larsen ◽

Peter Bischof

Keyword(s):

Bond Interaction ◽

Pi Systems

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Through-bond interaction of two mutually perpendicular .pi. systems. A comparison with spiroconjugation

Journal of the American Chemical Society ◽

10.1021/ja00472a003 ◽

1978 ◽

Vol 100 (4) ◽

pp. 1036-1042 ◽

Cited By ~ 54

Author(s):

Peter Bischof ◽

Rolf Gleiter ◽

Rudolf Haider

Keyword(s):

Bond Interaction ◽

Pi Systems

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Faculty Opinions recommendation of Large-Scale Analysis of Hydrogen Bond Interaction Patterns in Protein-Ligand Interfaces.

Faculty Opinions – Post-Publication Peer Review of the Biomedical Literature ◽

10.3410/f.727608962.793532353 ◽

2017 ◽

Author(s):

Diana Wetmore

Keyword(s):

Hydrogen Bond ◽

Large Scale ◽

Interaction Patterns ◽

Scale Analysis ◽

Hydrogen Bond Interaction ◽

Bond Interaction ◽

Large Scale Analysis

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ChemInform Abstract: IMPACT OF HIGH-LYING Σ ORBITALS AND EXTENSIVE THROUGH-BOND INTERACTION ON CHEMICAL REACTIVITY. 2. SOLVOLYTIC STUDIES OF HYPOSTROPHENE DERIVATIVES

Chemischer Informationsdienst ◽

10.1002/chin.197834167 ◽

1978 ◽

Vol 9 (34) ◽

Author(s):

G. KLEIN ◽

L. A. PAQUETTE

Keyword(s):

Chemical Reactivity ◽

Bond Interaction

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Theoretical Study of Optical Absorption Curves of Molecules. III: Force Constant and Bond-Bond Interaction in Conjugated Molecules

Progress of Theoretical Physics ◽

10.1143/ptp.51.1646 ◽

1974 ◽

Vol 51 (5) ◽

pp. 1646-1646 ◽

Cited By ~ 6

Author(s):

T. Kakitani

Keyword(s):

Optical Absorption ◽

Force Constant ◽

Theoretical Study ◽

Conjugated Molecules ◽

Bond Interaction

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.eta.2-Acyl coordination and .beta.-carbon-hydrogen bond interaction in acyl complexes of molybdenum. Crystal and molecular structures of tris(trimethylphosphine)carbonylchloro(.eta.2-trimethylsilylacetyl)molybdenum [Mo(.eta.2-COCH2SiMe3)Cl(CO)(PMe3)3] and the cyclic complex [cyclic] Mo(COCH3)(S2CNMe2)(CO)(PMe3)2

Journal of the American Chemical Society ◽

10.1021/ja00323a025 ◽

1984 ◽

Vol 106 (11) ◽

pp. 3214-3222 ◽

Cited By ~ 40

Author(s):

Ernesto Carmona ◽

Luis Sanchez ◽

Jose M. Marin ◽

Manuel L. Poveda ◽

Jerry L. Atwood ◽

...

Keyword(s):

Hydrogen Bond ◽

Molecular Structures ◽

Hydrogen Bond Interaction ◽

Crystal And Molecular Structures ◽

Acyl Complexes ◽

Bond Interaction

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Atomic-level insights into the activation of nitrogen via hydrogen-bond interaction toward nitrogen photofixation

Chem ◽

10.1016/j.chempr.2021.03.018 ◽

2021 ◽

Author(s):

Yue Xin ◽

Sanmei Wang ◽

Haibo Yuan ◽

Tingting Hou ◽

Wenkun Zhu ◽

...

Keyword(s):

Hydrogen Bond ◽

Atomic Level ◽

Hydrogen Bond Interaction ◽

Bond Interaction

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ChemInform Abstract: THROUGH-BOND INTERACTION OF TWO MUTUALLY PERPENDICULAR Π SYSTEMS. A COMPARISON WITH SPIROCONJUGATION

Chemischer Informationsdienst ◽

10.1002/chin.197823063 ◽

1978 ◽

Vol 9 (23) ◽

Author(s):

P. BISCHOF ◽

R. GLEITER ◽

R. HAIDER

Keyword(s):

Bond Interaction

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The Through-Bond Interaction of a Sulfur Lone Pair with Oxygenated Substituents in the Thiacyclohexane Framework

Australian Journal of Chemistry ◽

10.1071/ch05073 ◽

2005 ◽

Vol 58 (7) ◽

pp. 531

Author(s):

Laura Andrau ◽

Jonathan M. White

Keyword(s):

Low Temperature ◽

Crystal Structures ◽

Bond Distance ◽

Lone Pair ◽

X Ray ◽

Ester Derivative ◽

Bond Interaction ◽

Derivatives Of ◽

Electron Demand

Low-temperature X-ray crystal structures were determined on a range of derivatives of 4-thiacyclohexanol 5a of varying electron demand with a view to finding evidence for a through-bond interaction between the sulfur lone pair and the oxygenated substituent. In contrast to earlier suggestions, plots of C–OR bond distance versus pKa (ROH) showed that any interaction between the sulfur and the OR group is unlikely to be of a through-bond origin. Furthermore, unimolecular solvolysis rate measurements on the nosylate ester derivative 5g showed that the sulfur actually retards the reaction slightly in comparison with the corresponding sulfur-free analogue 6.

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